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Exploiting Non-Innocent Ligands to Prepare Masked Palladium(0) Complexes
- Source :
- Angewandte Chemie International Edition, Angewandte Chemie International Edition, Wiley-VCH Verlag, 2010, 49 (39), pp.7040-7044. ⟨10.1002/anie.201003946⟩, Angewandte Chemie International Edition, 2010, 49 (39), pp.7040-7044. ⟨10.1002/anie.201003946⟩
- Publication Year :
- 2010
- Publisher :
- Wiley, 2010.
-
Abstract
- International audience; Reaction of [PdMe2(tmeda)] with pyridyl-N-di(tert-butyl)phosphinoimine spontaneously affords an unusual bimetallic palladium(I) ligand-based biradical complex, which behaves as a "masked" form of Pd0 in its reactions with neutral ligands and chlorobenzene.
- Subjects :
- Stereochemistry
chemistry.chemical_element
[CHIM.INOR]Chemical Sciences/Inorganic chemistry
010402 general chemistry
01 natural sciences
Redox
Catalysis
Coordination complex
chemistry.chemical_compound
N ligands
redox reactions
Bimetallic strip
chemistry.chemical_classification
010405 organic chemistry
Ligand
non-innocent ligands
General Medicine
General Chemistry
palladium
Combinatorial chemistry
Non-innocent ligand
3. Good health
0104 chemical sciences
[CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistry
chemistry
Chlorobenzene
coordination chemistry
Palladium
Subjects
Details
- ISSN :
- 14337851 and 15213773
- Volume :
- 49
- Database :
- OpenAIRE
- Journal :
- Angewandte Chemie International Edition
- Accession number :
- edsair.doi.dedup.....1d28892ae5f8bea0b7a320fe1aeeb686