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Studies on the mechanisms of action of 2-formyl-4-pyrrolidinopyridine: Isolation and...

Authors :
Sammakia, Tarek
Hurley, T. Brian
Source :
Journal of Organic Chemistry. 06/25/99, Vol. 64 Issue 13, p4652. 13p. 17 Diagrams, 4 Charts, 8 Graphs.
Publication Year :
1999

Abstract

Demonstrates the mechanism of action of 2-formyl-4-pyrrolidinopyridine, a catalyst for the hydroxyl-directed methanolysis of alpha-hydroxy esters. Influence of para-nitrophenol in the catalytic reaction; Reaction via dioxolanone intermediate; Formation of dioxolanone; Hydroxyl-directed reactions in organic synthesis.

Details

Language :
English
ISSN :
00223263
Volume :
64
Issue :
13
Database :
Academic Search Index
Journal :
Journal of Organic Chemistry
Publication Type :
Academic Journal
Accession number :
2151734
Full Text :
https://doi.org/10.1021/jo982281n