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Start Over Author "Voloshyn I" Journal chemical communications cambridge england

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1. Secondary structure changes as the potential H 2 sensing mechanism of group D [FeFe]-hydrogenases.

Author

Voloshyn I, Schumann C, Cabotaje PR, Zamader A, Land H, and Senger M

Subjects
Iron-Sulfur Proteins chemistry, Iron-Sulfur Proteins metabolism, Protein Structure, Secondary, Hydrogenase chemistry, Hydrogenase metabolism, Hydrogen chemistry, Hydrogen metabolism
Abstract

[FeFe]-hydrogenases function as both H 2 catalysts and sensors. While catalysis is well investigated, details regarding the H 2 sensing mechanism are limited. Here, we relate protein structure changes to H 2 sensing, similar to light-driven bio-sensors. Our results highlight how identical cofactors incorporated in alternative protein scaffolds serve different functions in nature.

Published
2024
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