Radical boron migration of allylboronic esters

Authors :: Xiangzhang Tao
Shengyang Ni
Lingyu Kong
Yi Wang
Yi Pan
Source :: Chemical science. 13(7)
Publication Year :: 2021
Abstract: A photocatalyzed 1,3-boron shift of allylboronic esters is reported. The atom-switch acrobatics proceeds via cascade 1,2-boron migrations and Smiles type rearrangement to furnish a variety of terminally functionalized alkyl boronates.

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