155,242 results
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2. A fully-automated paper ECG digitisation algorithm using deep learning.
- Author
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Wu, Huiyi, Patel, Kiran Haresh Kumar, Li, Xinyang, Zhang, Bowen, Galazis, Christoforos, Bajaj, Nikesh, Sau, Arunashis, Shi, Xili, Sun, Lin, Tao, Yanda, Al-Qaysi, Harith, Tarusan, Lawrence, Yasmin, Najira, Grewal, Natasha, Kapoor, Gaurika, Waks, Jonathan W., Kramer, Daniel B., Peters, Nicholas S., and Ng, Fu Siong
- Subjects
DEEP learning ,ELECTROCARDIOGRAPHY ,ELECTRONIC paper ,ATRIAL fibrillation ,ALGORITHMS ,HEART failure ,HEART rate monitors - Abstract
There is increasing focus on applying deep learning methods to electrocardiograms (ECGs), with recent studies showing that neural networks (NNs) can predict future heart failure or atrial fibrillation from the ECG alone. However, large numbers of ECGs are needed to train NNs, and many ECGs are currently only in paper format, which are not suitable for NN training. We developed a fully-automated online ECG digitisation tool to convert scanned paper ECGs into digital signals. Using automated horizontal and vertical anchor point detection, the algorithm automatically segments the ECG image into separate images for the 12 leads and a dynamical morphological algorithm is then applied to extract the signal of interest. We then validated the performance of the algorithm on 515 digital ECGs, of which 45 were printed, scanned and redigitised. The automated digitisation tool achieved 99.0% correlation between the digitised signals and the ground truth ECG (n = 515 standard 3-by-4 ECGs) after excluding ECGs with overlap of lead signals. Without exclusion, the performance of average correlation was from 90 to 97% across the leads on all 3-by-4 ECGs. There was a 97% correlation for 12-by-1 and 3-by-1 ECG formats after excluding ECGs with overlap of lead signals. Without exclusion, the average correlation of some leads in 12-by-1 ECGs was 60–70% and the average correlation of 3-by-1 ECGs achieved 80–90%. ECGs that were printed, scanned, and redigitised, our tool achieved 96% correlation with the original signals. We have developed and validated a fully-automated, user-friendly, online ECG digitisation tool. Unlike other available tools, this does not require any manual segmentation of ECG signals. Our tool can facilitate the rapid and automated digitisation of large repositories of paper ECGs to allow them to be used for deep learning projects. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
3. A Machine Learning Model to Predict Citation Counts of Scientific Papers in Otology Field.
- Author
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Alohali, Yousef A., Fayed, Mahmoud S., Mesallam, Tamer, Abdelsamad, Yassin, Almuhawas, Fida, and Hagr, Abdulrahman
- Subjects
DECISION trees ,SERIAL publications ,NATURAL language processing ,BIBLIOMETRICS ,MACHINE learning ,REGRESSION analysis ,RANDOM forest algorithms ,CITATION analysis ,DESCRIPTIVE statistics ,PREDICTION models ,ARTIFICIAL neural networks ,MEDICAL research ,MEDICAL specialties & specialists ,ALGORITHMS - Abstract
One of the most widely used measures of scientific impact is the number of citations. However, due to its heavy-tailed distribution, citations are fundamentally difficult to predict but can be improved. This study was aimed at investigating the factors and parts influencing the citation number of a scientific paper in the otology field. Therefore, this work proposes a new solution that utilizes machine learning and natural language processing to process English text and provides a paper citation as the predicted results. Different algorithms are implemented in this solution, such as linear regression, boosted decision tree, decision forest, and neural networks. The application of neural network regression revealed that papers' abstracts have more influence on the citation numbers of otological articles. This new solution has been developed in visual programming using Microsoft Azure machine learning at the back end and Programming Without Coding Technology at the front end. We recommend using machine learning models to improve the abstracts of research articles to get more citations. [ABSTRACT FROM AUTHOR]
- Published
- 2022
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4. Efficient and Effective Academic Expert Finding on Heterogeneous Graphs through (k, P)-Core based Embedding.
- Author
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YUXIANG WANG, JUN LIU, XIAOLIANG XU, XIANGYU KE, TIANXING WU, and XIAOXUAN GOU
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COMMUNITIES ,SEMANTICS ,ALGORITHMS - Abstract
Expert finding is crucial for a wealth of applications in both academia and industry. Given a user query and trove of academic papers, expert finding aims at retrieving the most relevant experts for the query, from the academic papers. Existing studies focus on embedding-based solutions that consider academic papers’ textual semantic similarities to a query via document representation and extract the top-n experts from the most similar papers. Beyond implicit textual semantics, however, papers’ explicit relationships (e.g., co-authorship) in a heterogeneous graph (e.g., DBLP) are critical for expert finding, because they help improve the representation quality. Despite their importance, the explicit relationships of papers generally have been ignored in the literature. In this article, we study expert finding on heterogeneous graphs by considering both the explicit relationships and implicit textual semantics of papers in one model. Specifically, we define the cohesive (k, P)-core community of papers w.r.t. a meta-path P (i.e., relationship) and propose a (k, P)-core based document embedding model to enhance the representation quality. Based on this, we design a proximity graph-based index (PGIndex) of papers and present a threshold algorithm (TA)-based method to efficiently extract top-n experts from papers returned by PG-Index. We further optimize our approach in two ways: (1) we boost effectiveness by considering the (k, P)-core community of experts and the diversity of experts’ research interests, to achieve high-quality expert representation from paper representation; and (2) we streamline expert finding, going from “extract top-n experts from top-m (m > n) semantically similar papers” to “directly return top-n experts”. The process of returning a large number of top-m papers as intermediate data is avoided, thereby improving the efficiency. Extensive experiments using real-world datasets demonstrate our approach’s superiority. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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5. Cost Optimal Production-Scheduling Model Based on VNS-NSGA-II Hybrid Algorithm—Study on Tissue Paper Mill.
- Author
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Zhang, Huanhuan, Li, Jigeng, Hong, Mengna, Man, Yi, and He, Zhenglei
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PAPER mills ,FLOW shop scheduling ,PRODUCTION scheduling ,INDUSTRIAL costs ,ALGORITHMS - Abstract
With the development of the customization concept, small-batch and multi-variety production will become one of the major production modes, especially for fast-moving consumer goods. However, this production mode has two issues: high production cost and the long manufacturing period. To address these issues, this study proposes a multi-objective optimization model for the flexible flow-shop to optimize the production scheduling, which would maximize the production efficiency by minimizing the production cost and makespan. The model is designed based on hybrid algorithms, which combine a fast non-dominated genetic algorithm (NSGA-II) and a variable neighborhood search algorithm (VNS). In this model, NSGA-II is the major algorithm to calculate the optimal solutions. VNS is to improve the quality of the solution obtained by NSGA-II. The model is verified by an example of a real-world typical FFS, a tissue papermaking mill. The results show that the scheduling model can reduce production costs by 4.2% and makespan by 6.8% compared with manual scheduling. The hybrid VNS-NSGA-II model also shows better performance than NSGA-II, both in production cost and makespan. Hybrid algorithms are a good solution for multi-objective optimization issues in flexible flow-shop production scheduling. [ABSTRACT FROM AUTHOR]
- Published
- 2022
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6. Research on the Fusion of Hybrid Fuzzy Clustering Algorithm and Computer Automatic Test Paper Composition Algorithm.
- Author
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Kan, Baopeng
- Subjects
COMPUTERS ,COMPUTER algorithms ,FUZZY algorithms ,COMPUTER workstation clusters ,ALGORITHMS ,HIGHER education exams - Abstract
In order to improve the effect of intelligent automatic test paper composition, this paper combines the hybrid fuzzy clustering algorithm to study the computer automatic test paper composition algorithm. In this paper, a computer automatic test paper composition system based on hybrid fuzzy clustering algorithm is constructed. Moreover, the hybrid fuzzy clustering method used in this paper is used as the basic algorithm of the system, and the algorithm is improved according to the actual needs of intelligent paper composition. In addition, this paper uses an intelligent algorithm to input the relevant constraint parameters and combines the original parameters to select the most suitable test questions from the database and combine them into test papers. Finally, this paper constructs the system structure based on the requirements of intelligent test paper composition. The experimental research shows that the computer automatic test paper composition system based on the hybrid fuzzy clustering algorithm proposed in this paper has a good test paper composition function, which can effectively promote the progress of the intelligent examination mode in colleges and universities. [ABSTRACT FROM AUTHOR]
- Published
- 2022
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7. Tools and algorithms for the construction and analysis of systems: a special issue on tool papers for TACAS 2021.
- Author
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Jensen, Peter Gjøl and Neele, Thomas
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ALGORITHMS ,SOFTWARE verification ,INTEGRATED circuit verification ,SYSTEMS software ,CONFERENCES & conventions - Abstract
This special issue contains six revised and extended versions of tool papers that appeared in the proceedings of TACAS 2021, the 27th International Conference on Tools and Algorithms for the Construction and Analysis of Systems. The issue is dedicated to the realization of algorithms in tools and the studies of the application of these tools for analysing hard- and software systems. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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8. Socio‐technical issues in the platform‐mediated gig economy: A systematic literature review: An Annual Review of Information Science and Technology (ARIST) paper.
- Author
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Dedema, Meredith and Rosenbaum, Howard
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INFORMATION science ,TECHNOLOGY ,CORPORATE culture ,ALGORITHMS ,ECONOMICS - Abstract
The gig economy and gig work have grown quickly in recent years and have drawn much attention from researchers in different fields. Because the platform mediated gig economy is a relatively new phenomenon, studies have produced a range of interesting findings; of interest here are the socio‐technical issues that this work has surfaced. This systematic literature review (SLR) provides a snapshot of a range of socio‐technical issues raised in the last 12 years of literature focused on the platform mediated gig economy. Based on a sample of 515 papers gathered from nine databases in multiple disciplines, 132 were coded that specifically studied the gig economy, gig work, and gig workers. Three main socio‐technical themes were identified: (1) the digital workplace, which includes information infrastructure and digital labor that are related to the nature of gig work and the user agency; (2) algorithmic management, which includes platform governance, performance management, information asymmetry, power asymmetry, and system manipulation, relying on a diverse set of technological tools including algorithms and big data analytics; (3) ethical design, as a relevant value set that gig workers expect from the platform, which includes trust, fairness, equality, privacy, and transparency. A social informatics perspective is used to rethink the relationship between gig workers and platforms, extract the socio‐technical issues noted in prior research, and discuss the underexplored aspects of the platform mediated gig economy. The results draw attention to understudied yet critically important socio‐technical issues in the gig economy that suggest short‐ and long‐term opportunities for future research directions. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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9. A mathematical foundation for foundation paper pieceable quilts.
- Author
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Leake, Mackenzie, Bernstein, Gilbert, Davis, Abe, and Agrawala, Maneesh
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QUILTS ,QUILTING ,PATCHWORK quilts ,SEWING patterns ,ALGORITHMS - Abstract
Foundation paper piecing is a popular technique for constructing fabric patchwork quilts using printed paper patterns. But, the construction process imposes constraints on the geometry of the pattern and the order in which the fabric pieces are attached to the quilt. Manually designing foundation paper pieceable patterns that meet all of these constraints is challenging. In this work we mathematically formalize the foundation paper piecing process and use this formalization to develop an algorithm that can automatically check if an input pattern geometry is foundation paper pieceable. Our key insight is that we can represent the geometric pattern design using a certain type of dual hypergraph where nodes represent faces and hyperedges represent seams connecting two or more nodes. We show that determining whether the pattern is paper pieceable is equivalent to checking whether this hypergraph is acyclic, and if it is acyclic, we can apply a leaf-plucking algorithm to the hypergraph to generate viable sewing orders for the pattern geometry. We implement this algorithm in a design tool that allows quilt designers to focus on producing the geometric design of their pattern and let the tool handle the tedious task of determining whether the pattern is foundation paper pieceable. [ABSTRACT FROM AUTHOR]
- Published
- 2021
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10. Performance Evaluation of the Extractive Methods in Automatic Text Summarization Using Medical Papers.
- Author
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Kus, Anil and Aci, Cigdem Inan
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PERFORMANCE evaluation ,TEXT summarization ,MEDICAL sciences ,ALGORITHMS ,SEMANTICS - Abstract
Copyright of Gazi Journal of Engineering Sciences (GJES) / Gazi Mühendislik Bilimleri Dergisi is the property of Gazi Journal of Engineering Sciences and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
- Published
- 2023
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- View/download PDF
11. Scientific papers and artificial intelligence. Brave new world?
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Nexøe, Jørgen
- Subjects
COMPUTERS ,MANUSCRIPTS ,ARTIFICIAL intelligence ,MACHINE learning ,DATA analysis ,MEDICAL literature ,MEDICAL research ,ALGORITHMS - Published
- 2023
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12. Discussion paper: implications for the further development of the successfully in emergency medicine implemented AUD2IT-algorithm.
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Przestrzelski, Christopher, Jakob, Antonina, Jakob, Clemens, and Hoffmann, Felix R.
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DOCUMENTATION ,CURRICULUM ,HUMAN services programs ,EMERGENCY medicine ,EXPERIENCE ,MEDICAL records ,ELECTRONIC publications ,ALGORITHMS ,PATIENTS' attitudes - Abstract
The AUD2IT-algorithm is a tool to structure the data, which is collected during an emergency treatment. The goal is on the one hand to structure the documentation of the data and on the other hand to give a standardised data structure for the report during handover of an emergency patient. AUD2IT-algorithm was developed to provide residents a documentation aid, which helps to structure the medical reports without getting lost in unimportant details or forgetting important information. The sequence of anamnesis, clinical examination, considering a differential diagnosis, technical diagnostics, interpretation and therapy is rather an academic classification than a description of the real workflow. In a real setting, most of these steps take place simultaneously. Therefore, the application of the AUD2IT-algorithm should also be carried out according to the real processes. A big advantage of the AUD2IT-algorithm is that it can be used as a structure for the entire treatment process and also is entirely usable as a handover protocol within this process to make sure, that the existing state of knowledge is ensured at each point of a team-timeout. PR-E-(AUD2IT)-algorithm makes it possible to document a treatment process that, in principle, does not have to be limited to the field of emergency medicine. Also, in the outpatient treatment the PR-E-(AUD2IT)-algorithm could be used and further developed. One example could be the preparation and allocation of needed resources at the general practitioner. The algorithm is a standardised tool that can be used by healthcare professionals of any level of training. It gives the user a sense of security in their daily work. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
13. Digitalized Control Algorithm of Bridgeless Totem-Pole PFC with a Simple Control Structure Based on the Phase Angle.
- Author
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Lee, Gi-Young, Park, Hae-Chan, Ji, Min-Woo, and Kim, Rae-Young
- Subjects
ELECTRIC current rectifiers ,ELECTRONIC paper ,PHASE-locked loops ,ALGORITHMS ,ANGLES ,VOLTAGE - Abstract
Compared to the conventional boost power factor correction (PFC) converter, a totem-pole bridgeless PFC has high efficiency because it does not have an input diode rectifier stage, but a current spike may occur when the polarity of the grid voltage changes. This paper proposes a digital control algorithm for bridgeless totem-pole PFC with a simple control structure based on the phase angle of grid voltage. The proposed algorithm has a PI-based double-loop control structure and performs DC-link voltage and input inductor current control. Rectifying switches operate based on the proposed rectification algorithm using phase angle information calculated through a single-phase phase-locked loop (PLL) to prevent current spikes. The feed-forward duty ratio value is calculated according to the polarity of the grid voltage and added to the double-loop controller to perform appropriate power factor control. The performance and feasibility of the proposed control algorithm are verified through a 3 kW hardware prototype. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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14. Hybrid Methods of Bibliographic Coupling and Text Similarity Measurement for Biomedical Paper Recommendation.
- Author
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Hongmei Guo, Zhesi Shen, Jianxun Zeng, and Na Hong
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BIBLIOGRAPHY ,CONFERENCES & conventions ,CITATION analysis ,BIBLIOGRAPHICAL citations ,RESEARCH funding ,CONTENT analysis ,ALGORITHMS - Abstract
The amount of available scientific literature is increasing, and studies have proposed various methods for evaluating document-document similarity in order to cluster or classify documents for science mapping and knowledge discovery. In this paper, we propose hybrid methods for bibliographic coupling (BC) and linear evaluation of text or content similarity: We combined BC with BM25, Cosine, and PMRA to compare their performances with single methods in paper recommendation tasks using TREC Genomics Track 2005datasets. For paper recommendation, BC and text-based methods complement each other, and hybrid methods were better than single methods. The combinations of BC with BM25 and BC with Cosine performed better than BC with PMRA. The performances were best when the weights of BM25, Cosine, and PMRA were 0.025, 0.2, and 0.2, respectively, in hybrid methods. For paper recommendation, the combinations of BC with text-based methods were better than BC or text-based methods used alone. The choice of method should depend on the actual data and research needs. In the future, the underlying reasons for the differences in performance and the specific part or type of information they complement in text clustering or recommendation need to be examined. [ABSTRACT FROM AUTHOR]
- Published
- 2021
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15. Automated analysis of pen-on-paper spirals for tremor detection, quantification, and differentiation.
- Author
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Rajan, Roopa, Anandapadmanabhan, Reghu, Nageswaran, Sharmila, Radhakrishnan, Vineeth, Saini, Arti, Krishnan, Syam, Gupta, Anu, Vishnu, Venugopalan Y., Pandit, Awadh K., Singh, Rajesh Kumar, Radhakrishnan, Divya M, Singh, Mamta Bhushan, Bhatia, Rohit, Srivastava, Achal, Kishore, Asha, and Padma Srivastava, M. V.
- Subjects
STATISTICS ,RESEARCH ,CONFIDENCE intervals ,ANALYSIS of variance ,TASK performance ,HANDWRITING ,ACCELEROMETERS ,DYSTONIA ,MOVEMENT disorders ,TREMOR ,DRAWING ,DESCRIPTIVE statistics ,PARKINSON'S disease ,SENSITIVITY & specificity (Statistics) ,DATA analysis ,RECEIVER operating characteristic curves ,DATA analysis software ,ALGORITHMS - Abstract
OBJECTIVE: To develop an automated algorithm to detect, quantify, and differentiate between tremor using pen-on-paper spirals. METHODS: Patients with essential tremor (n = 25), dystonic tremor (n = 25), Parkinson’s disease (n = 25), and healthy volunteers (HV, n = 25) drew free-hand spirals. The algorithm derived the mean deviation (MD) and tremor variability from scanned images. MD and tremor variability were compared with 1) the Bain and Findley scale, 2) the Fahn–Tolosa–Marin tremor rating scale (FTM–TRS), and 3) the peak power and total power of the accelerometer spectra. Inter and intra loop widths were computed to differentiate between the tremor. RESULTS: MD was higher in the tremor group (48.9±26.3) than in HV (26.4±5.3; p < 0.001). The cut-off value of 30.3 had 80.9% sensitivity and 76.0% specificity for the detection of the tremor [area under the curve: 0.83; 95% confidence index (CI): 0.75, 0.91, p < 0.001]. MD correlated with the Bain and Findley ratings (rho = 0.491, p = 0 < 0.001), FTM–TRS part B (rho = 0.260, p = 0.032) and accelerometric measures of postural tremor (total power, rho = 0.366, p < 0.001; peak power, rho = 0.402, p < 0.001). Minimum Detectable Change was 19.9%. Inter loop width distinguished Parkinson’s disease spirals from dystonic tremor (p < 0.001, 95% CI: 54.6, 211.1), essential tremor (p = 0.003, 95% CI: 28.5, 184.9), or HV (p = 0.036, 95% CI: -160.4, -3.9). CONCLUSION: The automated analysis of pen-on-paper spirals generated robust variables to quantify the tremor and putative variables to distinguish them from each other. SIGNIFICANCE: This technique maybe useful for epidemiological surveys and follow-up studies on tremor. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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16. 基于多目标优化的联邦学习进化.
- Author
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胡智勇, 于千城, 王之赐, and 张丽丝
- Subjects
FEDERATED learning ,ALGORITHMS ,PRIVACY - Abstract
Copyright of Application Research of Computers / Jisuanji Yingyong Yanjiu is the property of Application Research of Computers Edition and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
- Published
- 2024
- Full Text
- View/download PDF
17. Classification of forensic hyperspectral paper data using hybrid spectral similarity algorithms.
- Author
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Devassy, Binu Melit, George, Sony, Nussbaum, Peter, and Thomas, Tessamma
- Subjects
SPECTRAL imaging ,FORGERY ,ALGORITHMS ,FORENSIC sciences ,CLASSIFICATION ,CONFIDENCE intervals ,CLASSIFICATION algorithms - Abstract
Document forgeries that involve modification of the materials used, such as ink and paper, provide evidence of any malpractices being performed. Forensic specialists use different techniques to identify and classify these samples; however, the most preferred method is to use nondestructive techniques to avoid any potential damage to the original specimen under investigation. Hyperspectral imaging has already been explored in several application domains and used as a powerful method in forensic investigations to extract information about the materials under examination. To precisely classify the material information and utilize the hyperspectral imaging technique's potential, we probed the potential of some hybrid spectral similarity measures to classify different commonly used paper samples. A comparison of these methods is quantitatively presented in this article. Hybrid spectral similarity algorithms are tested on forensic analysis of paper data. We compared the classification capabilities of various hybrid spectral similarity algorithms on hyperspectral data of 40 different paper samples. The overall accuracy (OA), kappa K̂, Z‐score of kappa (ZK̂), and the 95% confidence interval of kappa (CI(K̂)) are used for comparison. The SID‐SAM and SID‐SCA produced an overall accuracy of 88% and 87%, respectively, which is highest among the hybrid spectral similarity measures tested. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
18. Selected Papers of the 32nd International Workshop on Combinatorial Algorithms, IWOCA 2021.
- Author
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Flocchini, Paola and Moura, Lucia
- Subjects
EULERIAN graphs ,ALGORITHMS ,APPROXIMATION algorithms ,WEB hosting - Abstract
They give fixed parameter tractable algorithms for the problem parameterized by various structural parameters. The authors give a greedy loop-free algorithm for the exhaustive generation, a successor algorithm that runs in constant amortized time, among other algorithms, as well as results for the fixed spin generalization of this problem. IWOCA (International Workshop on Combinatorial Algorithms) is an annual conference series covering all aspects of combinatorial algorithms. [Extracted from the article]
- Published
- 2023
- Full Text
- View/download PDF
19. A review paper of optimal resource allocation algorithm in cloud environment.
- Author
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Patadiya, Namrata and Bhatt, Nirav
- Subjects
RESOURCE allocation ,LITERATURE reviews ,SERVICE level agreements ,ALGORITHMS ,ELECTRONIC data processing ,CLOUD computing - Abstract
Cloud computing has become a popular approach for processing data and running computationally expensive services on a pay-as-you-go basis. Due to the ever-increasing requirement for cloud-based apps, appropriately allocating resources according to user requests while meeting service-level agreements between customers and service providers has become increasingly complex. An efficient and versatile resource allocation method is required to properly deploy these assets and meet user needs. The technique of distributing resources has become more arduous as user demand has increased. One of the key areas of research experts is how to design optimal solutions for this approach. In this paper, a literature review on proposed dynamic resource allocation approaches is introduced. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
20. The influence of memory, sample size effects, and filter paper material on online laser-based plant and soil water isotope measurements.
- Author
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Cui, Jiangpeng, Tian, Lide, Gerlein‐Safdi, Cynthia, and Qu, Dongmei
- Subjects
ISOTOPES ,INFRARED spectroscopy ,CAVITY-ringdown spectroscopy ,ALGORITHMS ,FILTER paper - Abstract
Rationale The recent development of isotope ratio infrared spectroscopy (IRIS) was quickly followed by the addition of online extraction and analysis systems, making it faster and easier to measure soil and plant water isotopes. However, memory and sample size effects limit the efficiency and accuracy of these new setups. In response, this study presents a scheme dedicated to estimating and eliminating these two effects. Methods Memory effect was determined by injecting two standard waters alternately. Each standard was injected nine times in a row and analyzed using induction module cavity ring-down spectroscopy (IM-CRDS). Memory coefficients were calculated using a new 'multistage jump' algorithm. Sample size effects were evaluated by injecting water volumes ranging from 1 μL to 6 μL. Finally, the influence of cellulose filter paper on the isotopic measurements, the memory, and the sample size effect was evaluated by comparing it with glass filter paper. Results Memory effects were detected for both δ
18 O and δ2 H values, with the latter being stronger. Isotopic differences between replicates of the same plant or soil sample showed a clear decrease after memory correction. A small water volume effect was found only when the injected water volume was larger than 3 μL. However, while the correction method performed well for laboratory-made samples, it did not for field samples, due to the heterogeneity of the isotopic composition of the samples. Stronger memory and water volume effects were found for cellulose filter paper. Conclusions The memory coefficients and the water volume-isotope relationship improved the consistency and accuracy of both laboratory and field data. Our results indicate that cellulose filter paper may not be a suitable medium to measure standard waters and evaluate memory and water volume effects. Finally, a detailed correction and calibration protocol is suggested, along with notes on best practices to obtain good-quality IM-CRDS data. Copyright © 2017 John Wiley & Sons, Ltd. [ABSTRACT FROM AUTHOR]- Published
- 2017
- Full Text
- View/download PDF
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