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Stable bromoallene oxides
- Source :
- Chemical Communications. 52:11219-11222
- Publication Year :
- 2016
- Publisher :
- Royal Society of Chemistry (RSC), 2016.
-
Abstract
- The first stable bromoallene oxides were obtained by the DMDO epoxidation of 1-bromo-1,3-di-tert-alkylallenes, producing the first crystalline allene oxide of any kind. The epoxidations are regioselective for the bromine-bearing Δ1,2 alkene, and also face selective producing single diastereomer E-olefin products.
- Subjects :
- chemistry.chemical_classification
010405 organic chemistry
Chemistry
Alkene
Allene
Organic Chemistry
Metals and Alloys
Diastereomer
Oxide
Regioselectivity
General Chemistry
010402 general chemistry
01 natural sciences
Catalysis
0104 chemical sciences
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
chemistry.chemical_compound
Chemical Sciences
Materials Chemistry
Ceramics and Composites
Organic chemistry
Subjects
Details
- ISSN :
- 1364548X and 13597345
- Volume :
- 52
- Database :
- OpenAIRE
- Journal :
- Chemical Communications
- Accession number :
- edsair.doi.dedup.....12b451615e481ce273c82e3b36dfd7db
- Full Text :
- https://doi.org/10.1039/c6cc06395k