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The water content is crucial to the preparation of [P4442][Suc] and its capture of CO2. The use of a large amount of water in the preparation of this ionic liquid results in the significant formation of the byproduct succinamate anions and difficulties in water removal, which strongly reduces the capacity of CO2 absorption through a bicarbonate mechanism. By contrast, the addition of a small amount of water maintains a high absorption capacity through cooperation. [ABSTRACT FROM AUTHOR]

A novel strategy based on the concept of preorganization and cooperation has been designed for a superior capacity to capture low-concentration CO2 by imide-based ionic liquids. By using this strategy, for the first time, an extremely high gravimetric CO2 capacity of up to 22 wt % (1.65 mol mol−1) and excellent reversibility (16 cycles) have been achieved from 10 vol. % of CO2 in N2 when using an ionic liquid having a preorganized anion. Through a combination of quantum-chemical calculations and spectroscopic investigations, it is suggested that cooperative interactions between CO2 and multiple active sites in the preorganized anion are the driving force for the superior CO2 capacity and excellent reversibility. [ABSTRACT FROM AUTHOR]