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Croton insularis introduces the seco-casbane class with EBC-329 and the first casbane endoperoxide EBC-324.

Authors :
Maslovskaya, Lidiya A.
Pierce, Carly J.
Parsons, Peter G.
Savchenko, Andrei I.
Krenske, Elizabeth H.
Williams, Craig M.
Gordon, Victoria A.
Reddell, Paul W.
Source :
Chemical Communications. 2014, Vol. 50 Issue 82, p12315-12317. 3p.
Publication Year :
2014

Abstract

Investigation of Croton insularis afforded the first in class seco-casbane diterpene, EBC-329. A highly oxidised casbane, EBC-324, was also isolated. The structural motif within EBC-324, which consists of an epoxidised hemi-acetal endoperoxide, is new to the casbane family. [ABSTRACT FROM AUTHOR]

Subjects

Subjects :
*CROTON (Genus)
*BIOSYNTHESIS
*PLANT-microbe relationships & genetics
*HYDROGEN peroxide synthesis
*DENSITY functional theory
*NUCLEAR magnetic resonance spectroscopy
*NATURAL products

Details

Language :
English
ISSN :
13597345
Volume :
50
Issue :
82
Database :
Academic Search Index
Journal :
Chemical Communications
Publication Type :
Academic Journal
Accession number :
100188766
Full Text :
https://doi.org/10.1039/c4cc05413j
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