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1. Croton insularis introduces the seco-casbane class with EBC-329 and the first casbane endoperoxide EBC-324.

Author

Maslovskaya, Lidiya A., Pierce, Carly J., Parsons, Peter G., Savchenko, Andrei I., Krenske, Elizabeth H., Williams, Craig M., Gordon, Victoria A., and Reddell, Paul W.

Subjects
*CROTON (Genus), *BIOSYNTHESIS, *PLANT-microbe relationships & genetics, *HYDROGEN peroxide synthesis, *DENSITY functional theory, *NUCLEAR magnetic resonance spectroscopy, *NATURAL products
Abstract

Investigation of Croton insularis afforded the first in class seco-casbane diterpene, EBC-329. A highly oxidised casbane, EBC-324, was also isolated. The structural motif within EBC-324, which consists of an epoxidised hemi-acetal endoperoxide, is new to the casbane family. [ABSTRACT FROM AUTHOR]

Published
2014
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