1. Evaluation of leaching efficiency in extracting calcium from Iraqi rocks using hydrochloric acid.
- Author
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Hussein, Farah Adil Abdul, Fadhil, Amjad Ibrahim, and Hussein, Samar Saadi
- Abstract
In this study, the rocks of the Fatha Formation in the Zurbatiyah district were studied from a mineralogical standpoint, through the extraction of calcium from its ores were represented by hydrated calcium sulfate (gypsum rocks) and calcium carbonate (limestone) by leaching process in HCl presence. Twenty experiment tests were conducted for both gypsum and limestone samples. The effects of particle size distribution and acid concentration on extraction efficiency were studied. Different particles sizes (225, 125, 75, 63, and 53) μm, and two concentrations of hydrochloric acid (2, 4) M were used for extraction. X-ray diffraction results showed that the gypsum rocks are of high purity, and the carbonate rocks are dolomitic limestone. Electron microscopic examination confirmed that the gypsum rocks are high-purity crystals of multiple shapes, while the limestone contains crystals of calcite and dolomite, as well as small percentages of gypsum. The results of the experiments work showed the efficiency of hydrochloric acid in extracting calcium\, but it was more effective in extraction calcium from gypsum rocks compared with limestone rocks. The percentage of extracted calcium from gypsum rocks was up to (90.6%), while the extracted calcium to (38.2%) in limestone rocks. It was also found that increasing the concentration of the acid solution led to a significant increase in the efficiency of the process in gypsum rocks. Also, new correlations with high reliability have been created between particles size and leaching percentage for both types of rocks. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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