1. Exploiting Non-Innocent Ligands to Prepare Masked Palladium(0) Complexes
- Author
-
Ruth Edge, Philip W. Dyer, Karine Costuas, Andrei S. Batsanov, Jean Frangois Halet, Dan Smith, Judith A. K. Howard, David C. Apperley, David Collison, Department of Chemistry, Durham University, Institut des Sciences Chimiques de Rennes (ISCR), Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA), Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), and Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)
- Subjects
Stereochemistry ,chemistry.chemical_element ,[CHIM.INOR]Chemical Sciences/Inorganic chemistry ,010402 general chemistry ,01 natural sciences ,Redox ,Catalysis ,Coordination complex ,chemistry.chemical_compound ,N ligands ,redox reactions ,Bimetallic strip ,chemistry.chemical_classification ,010405 organic chemistry ,Ligand ,non-innocent ligands ,General Medicine ,General Chemistry ,palladium ,Combinatorial chemistry ,Non-innocent ligand ,3. Good health ,0104 chemical sciences ,[CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistry ,chemistry ,Chlorobenzene ,coordination chemistry ,Palladium - Abstract
International audience; Reaction of [PdMe2(tmeda)] with pyridyl-N-di(tert-butyl)phosphinoimine spontaneously affords an unusual bimetallic palladium(I) ligand-based biradical complex, which behaves as a "masked" form of Pd0 in its reactions with neutral ligands and chlorobenzene.
- Published
- 2010