1. Low temperature synthesis of Li and Cl added Bi-2212 superconductors.
- Author
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Noro, Masaki, Andoh, Hiroya, Murotani, Hideaki, Sugiura, Touko, and Tsukamoto, Takehiko
- Subjects
COPPER oxide superconductors ,LOW temperatures ,INORGANIC synthesis ,CHEMICAL sample preparation ,HEATING ,PERCHLORATES - Abstract
Abstract: Low temperature synthesis of Bi2Sr2CaCu2Oy (Bi-2212) bulk superconductors has been achieved by the addition of lithium (Li) and chlorine (Cl). The samples were prepared by a solid-state reaction method. The samples with nominal composition Bi2.12Sr1.90Ca1.02Cu1.96LixClxOy (0 ≤x ≤ 0.3) were heated in air at temperatures ranged from 700 to 780°C. The lithium perchlorate (LiClO4) addition (x≥0.05) promotes the formation of the Bi-2212 phase in low temperature synthesis. The Bi-2212 sample (Tc=78K) was obtained for x=0.15 by heating even at 720°C, which is about 100°C lower than that of the non-doped 2212 phase. [Copyright &y& Elsevier]
- Published
- 2012
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