1. Stable bromoallene oxides
- Author
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Andrew J. P. White, Henry Rzepa, D. Christopher Braddock, and Areeb Mahtey
- Subjects
chemistry.chemical_classification ,010405 organic chemistry ,Chemistry ,Alkene ,Allene ,Organic Chemistry ,Metals and Alloys ,Diastereomer ,Oxide ,Regioselectivity ,General Chemistry ,010402 general chemistry ,01 natural sciences ,Catalysis ,0104 chemical sciences ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,chemistry.chemical_compound ,Chemical Sciences ,Materials Chemistry ,Ceramics and Composites ,Organic chemistry - Abstract
The first stable bromoallene oxides were obtained by the DMDO epoxidation of 1-bromo-1,3-di-tert-alkylallenes, producing the first crystalline allene oxide of any kind. The epoxidations are regioselective for the bromine-bearing Δ1,2 alkene, and also face selective producing single diastereomer E-olefin products.
- Published
- 2016
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