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1. Radical boron migration of allylboronic esters

Author

Xiangzhang Tao, Shengyang Ni, Lingyu Kong, Yi Wang, and Yi Pan

Subjects
General Chemistry
Abstract

A photocatalyzed 1,3-boron shift of allylboronic esters is reported. The atom-switch acrobatics proceeds via cascade 1,2-boron migrations and Smiles type rearrangement to furnish a variety of terminally functionalized alkyl boronates.

Published
2021

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