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Start Over Author "Sambasivan R" Journal angewandte chemie international ed in english

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1. Screening rhodium metallopeptide libraries "on bead": asymmetric cyclopropanation and a solution to the enantiomer problem.

Author

Sambasivan R and Ball ZT

Subjects
Amino Acid Sequence, Catalysis, Stereoisomerism, Cyclopropanes chemistry, Metalloproteins chemistry, Rhodium chemistry
Abstract

Searching with a beady eye: A high-throughput, on-bead screen of rhodium metallopeptide catalysts was developed in a 96-well format for asymmetric cyclopropanation. Different sequences of natural L-amino acids have been identified that produce opposite product enantiomers. In addition to styrene derivatives, high enantioselectivity is observed for vinyl ether and vinyl amine derivatives., (Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)

Published
2012
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