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We demonstrated an efficient extreme ultraviolet (EUV) source at a wavelength of 13.5 nm using spatially separated multiple solid-state-laser pulse irradiation. The maximum conversion efficiency (CE) achieved was 3.8% for ± 30 ° oblique laser pulse injection, which was about twice as high as that for single laser pulse irradiation of 1.7%, with an EUV source size of about 100 μm for two spatially separated laser pulses with a total laser energy of 500 mJ at a laser intensity of 2 × 10 11 W/cm2. In addition, we achieved an EUV CE of 4.7% for ± 60 ° oblique laser pulse injection, which was one of the highest values ever reported, in the case of a 1-μm solid-state laser-produced planar Sn target plasma by multiple laser pulse irradiation. This result suggests that multiple laser-pulse irradiation at high repetition rate operation could credibly provide the next technology for future high-power EUV sources and exposure tools toward future EUV technology nodes. [ABSTRACT FROM AUTHOR]

Terahertz radiation from laser plasmas exhibits a broadband spectrum, making it a bright prospect for terahertz spectroscopy. In this work, we demonstrate that the continuous redshift of terahertz radiation from a dc-biased plasma filament can be achieved by increasing the length of the plasma filament. A theoretical model concerning a Lorentz distribution of the plasma density along a filament is proposed to interpret this spectral tuning effect. This finding provides not only an approach to spectral tuning but also a gentle way of diagnosing the distribution of the plasma density inside such plasmas. [ABSTRACT FROM AUTHOR]

We demonstrated spectral control of beyond extreme ultraviolet (B-EUV) emission at a central wavelength of 6.76 nm from a gadolinium (Gd) laser-produced plasma. The highest spectral purity (SP) was 5.1% under dual 1-μm laser pulse irradiation. It doubled compared to a value of 2.4% attained under single laser pulse irradiation of solid density Gd because of the reduction in optical depth. The highest maximum SP was higher than that obtained using a mid-infrared laser at 10.6 μm. The SP for the 150-ps main laser was also higher than that for 6-ns main laser irradiation. Our approach can be extended to mid-infrared solid-state laser-produced plasmas (LPPs) using driving laser wavelengths ranging from 2 to 9 μm for efficient B-EUV source development. [ABSTRACT FROM AUTHOR]

Laser-assisted discharge-produced plasma (LDP) is one of the ways to generate extreme ultraviolet (EUV) light used in the semiconductor manufacturing processes. This light source uses a pulsed laser and a high-current pulsed electrical discharge to make a high-temperature and high-density tin plasma. One of two rotating disk electrodes, of which surfaces are coated by liquid tin (Sn), is irradiated by the laser to produce tin plasma. The plasma propagates from one electrode (cathode) to the other (anode) and ignites an electrical breakdown between the electrodes. The low-inductance circuit connected to the electrodes provides a current of approximately 15 kA and 150 ns to the tin plasma. The plasma implodes due to its own magnetic pressure, and EUV radiation is emitted from the resultant hot and dense plasma. High-speed ions are also emitted from the plasma and limit the lifetime of the mirror used to collect the EUV light. We need to maximize the light emission and minimize the ion emission. The role of the laser is essential in the LDP EUV source not only to ignite the discharge but also to condition the initial plasma. It influences EUV energy, EUV brightness, and emitted ion speed distribution of the plasma. The experiment suggested that laser intensity higher than 25 GW/cm2 produced high EUV brightness and low emitted ion speed. [ABSTRACT FROM AUTHOR]

We introduce a spectroscopic absorption imaging method in the UV regime (225–400 nm) to study tin vapor created by irradiating a thin film with a low intensity 108 W cm−2 nanosecond laser pulse, a case inspired by current developments around "advanced target shaping" in industrial laser-produced plasma sources for extreme ultraviolet light. The 4-ns-time-resolved, 10-μm-spatial-resolution images contain a 10-cm−1-resolution spectrum of the vapor in each pixel 100 ns after the vaporization. The images allow us to reveal a homogeneous temperature profile throughout the vapor of around 3000 K. We obtain a density map of the atoms (with a peak density of 5 × 1018 cm−3) and nanoparticles (1012 cm−3 for the best fitting 20 nm radius case), which both are shown to be present in the vapor. For each free atom, approximately three appear to be clustered in nanoparticles, and this composition is invariant over space and density. The density and temperature maps of the free atoms are combined to estimate the electron density (peaking at 1013 cm−3) in the vapor. [ABSTRACT FROM AUTHOR]

We demonstrate the efficient generation of extreme ultraviolet (EUV) light from laser-produced plasma (LPP) driven by 2 μm wavelength laser light as an alternative for 10 μm CO2 gas LPP currently employed in EUV lithography machines for high-volume manufacturing of semiconductor devices. High conversion efficiencies of laser light into "in-band" EUV photons up to 5.0% are achieved by homogeneously heating the plasma that is laser-generated from preshaped tin microdroplet targets. Scaling the laser pulse duration, spot size, and intensity yields a high in-band EUV energy output of up to 12.5 mJ. The EUV emission source size is studied under a similar parameter range and is shown to match typical etendues of EUV optic columns. Our findings make 2 μm LPP a particularly promising candidate to power future EUV nanolithography. [ABSTRACT FROM AUTHOR]

We present the results of joint measurements of electron density ( n e ), temperature ( T e ), and emission spectra of an Nd:YAG-driven tin plasma. Collective Thomson scattering provides space- and time-resolved n e and T e data during drive laser irradiation, and extreme ultraviolet (EUV) emission spectra, which is space-resolved in the target normal, are measured using a flat-field grazing incidence spectrometer (GIS). As the distance from the target increased, the emission intensity quickly decreases, and the peaks of the spectra gradually shift to longer wavelengths. This can be explained by the rapid decrease in n e , and thus, self-absorption, with an increase in distance. We obtain the EUV spectra by calculating the transfer of photons along the line-of-sight of the GIS, using theoretical emissivity and opacity, and applying the measured spatial distribution of n e and T e . The results quantitatively demonstrate that the self-absorption effect is significant; the emission from the core regions is mostly reabsorbed by the surrounding plasma. The calculated spectra are compared with the measured spectra. While good agreement is achieved in the spectral region of 13.3 and 15.3 nm, considerable differences are found in the 12.5–13 and 15.5–17.5 nm region. The results demonstrate the significance of this joint measurement for further validation of the atomic process model considering self-absorption effect, which is critical for the future high-density, solid laser-driven EUV source. [ABSTRACT FROM AUTHOR]

Advancements in state-of-the-art nanolithography technology over the past decade have been raising an ongoing demand for improvement of the power and efficiency of extreme-ultraviolet (EUV) light sources that stand at its heart. This study introduces a double-sided laser illumination scheme aimed at enhancing EUV emission from such a laser-produced Sn plasma source. Using a solid-state laser, experiments were conducted with suspended solid Sn targets of varying thicknesses, evaluating the resulting effect on EUV output intensity. A significant increase in EUV emission to the collection side was observed due to the addition of illumination of the other side, particularly for thinner targets. For targets with thicknesses of 60 and 20 nm, an increase between 50% and 150% in EUV emission was detected in comparison with single-sided illumination. Extrapolating to a long laser pulse that burns through the target, the enhancement is projected to be 17% for a 300 nm thick target. These results highlight a promising way for further improvement of output power and energy efficiency in next-generation EUV light sources. [ABSTRACT FROM AUTHOR]

Femtosecond laser-based terahertz (THz) sources have gained attention for their potential in various applications. As for any electromagnetic radiation, the wave polarization is a critical parameter, which needs to be under control in a wide class of those applications. However, characterizing the polarization of broadband THz pulses remains challenging due to their limited efficient optics. THz air-biased coherent detection has emerged as a promising candidate. The technique employed is heterodyne detection, utilizing second-harmonic generation induced by THz radiation in laser-induced air plasmas. This approach provides exceptional spectral bandwidth and an unbounded power detection limit, rendering it highly suitable for ultra-broadband and high-power THz sources. It enables a very efficient polarization measurement too. However, recent findings have revealed that the laser-induced air plasma generated in this technique can exhibit birefringence, which in turn adds systematic errors to the polarization-state determination. In this Letter, we propose a simplified approach that utilizes a weak probe beam and avoids high-voltage DC bias-fields. Unlike the terahertz (THz) air-biased coherent detection scheme, our approach yields a unipolar, intensity-proportional signal for second-harmonic generation. The experimental results reported in this Letter show the absence of induced birefringence in air and, hence, demonstrate accurate measurements of the polarization state of ultra-broadband THz pulses. Therefore, our technique may provide valuable results in applications where the polarization state, and not the full electric field waveform, is required for analysis or characterization. Finally, we discuss a possible application of our method to the emergent field of THz singular optics. [ABSTRACT FROM AUTHOR]

Next generation EUV sources for photolithography use light produced by laser-produced plasmas (LPP) from ablated tin droplets. A major challenge for extending the lifetime of these devices is mitigating damage caused by deposition of tin debris on the sensitive collection mirror. Especially difficult to stop are high energy (up to 10 keV) highly charged tin ions created in the plasma. Existing solutions include the use of stopping gas, electric fields, and magnetic fields. One common configuration consists of a magnetic field perpendicular to the EUV emission direction, but such a system can result in ion populations that are trapped rather than removed. We investigate a previously unconsidered mitigation geometry consisting of a magnetic null by performing full-orbit integration of the ion trajectories in an EUV system with realistic dimensions and optimize the coil locations for the null configuration. The magnetic null prevents a fraction of ions from hitting the mirror comparable to that of the perpendicular field, but does not trap any ions due to the chaotic nature of ion trajectories that pass close to the null. This technology can potentially improve LPP-based EUV photolithography system efficiency and lifetime and may allow for a different, more efficient formulation of buffer gas. [ABSTRACT FROM AUTHOR]

Laser-produced plasma sources of short-wavelength (1–20-nm) radiation are actively used nowadays in numerous applications, including water-window microscopy and extreme ultra-violet lithography. Suppression of laser-plasma debris (responsible for damaging optics) is crucial for the lifetime prolongation of optical systems operated with the short-wavelength radiation. Here, we examine the capability of single-walled carbon nanotube (SWCNT)-based membranes to decrease an InSn plasma flux containing both ions and atoms. Faraday cup measurements show that 40- and 90-nm-thick SWCNT membranes reduce the total charge transition by 20 and 130 times, respectively. The ion analyzer measurements demonstrate that ions pass through the membrane mainly due to the collisionless (ballistic) mechanism. Using scanning electron microscopy, we estimate a decrease in a plasma (ions + atoms) flux to be of 18 and 140 times for 40- and 90-nm-thick SWCNT-based membranes, respectively. The average plasma flux attenuation coefficient of SWCNT membranes is calculated as k = 0.063 nm − 1 . [ABSTRACT FROM AUTHOR]

Particulate matter air pollution in the form of ultrafine dust is a growing global concern. In this Letter, we will use a nanodusty Ar/HMDSO plasma as a model system for a heavily contaminated gas and we present the development of a technique for real-time in situ measurements of the dust particle size. The method is based on laser-induced photodetachment of bound electrons from the surface of dust particles. These photo-released electrons are measured as an increase in the free electron density of the plasma using microwave cavity resonance spectroscopy. We show that instead of reconstructing the entire resonance profile, the temporal response of a single microwave frequency was enough to perform the measurements. More specifically, the decay timescale of the cavity response can be interpreted as the re-charging timescale of the dust particles. Then, using a stochastic model, this timescale can be modeled, which eventually retrieves the dust particle size. We found good agreement between the predicted dust particle size and the average dust particle size obtained from ex situ scanning electron microscopy measurements. This method allows for the real-time monitoring of the dust particle size and a controlled production of nanometer-scale dust particles, which gives opportunities both for fundamental dusty plasma physics and models, as well as for applications in monitoring ultrafine dust air pollution. [ABSTRACT FROM AUTHOR]

Several recent experiments have demonstrated low-damage processing of 2D materials, such as graphene and single crystal diamond, using electron beam (e-beam) generated plasmas with applied crossed electric and magnetic (E × B) fields. The low damage of these sensitive materials is commonly attributed to the low energy of ions incident to the substrate surface and the ion confinement in E × B fields. In this work, measurements of atom and ion velocity distribution functions in an e-beam E × B plasma at sub-mTorr argon pressures using a laser-induced fluorescence diagnostic revealed the presence of a warm population of ions with temperatures of ∼ 1 eV that are sufficient to destroy the ion confinement in E × B fields and drive the ion flux by cross field diffusion in the direction opposite to the applied electric field, toward the plasma-bounded walls or substrate. Thus, it is this nearly ambipolar diffusion process that is responsible for the flux of charged particles impinging on the wall/substrate surface. [ABSTRACT FROM AUTHOR]

Gas optical emission enhanced by solid initiator (GENS) is designed to support the laser-induced breakdown spectroscopy (LIBS) technique for studying the impact of intense radiation beams on cultural heritage materials. GENS-LIBS generates plasma in the atmosphere using a metal target, which increases sensitivity while lowering laser irradiance. This method is designed to monitor gas emissions from ancient materials during intense radiation analysis, particularly under ion beam irradiation. The study focused on analyzing hydrogen gas emissions from lead white pigments mixed with linseed oil as a binder in paintings. The results show that the GENS-LIBS method has allowed us to quantify the hydrogen emission of lead white-containing paint layers exposed to 10 to 40 μC/cm2 of 3 MeV protons in a specially designed sealed cell. This technique permits the tracking of hydrogen and other light elements, such as oxygen and nitrogen, thus facilitating the follow-up of changes in the material composition of artworks. GENS-LIBS offers a promising method for safely analyzing and preserving valuable cultural heritage artifacts. [ABSTRACT FROM AUTHOR]

We have demonstrated angular distribution separation of the extreme ultraviolet (EUV) emission and suprathermal ions with a significant energy reduction for ions produced using dual pulse irradiation of a planar gadolinium (Gd) target. The pulse separation time between the pre-pulse and the main laser heating pulse was set at 30 ns, and the pre-plasma was irradiated at a distance of 50 μm above the target. Angular distributions of the EUV emission and the suprathermal ions were almost isotropic and followed a cos 4 θ distribution, respectively. The suprathermal ions were emitted normal to the target along the pre-pulse laser axis. The most probable energy of the suprathermal ions was less than 2 keV, while their maximum charge state was Gd6+ with the pre-plasma, compared to an energy of about 10 keV with a maximum charge state Gd15+ without the pre-plasma. The results suggest that the collector mirror position may be chosen to achieve a long lifetime, by avoiding damage from fast ion collisions. [ABSTRACT FROM AUTHOR]

Laser-induced liquid plasma is expected to be an efficient medium for a new generation of terahertz (THz) devices. However, the mechanism of interaction between liquid plasma and THz waves is currently unclear. Here, we observed two phenomena related to THz wave interaction with water plasma: THz-induced second harmonic (TISH) radiation in water plasma and THz absorption by water plasma. We established an internal relationship between these two macroscopic phenomena by utilizing a photocurrent model and the Drude model. Using liquid water and air as examples, a scheme is proposed to analyze the photonic characteristics of plasma in different physical states. This study offers an experimental basis for predicting the TISH phenomenon across various substances and states and also provides the theoretical support for the practical implementation of liquid-based detection of THz waves. [ABSTRACT FROM AUTHOR]

One of the critical issues in lithography using extreme ultraviolet (EUV) light is tin contamination of the EUV collector mirrors in the tin-based LPP-EUV light source. The contamination can be removed by the reaction of tin atoms with hydrogen radicals producing stannane (SnH4), which is gaseous at the normal temperature. Hydrogen radicals can be produced from hydrogen molecules through photo-dissociation and photo-ionization induced by broadband radiation emitted from the EUV light source. In this work, an efficient production of hydrogen radical using vacuum ultraviolet (VUV) light emitted from laser-produced high-Z plasma is experimentally demonstrated. A two-dimensional radiation hydrodynamic simulation, coupled with photoionization and photo-dissociation cross sections, also shows the efficient hydrogen radical production by increased VUV light emission, as observed in the experiment. [ABSTRACT FROM AUTHOR]

The radio-frequency power radiated from laser-target plasmas in a vacuum can be orders of magnitude greater than expected from such sources that have a negligible electric dipole moment. A model combining the Tidman–Stamper circuit model of a laser-target plasma with the theory of radiation from currents immersed in plasmas, however, predicts scaling of electric-dipole power radiated from laser plasmas in agreement with experiments. [ABSTRACT FROM AUTHOR]

Strong-field terahertz (THz) light-matter interaction provides various nonlinear control approaches in condensed matter physics, energy and material sciences, electron acceleration, and manipulation. Recently developed spintronic THz emission with minimum complexities has been demonstrated to have the capability for generating high field strengths. Up to now, nonlinear applications based on the spintronic THz transients have yet been realized. Here, we report THz emission from two-color femtosecond laser plasma filaments modulated by a 60-kV/cm THz pulse from W/CoFeB/Pt heterostructures. Enhanced THz radiation based on electron acceleration in plasma is recorded when the direction of the spintronic THz modulating field is in line with that of the electron movement. This behavior is quantitatively reproduced by a local current model of the plasma THz source. Our experimental and theoretical results may inspire further nonlinear THz investigation and accelerate ultrafast THz engineering in matter. [ABSTRACT FROM AUTHOR]

We report experiments exhibiting specific features in generating hard x rays with femtosecond laser plasmas as relativistic intensities are approached. Copper foils are irradiated with 1-J/130-fs Ti:sapphire laser pulses, and the x rays are detected with spatial resolution. The results demonstrate a dramatic reduction in the x-ray-emitting spot size at intensities around 10[sup 19] W/cm², and a corresponding increase in the x-ray flux density. These findings are explained in terms of forward acceleration of electrons due to relativistic effects. [ABSTRACT FROM AUTHOR]

Manipulation and patterning of diamond surface chemistry is of interest for a wide range of diamond-based technologies. We report the patterned oxidation of hydrogen-terminated diamond surfaces with sub-monolayer (ML) precision by a deep-UV two-photon process performed in air. Using focused laser pulses of photon energy 4.66 eV (266 nm; below the diamond bandgap of 5.47 eV), hydrogen-terminated (001) surfaces were exposed with calibrated doses to remove carbon with a precision of 0.02 ML. The measurement of the electrical properties of the laser-exposed zone between ohmic electrodes enabled monitoring of the transition from a conducting H-terminated surface to insulating O-terminated. The surface resistance increases by more than 7 orders of magnitude for doses corresponding to 0.5 ML, and the I–V characteristics show a transition from linear to nonlinear for doses above 0.30 ML. We show that this behavior agrees well with a surface percolation model for carrier diffusion in which the laser etch rate for the H-terminated top layer is the same as for O-terminated. Hence, this work reveals an ultra-precise method for modifying the sub-monolayer surface chemistry with the practical advantages of a laser-induced mechanism compared to conventional plasma or chemical processing methods. [ABSTRACT FROM AUTHOR]

Examines the high conversion efficiency generation of kiloelectron volt x-ray from copper and iron targets using krypton fluoride laser plasmas. Determination of conversion efficiencies using aberration corrected focal length lens; Difference in x-ray responsivity for each target materials; Saturation of conversion efficiency at high total energies.

We report on a hybrid optoacoustic method aimed to retrieve the three-dimensional spatial distributions of the plasma electron density and the deposited energy density in the region of plasma formation under optical breakdown in condensed medium. The spatial distribution of the plasma electron density obtained by the proposed method with the accuracy of 3 × 1 0 18 c m − 3 gives the qualitative characterization of the laser pulse propagation in the region of plasma formation. The spatial distribution of the deposited energy density retrieved by the proposed method with the accuracy of 14 J / c m 3 provides the quantitative description of the laser impact on the bulk of the medium. The method is based on photoacoustic imaging and shadowgraphy techniques, which have the spatial resolution of 2 μ m and 10 μ m , respectively. The proposed method can be applied both in the area of technological applications, such as micromachining of transparent materials, and in the field of the fundamental science of laser–matter interaction. [ABSTRACT FROM AUTHOR]

A compact low-energy and high-intensity electron source for material aging applications is presented. A laser-induced plasma moves inside a 30 kV diode and produces a 5 MW electron beam at the anode location. The corresponding dose that can be deposited into silicon or gallium samples is estimated to be 25 kGy per laser shot. The dose profile strongly depends on the cathode voltage and can be adjusted from 100 nm to 1 μm. With this versatile source, a path is opened to study micro- or nano-electronic components under high irradiation, without the standard radioprotection issues. [ABSTRACT FROM AUTHOR]

High-voltage laser-triggered switches (HV-LTSs) are used in pulsed-power applications where low jitter and precise timing are required. The switches allow operation in the megaampere, megavolt regime while maintaining low insertion losses. Currently, there is a lack of detailed plasma measurements in these switches, yet such measurements are needed to elucidate the detailed physics, which include a range of processes such as laser breakdown, streamer formation and growth, current flow, plasma evolution, and cooling. Detailed spatially- and temporally resolved measurements of plasma properties within the switches could contribute to validating and advancing numeric models of these systems. This contribution presents laser Thomson scattering measurements of the electron number density and temperature evolution in a HV-LTS. The switch was operated at 6 kV with current flow for a duration of 145 ns and a peak current density of 0.2 MA/cm2 into a matched load. The Thomson scattering diagnostic system uses a 532 nm probe from an Nd:YAG laser allowing a temporal resolution of ∼10 ns. We find that during the switch current pulse, the plasma electron temperature rose from a starting value of 8.1 ± 1.6 eV (due to cooling of the earlier trigger laser plasma) to a peak value of 26 ± 5 eV with an associated increase in the electron density from 8.6 ± 1.7 × 1017 to 3.1 ± 0.6 × 1018 cm−3. [ABSTRACT FROM AUTHOR]

Experimental scaling relations of the optical depth are presented for the emission spectra of a tin-droplet-based, 1-μm-laser-produced plasma source of extreme-ultraviolet (EUV) light. The observed changes in the complex spectral emission of the plasma over a wide range of droplet diameters (16–65 μm) and laser pulse durations (5–25 ns) are accurately captured in a scaling relation featuring the optical depth of the plasma as a single, pertinent parameter. The scans were performed at a constant laser intensity of 1.4 × 1011 W/cm2, which maximizes the emission in a 2% bandwidth around 13.5 nm relative to the total spectral energy, the bandwidth relevant for industrial EUV lithography. Using a one-dimensional radiation transport model, the relative optical depth of the plasma is found to linearly increase with the droplet size with a slope that increases with the laser pulse duration. For small droplets and short laser pulses, the fraction of light emitted in the 2% bandwidth around 13.5 nm relative to the total spectral energy is shown to reach high values of more than 14%, which may enable conversion efficiencies of Nd:YAG laser light into—industrially—useful EUV radiation rivaling those of current state-of-the-art CO2-laser-driven sources. [ABSTRACT FROM AUTHOR]

Laser ionized liquid has been considered as a promising broadband terahertz (THz) source recently. The ponderomotive force induced dipole model can be used to describe the mechanism of THz generation, implying that the lateral THz emission is stronger than the forward emission. Thus, we systemically investigate the lateral THz emission from laser induced plasma in liquid water line. THz energy about 4.4-times of that from the forward emission is achieved from the lateral emission scheme. Results on the angular distribution of coherent THz radiation indicate that the maximal THz radiation falls between 120° and 150° with respect to the pump laser propagation direction. Moreover, dependence of collected THz energy on the relative position between laser focus and the water line shows a counterintuitive "two peaks" trend, which can be explained by the impact of cylindrical water surface on the divergence angle of the generated THz wave. Therefore, the enhancement in THz energy can be attributed to the high-efficiency lateral collection scheme and the tradeoff between the THz wave converging effect of the cylindrical surface and the absorption in water. Our work helps to further optimize the coupling efficiency of generated THz wave out of liquid samples. [ABSTRACT FROM AUTHOR]

A novel proton imaging technique was applied which allows a continuous temporal record of electric fields within a time window of several nanoseconds. This “proton streak deflectometry” was used to investigate transient electric fields of intense (∼1017 W/cm2) laser irradiated foils. We found out that these fields with an absolute peak of up to 108 V/m extend over millimeter lateral extension and decay at nanosecond duration. Hence, they last much longer than the (approximately picosecond) laser excitation and extend much beyond the laser irradiation focus. [ABSTRACT FROM AUTHOR]

We report on a waveform control of enhanced THz radiation along a femtosecond laser filament in air with a high voltage technique. By applying a DC high-voltage electric field from two sharp electrodes in a direction parallel to the laser filament and scanning it along the filament, the longitudinal evolution of amplified THz emission was demonstrated. By changing the position of the pair of electrodes along the laser filament, different waveforms of THz radiation were obtained. Due to the change of the plasma density distribution at the leading and trailing ends of a laser filament, the enhanced THz waveforms could have a phase shift of ∼π. The technique is very simple. It could help to understand the THz generation process through external electric field assisted laser filamentation. [ABSTRACT FROM AUTHOR]

Axial focusing arrangement effects on collinear dual-pulse laser-induced breakdown spectroscopy (DP-LIBS) in a bulk solution were investigated by spectra and fast images. By properly defocusing the second laser pulse beyond the first laser formed bubble (LFB), brighter and larger plasmas could be produced due to higher breakdown efficiency and higher expansion efficiency. It is attributed to a distinct mechanism of underwater DP-LIBS that the plasma mostly forms at the bubblewater interface and then expands into the gaseous LFB. The results show that optimization of the axial focusing arrangement in underwater collinear DP-LIBS enables significant emission enhancements with relatively low laser energies. [ABSTRACT FROM AUTHOR]

We experimentally demonstrate that the interaction between plasma and nanometer-sized semiconductor quantum dots (QDs) is directly connected to a change in their photoluminescence (PL) spectrum. This is done by taking in situ, high resolution, and temporally resolved spectra of the light emitted by laser-excited QDs on an electrically floating sample exposed to a low pressure argon plasma. Our results show a fast redshift of the PL emission peak indicating the quantum-confined Stark effect due to plasma-generated excess charges on the substrate and near the QD surface, while other plasma-induced (thermal and ion) effects on longer timescales could clearly be distinguished from these charging effects. The presented results and method open up pathways to direct visualization and understanding of fundamental plasma–particle interactions on nanometer length scales. [ABSTRACT FROM AUTHOR]

Based on theoretical predictions on the appearance of antibunching before the laser threshold at the nano- and microscale, we analyze the amount of photon-number squeezing naturally produced in the laser emission. Up to 3 dB photon number noise reduction is obtained in comparison with the coherent emission, with output power in the range of pW and with negligible effects due to pump fluctuations. The scheme requires a moderately high Q cavity and holds promise for the construction of a simple and effective photon-number squeezed source. [ABSTRACT FROM AUTHOR]

Laser focusing geometry effects on plasma emissions in bulk water were investigated with five focusing angles ranging from 11.9° to 35.4°. Fast imaging and space-resolved spectroscopy techniques were used to observe the plasma emission distributions and fluctuations. We demonstrated that by increasing the focusing angle, discrete and irregular plasma formed in multiple sites could be turned into continuous and stable plasma with single core fixed at the laser focal point. This indicates the key role of laser focusing angle in the stabilization of plasma positions, which is crucial to the improvement of laser-induced breakdown spectroscopy repeatability in bulk water. [ABSTRACT FROM AUTHOR]

With the help of adapted off-axis reflection zone plates, near edge X-ray absorption fine structure spectra at the C and N K-absorption edge have been recorded using a single 1.2 ns long soft X-ray pulse. The transmission experiments were performed with a laser-produced plasma source in the laboratory rendering time resolved measurements feasible independent on large scale facilities. A resolving power of E/ΔE~950 at the respective edges could be demonstrated. A comparison of single shot spectra with those collected with longer measuring time proves that all features of the used reference samples (silicon nitrate and polyimide) can be resolved in 1.2 ns. Hence, investigations of radiation sensitive biological specimen become possible due to the high efficiency of the optical elements enabling low dose experiments. [ABSTRACT FROM AUTHOR]

Betatron-type laser-plasma x-rays are recorded simultaneously with their corresponding relativistic electron spectra in a laser wakefield acceleration scheme. The role of the multi-electron gas target in the betatron-type x-ray efficient generation is experimentally examined. A proof of principle experimental study shows that by using a multi-electron gas target and appropriately adjusting the pumping laser intensity an increase in betatron-type x-rays efficiency could be achieved. This is attributed to sophisticated control of the type of the electron injection inside the plasma bubble related to the tunneling ionization process occurring after the laser pulse peak. This method depends primarily on the gas target charge state chosen for attaining the ionization injection scheme and could be extended to a wide range of relativistic laser intensities. [ABSTRACT FROM AUTHOR]

A compact low-energy and high-intensity x-ray source for radiation biology applications is presented. A laser-induced plasma moves inside a 30 kV diode and produces a beam of 1014 electrons at the anode location. An aluminum foil converts a part of the energy of these electrons into x-ray photons, which are characterized using filtered imaging plates. The dose that would be deposited by these x-ray photons in C. elegans larvae is calculated from Geant4 simulations. It can be set to a value ranging between 10 μGy and 10 mGy per laser shot by simply changing the aluminum foil thickness and the diode voltage. Therefore, this versatile and compact x-ray source opens a new path to explore the radiation effects induced by dose rates varying over several orders of magnitude. [ABSTRACT FROM AUTHOR]

The correlation between the laser absorption and the conversion efficiency (CE) for 13.5 nm extreme ultraviolet (EUV) light in a laser-produced tin plasma was investigated. The absorption rate a and the CE were measured simultaneously for a laser-pre-formed low-density tin target as a function of the time delay between the pre-pulse and the main laser pulse. A clear and positive correlation between a and CE was found with increasing delay time; however, the CE decreases rapidly at longer delay times. This result is partly attributed to a reduction in the absorption rate, but is mainly attributed to the self-absorption of EUV light in excessively long-scale plasmas. [ABSTRACT FROM AUTHOR]

Time-resolved emission and scattering imaging are employed to analyze the ablation mechanisms of silver thin films induced by femtosecond laser irradiation of Gaussian intensity profile under different laser fluences and gas background pressures. At fluences near the ablation threshold, nanoparticles (NPs) of 40 nm–100 nm in size are ejected in the vertical direction from the target sample. The average ejection speed of these NPs increases with the laser fluence and also as the background gas pressure drops from ambient atmospheric to ∼10−5 Torr. At higher fluences, a plume is formed at the center of the laser beam and NPs are released in oblique trajectories from the peripheral area of the laser-irradiated spot. [ABSTRACT FROM AUTHOR]

Electron paramagnetic resonance (EPR) is used to experimentally determine the (0/−) level of the Mg acceptor in an Mg-doped β-Ga2O3 crystal. Our results place this level 0.65 eV (±0.05 eV) above the valence band, a position closer to the valence band than the predictions of several recent computational studies. The crystal used in this investigation was grown by the Czochralski method and contains large concentrations of Mg acceptors and Ir donors, as well as a small concentration of Fe ions and an even smaller concentration of Cr ions. Below room temperature, illumination with 325 nm laser light produces the characteristic EPR spectrum from neutral Mg acceptors (M g G a 0 ). A portion of the singly ionized Ir4+ donors are converted to their neutral Ir3+ state at the same time. For temperatures near 250 K, the photoinduced EPR spectrum from the neutral M g G a 0 acceptors begins to decay immediately after the laser light is removed, as electrons are thermally excited from the valence band to the Mg acceptor. Holes left in the valence band recombine with electrons at the deeper Ir3+ ions and restore the Ir4+ ions. An activation energy for the thermal decay of the M g G a 0 acceptors, and thus a value for the (0/−) level, is obtained by using a general-order kinetics model to analyze a set of five isothermal decay curves taken at temperatures between 240 and 260 K. [ABSTRACT FROM AUTHOR]

Colliding plasmas produced by neodymium-doped yttrium aluminium garnet (Nd:YAG) laser illumination of tin wedge targets form stagnation layers, the physical parameters of which can be controlled to optimise coupling with a carbon dioxide (CO2) heating laser pulse and subsequent extreme ultraviolet (EUV) production. The conversion efficiency (CE) of total laser energy into EUV emission at 13.5 nm61% was 3.6%. Neglecting both the energy required to form the stagnation layer and the EUV light produced before the CO2 laser pulse is incident results in a CE of 5.1% of the CO2 laser energy into EUV light. [ABSTRACT FROM AUTHOR]

We present observations of intense beams of energetic negative hydrogen ions and fast neutral hydrogen atoms in intense (5 × 1019 W/cm2) laser plasma interaction experiments, which were quantified in numerical calculations. Generation of negative ions and neutral atoms is ascribed to the processes of electron capture and loss by a laser accelerated positive ion in the collisions with a cloud of droplets. A comparison with a numerical model of charge exchange processes provides information on the cross section of the electron capture in the high energy domain. [ABSTRACT FROM AUTHOR]

We investigated the role of ambient gas pressure on the expansion and the emission features during ultrafast laser ablation of metal target. Plasma plumes were generated using 800 nm, 40 fs laser pulses on a copper target and the ambient air pressure was varied more than seven orders (1 × 10-5 - 760 Torr) of magnitude. Fast-gated images showed a complex interaction between the plume and ambient leading to changes in the plume geometry with pressure as well as time. The ambient pressure levels are found to affect both the line intensities and broadening along with signal to noise (S/N) and signal to background (S/B) ratios. The optimum pressure condition for analytical applications is found to be ∼100 Torr. [ABSTRACT FROM AUTHOR]

Dynamic return currents and electromagnetic field structure in laser-generated Z-pinch plasmas have been measured using proton deflectometry. Experiments were modeled to accurately interpret deflections observed in proton radiographs. Current flow is shown to begin on axis and migrate outwards with the expanding coronal plasma. Magnetic field strengths of ∼1 T are generated by currents that increase from ∼2 kA to ∼7 kA over the course of the laser pulse. Proton deflectometry has been demonstrated to be a practical alternative to other magnetic field diagnostics for these types of plasmas. [ABSTRACT FROM AUTHOR]

We demonstrate a table-top broadband emission water window source based on laser-produced high-Z plasmas. Resonance emission from multiply charged ions merges to produce intense unresolved transition arrays (UTAs) in the 2-4 nm region, extending below the carbon K edge (4.37 nm). Arrays resulting from n=4-n=4 transitions are overlaid with n=4-n=5 emission and shift to shorter wavelength with increasing atomic number. An outline of a microscope design for single-shot live cell imaging is proposed based on a bismuth plasma UTA source, coupled to multilayer mirror optics. [ABSTRACT FROM AUTHOR]

Hafnia is a high refractive index material used in the manufacturing of dielectric coatings for next generation lasers. The formation of defects during deposition is the major barrier to realizing high laser-damage resistant coatings for future high energy density laser applications. Understanding the precursors responsible for laser-induced damage in hafnia is therefore critical. In this work, we investigate the mechanism of laser-induced damage in 90-nm thick hafnia films produced by an oxygen assisted dual ion beam sputtering (IBS) process. Under pulsed, nanosecond ultraviolet laser exposure (355 nm, 8 ns), the laser-induced damage onset is found to be strongly dependent on the amount of argon and excessive oxygen entrapped in the nanobubbles within the hafnia films. The presence of nanobubbles is revealed and confirmed by small angle X-ray scattering and scanning/transmission electron microscopy coupled with high-angle annular dark-field. The damage onset is stable initially but decreases as the energy of oxygen goes beyond 100 eV. The damage initiation is ascribed to a laser-induced plasma generation within the nanobubbles through multiphoton ionization. The results reveal that nanobubbles formed in the IBS produced coatings are a potent precursor. Although nanobubbles are commonly present in IBS films, their negative impact on laser damage resistance of hafnia films has not been previously recognized. Our findings provide a fundamental basis for the development of potential mitigation strategies required for the realization of laser damage resistant hafnia films. [ABSTRACT FROM AUTHOR]

Laser-induced plasma formation and subsequent relaxation in dielectric solids is the precursor to structural modifications serving as the basis for direct laser writing of functional optical micro- and nanostructures. Based on an experimental arrangement combining a time-resolved transmission measurement with a cross-phase modulation measurement, we isolate the plasma formation and relaxation dynamics in the bulk of amorphous fused silica excited by femtosecond short-wavelength infrared (λ = 2100 nm) laser pulses. Whereas the relaxation time of the generated subcritical electron-hole plasma was so far assumed to be constant, our findings indicate an intensity-dependent relaxation time. We attribute this intensity dependence to vibrational activation of the medium, leading to detrapping of trapped carriers and a reduced trapping probability. [ABSTRACT FROM AUTHOR]