Author: "Hurley, T. Brian" / Database: Academic Search Index - Searchworks@Jio Institute Digital Library Search Results

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Author: Sammakia, Tarek and Hurley, T. Brian
Subjects: *CATALYSTS, *KETONES, *ESTERS, *BINDING sites
Abstract: Discusses the preparation of catalyst 2-acyl-4-aminopyridines using ketones as binding sites. Use of the catalyst in the hydroxyl-directed methanolysis of alpha-hydroxy esters; Enhancement of the selectivities by the ketones.
Published: 2000
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Author: Sammakia, Tarek and Hurley, T. Brian
Subjects: *PYRIDINE, *DIOXOLANES, *ORGANIC synthesis, *BIOCHEMICAL mechanism of action
Abstract: Demonstrates the mechanism of action of 2-formyl-4-pyrrolidinopyridine, a catalyst for the hydroxyl-directed methanolysis of alpha-hydroxy esters. Influence of para-nitrophenol in the catalytic reaction; Reaction via dioxolanone intermediate; Formation of dioxolanone; Hydroxyl-directed reactions in organic synthesis.
Published: 1999
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