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Abstract The Second White Specks is an enigmatic unconventional shale play in the Western Canada Foreland Basin (WCFB). This play has an inconsistent production performance that has impacted exploration and production risk, preventing extensive development. In this contribution, geochemical properties are studied with the purpose to identify possible geochemical factors that could contribute to the production variability of this unconventional petroleum system. The studied succession consists of the Second White Specks (SWS) and Upper Belle Fourche (UBF) alloformations, which are part of the SWS shale play. Organic petrology and Rock-Eval pyrolysis were combined to characterize the organic matter (OM), and assess OM richness, thermal maturity and hydrocarbon generation potential in the foredeep section of the basin. The results show that the OM richness and hydrocarbon generation potential in this area is good, and comparison with other studies show that they do not exhibit major lateral variations. The kerogen is marine Type II and is dominated by liptinite, vitrinite, inertinite macerals, and solid bitumen. Alginite and bituminite are the most abundant macerals. Altered bituminite provides evidence of anaerobic bacteria degradation. There is a modest contribution of inertinite that may be responsible for a dilution effect of the pyrolyzable carbon. The thermal maturity indicators in this study such as vitrinite reflectance, Tmax, and alginite UV fluorescence color indicate that the controls on thermal maturity and hydrocarbon generation are not well understood. There are lateral short scale variations or maturity anomalies that require further investigation, to reduce the exploration risk. Highlights • Exsudatinite, bituminized alginite and oil inclusions corroborate endogenous hydrocarbon generation. • The thermal maturity in most of the study area indicates onset of petroleum generation to peak oil window. • A low maturity anomaly was identified. Further research is needed to test hypotheses for lateral maturity variability. • The organic matter experienced several degrees of anaerobic degradation. [ABSTRACT FROM AUTHOR]

Abstract This study investigated the geochemical characteristics of source rocks in each sequence and studied on the oil-source correlation under a sequence stratigraphic framework of the Upper Cretaceous Yogou Formation. The Yogou Formation as the most primary and productive source bed in the Termit Basin (Niger), was further divided into three third-order sequences (i.e. YSQ1, YSQ2 and YSQ3, from bottom to top) in the study. On the basis of the geochemical analysis of a total of 35 rock samples from YSQ3, YSQ2 and YSQ1, the variation of the organic matter abundances, types and maturity of source rocks within different sequences were compared. The TOC content of YSQ2 and YSQ1 source rocks ranges from 0.76% to 1.69% with mature to high mature thermal evaluation stage (R o : 0.63%–1.29%), while the TOC content of YSQ3 source rocks is much higher (1.11%–6.63%) with a relatively lower maturation levels (R o : 0.59%–0.91%). All source rocks are dominated by Type II 2 –III kerogen. Moreover, in order to determine the oil-source correlation under a sequence stratigraphic framework, the composition of biomarkers in 35 source rocks and 25 crude oils were analyzed systematically. Various non-biomarker and biomarker parameters were applied involving source-related, maturity-related and environment-related parameters. The YSQ3 source rocks are typically characterized by relatively higher Pr/Ph ratio, higher concentration of dibenzofurans (DBFs) and lower gammacerane index indicating a suboxic transitional environment, and the relatively higher values of oleanane index and C 24 TeT/(C 24 TeT + C 26 TT) ratio reflecting a significant terrigenous organic matter input. Conversely, the YSQ2, YSQ1 source rocks and studied oils have relatively lower Pr/Ph ratios, higher content of gammacerane and dibenzothiophenes (DBTs) suggesting suboxic to anoxic conditions under shallow marine depositional environment, and low values of oleanane index and C 24 TeT/(C 24 TeT + C 26 TT) ratios indicating predominant algal aquatic organisms input. In addition, other molecular parameters in crude oils, including OEP, CPI, TAR, n C 21 -/ n C 22 +, (n C 21 + n C 22)/(n C 28 + n C 29), Pr/ n C 17 , Ph/ n C 18 ratios and the distribution patterns and relevant parameters of tricyclic terpane series, also have the obviously similar characteristics to YSQ2 and YSQ1 source rocks, rather than YSQ3 source rocks. The result of oil-source correlation shows that the discovered oils are dominantly derived from YSQ2 and YSQ1 source rocks, with minor contribution of YSQ3 source rocks. Therefore, the oil-source correlation within a sequence stratigraphic framework can provide a practical model for source rock assessment and petroleum system study. Highlights • The source rock was evaluated under a sequence stratigraphic framework. • The compositions of molecular markers for 3 sequences were discussed. • Oil-source correlation shows that the YSQ1 and YSQ2 are the main source beds. • Geochemical sequence stratigraphy has practical implication in petroleum system. [ABSTRACT FROM AUTHOR]

Graphical abstract Highlights • The Karing Volcanic Complex and the Dusunbaru Pluton represent a volcaniccentre. • Volcanicity took place over 630,000 years within the Asselian Stage of the Permian. • The West Sumatra Permian Block was a southern continuation of the Indochina Block. Abstract The Karing Volcanic Complex and the Dusunbaru Pluton comprise an Early Permian volcanic-plutonic centre in the Volcanic-Plutonic Arc on the western margin of the Kluet-Kuantan basin of the West Sumatra Block in Sumatra, Indonesia. The Karing Volcanic Complex is mostly composed of 'Monotonous Intermediate Type' tuffs which interfinger with the volcaniclastics and coastal and marine sediments of the Mengkarang Formation. Eight lithological Intervals each commencing with tuffs overlain by volcaniclastics and sediments, have been mapped in the Merangin river section. The climax of the volcanicity occurred in Interval IV. In the waning stages of volcanism basalt flows were extruded and the volcanic pile was eroded by lahars and debris flows. Zircon CA-IDTMS dates from tuff beds at the base and top of the section bracket the volcanic activity as having taken place over a period of 630,000 years within the Asselian Stage of the Permian. The Dusunbaru pluton is composed of Gabbroids, Granitoids with subordinate Metabasalts and Metatuffs occurring as xenoliths. These lithologies are present as lithic clasts within the Karing Volcanic Complex tuffs, and it is considered that the Dusunbaru Pluton represents a former magma chamber from which the tuffs were vented. The Mildly-alkaline to Sub-alkaline Metabasalts and Gabbroids, were derived from the N-MORB sector of the lithospheric 'Mantle Array' while the compositions of the Granitoids (including gabbroid-granitoid hybrid rocks) were influenced by the reaction of basic magmas with the lower crust. The Sub-alkaline and High–K Late Basalt Lava flows were derived from the melting of basalt below the crust-mantle interface. The rock suites were variably hydrated as a result of alterations. Magmatic alteration has affected the Metabasalts, Gabbroids, Granitoids, their xenoliths and the Late Basalts. Hydrothermal alteration has weakly affected the aubaerial tuffs and strongly changed the mineralogy of some of the Late Basalt flows, in particular the entablatures. The chemistry of the Dusunbaru Pluton is of Cordilleran-type, typical of continent margin volcanic-plutonic arcs. The Dusunbaru Pluton was likely originally emplaced at the interface between the Kuantan Formation (Visean to Permian) and a Proterozoic gneissic basement. A late hydrothermal event/tectonic event during which the Dusunbaru Pluton was faulted against the Karing Volcanic Complex, is attributed to the collision of the Woyla oceanic terrains with Sumatra in the late-mid Cretaceous. The stratigraphy of the West Sumatra Volcanic Arc and the Kluet-Kuantan Basin resembles that of the Sukhothai Volcanic Arc and associated basin sediments in the Indochina Block. A palaeogeographical reconstruction suggests that the West Sumatra Block originally was an appendage to the Indochina Block at a palaeolatitude between 5 and 15° S. [ABSTRACT FROM AUTHOR]

Highlights • The Lucaogou mudstones are still in the early oil window. • The biological sources are predominately algae and bacteria. • The Lucaogou mudstones were deposited in a hypersaline and anoxic environment. • The Lucaogou mudstones hold a significant exploration potential of tight oil. Abstract The mudstones of the Lucaogou Formation are the most important and organic-rich sediments and tight oil exploration target in the northwestern China. The organic and stable isotope geochemistry, and organic petrology were used to evaluate their sedimentary environments and hydrocarbon generative potential. The Lucaogou mudstones contain abundant organic matter, S 2 , hydrogen index (HI) and extractable organic matter (EOM), whereas S 1 values are low. The δ13C values of EOM are very light and display a negative correlation with HI. Rock pyrolysis data imply a low maturity (0.6–0.7 %R o equivalent) of the Lucaogou Formation, consistent with aliphatic and aromatic hydrocarbon ratios. The biological sources are predominately algae and bacteria, with less contribution of higher plants in the Lucaogou Formation as indicated by δ13C EOM , biomarkers and maceral composition. The Lucaogou mudstones contain low ratios of C 31 R/C 30 hopane, C 29 /C 30 hopane and C 22 /C 21 tricyclic terpane, and high C 24 /C 23 tricyclic terpane value, which are consistent with their depositional environments (i.e., lacustrine). The abundant β-carotane, gammacerane and hop-17(21)-enes indicate a hypersaline and anoxic environment. The studied samples are predominantly oil-prone with a dominant type I and II 1 kerogen. High contents of total organic carbon (TOC), S 2 , HI, EOM, saturated and aromatic hydrocarbons indicate that the Lucaogou Formation hold significant exploration potential of tight oil. [ABSTRACT FROM AUTHOR]

Abstract The Lower Permian Fengcheng Formation in the Mahu Sag of northwestern China is well-known for its alkaline lacustrine deposits. However, previous research is scarce due to this formation's notable burial depth (up to 5000 m) and limited oil and gas exploration. Using XRD, XRF, micro-XRF, and C-O isotope analyses, we determined: (1) the stratigraphic trends in mineral compositions, (2) the cyclic depositional processes, and (3) paleoclimate variations. The petrologic and geochemical data elucidate depositional and diagenetic processes in the mixed siliciclastic, volcaniclastic and chemical strata of the Fengcheng Formation. Sodium carbonate minerals in the studied core are dominated by wegscheiderite (Na 2 CO 3 ·3NaHCO 3) and trona (Na 2 CO 3 ·NaHCO 3 ·2H 2 O). Nahcolite (NaHCO 3) and a Mg-Na carbonate mineral, northupite (Na 2 CO 3 ·MgCO 3 ·NaCl), also occur, although their abundance is obviously lower than that of wegscheiderite and trona. These substances grew as bottom-growth crystals from lakes overlying tuffs. The volumetrically important Ca-Na carbonate mineral, shortite (Na 2 CO 3 ·2CaCO 3), and some northupite precipitated diagenetically from shallow groundwater brines in unlithified, dark-colored siliciclastic sediment and volcanic ash. Shortite mainly precipitated from the Ca-Na-CO 3 -rich shallow groundwater, whereas northupite precipitated from the Mg-Na-CO 3 -Cl-rich shallow groundwater. Sodium carbonates and tuffs, fine-grained tuffaceous rocks, and siliciclastic rocks formed repetitive centimeter- and meter-scale cycles that are shown as dark-colored lithological layers during lake expansion and contraction stages or during volcanic eruptions. The brine composition, which controlled the precipitation of sodium carbonates, was influenced strongly by volcanism and volcanism-related hydrothermal activity. Changes in climate and volcanic eruptions controlled the deposition of alternating beds of sodium carbonates and dark-colored lithologies. Changes in climate caused the expansion and contraction stages in the lakes. During relatively humid climate stages, diluted water entered the basin and resupplied the lake water with calcium and magnesium during flooding events. Sandy to silty beds were deposited by turbidity currents during this stage. During arid climate stages, bedded sodium carbonates grew in the lakes, and their co-occurrence suggests high atmospheric pCO 2 and high temperatures. The ashes that are provided by volcanic eruptions during arid climate stages can also stop the precipitation of sodium carbonates. Highlights • Sodium carbonates successions consist of alternating light-colored sodium carbonates layer and dark-colored tuff/tuffaceous layer. • The sodium carbonate minerals dominated by wegscheiderite and trona. Shortite and northupite occurred as transitional carbonate minerals. • Climates evolutions and periodic volcano eruptions joint to control the formation of depositional cycles in the sodium carbonates successions. [ABSTRACT FROM AUTHOR]

Abstract The exceptionally organic-rich rocks of the 1.98 Ga Zaonega Formation deposited in the Onega Basin, NW Russia, have refined our understanding of Earth System evolution during the Paleoproterozoic rise in atmospheric oxygen. These rocks were formed in vent- or seep-influenced settings contemporaneous with voluminous mafic volcanism and contain strongly 13C-depleted organic matter. Here we report new isotopic (δ34S, Δ33S, Δ36S, δ13C org) and mineralogical, major element, total sulphur and organic carbon data for the upper part of the Zaonega Formation, which was deposited shortly after the termination of the Lomagundi-Jatuli positive carbon isotope excursion. The data were collected on a recently obtained 102 m drill-core section and show a δ13C org shift from −38‰ to −25‰. Sedimentary sulphides have δ34S values typically between +15‰ and +25‰ reflecting closed-system sulphur isotope behaviour driven by high rates of microbial sulphate reduction, high sulphate demand, hydrothermal activity and hydrocarbon seepage. Four intervals record δ34S values that exceed +30‰. We interpret these unusually 34S-enriched sulphides to be a result of limited sulphate diffusion into pore waters due to changes in sedimentation and/or periods of basinal restriction. Additionally, there are four negative δ34S excursions that are interpreted to reflect changes in the open/closed-system behaviour of sulphate reduction or availability of reactive iron. Our findings highlight the influence of basinal processes in regulating sulphur isotope records and the need for care before interpreting such signals as reflecting global conditions. Highlights • Zaonega Formation Δ33S-δ34S data track basin-specific rather than global processes. • Opposing Δ33S-δ34S relationship relates to rapid microbial sulphate reduction. • Positive δ34S excursions reflect partial basinal restriction. [ABSTRACT FROM AUTHOR]

Abstract The formation of the Shiquanhe–Namco Ophiolite Mélange Zone (SNMZ) and its relationship to the Bangong–Nujiang Suture Zone (BNSZ) in central Tibet are key to understanding the Mesozoic tectonic evolution of the Meso-Tethys Ocean. This study presents zircon U Pb geochronological, whole-rock geochemical, and Lu Hf isotopic data for gabbros from the Asa Ophiolite of the central SNMZ. Four gabbros yielded zircon U Pb ages of 117.3 ± 0.6, 117.3 ± 0.5, 115.3 ± 0.5, and 114.9 ± 0.6 Ma. Whole-rock geochemical analyses indicate that these rocks are tholeiitic, enriched in light rare earth and large-ion lithophile elements, and depleted in Nb and Ta. These gabbros have geochemical affinities to island arc and mid-ocean ridge basalts, suggesting that they originated in an oceanic back-arc basin. Whole-rock geochemical data and isotopically juvenile εHf(t) values suggest that the gabbros were derived from a depleted mantle source that was enriched by slab-derived fluids and partial melts of sediment. Our data, combined with previous work, suggest that the BNSZ records the Early Cretaceous subduction of the Meso-Tethys oceanic crust and that the SNMZ represents a back-arc basin. During the Early Cretaceous, the Meso-Tethys Ocean remained open and contained an intra-oceanic subduction system and back-arc basin. Highlights • Ophiolite has Early Cretaceous ages (114-118 Ma). • Ophiolite has an oceanic back-arc spreading ridge setting. • The Bangon-Nujiang Meso-Tethys Ocean remained open during the Early Cretaceous. [ABSTRACT FROM AUTHOR]

Earth's core formation set the initial compositions of the core and mantle. Various aspects of core formation, such as the degree of metal–silicate equilibration, oxygen fugacity, and depth of equilibration, have significant consequences for the resulting compositions, yet are poorly constrained. The Hf–W isotopic system can provide unique constraints on these aspects relative to other geochemical or geophysical methods. Here we model the Hf–W isotopic evolution of the Earth, improving over previous studies by combining a large number of N -body simulations of planetary accretion with a core formation model that includes self-consistent evolution of oxygen fugacity and a partition coefficient of tungsten that evolves with changing pressure, temperature, composition, and oxygen fugacity. The effective average fraction of equilibrating metal is constrained to be k > 0.2 for a range of equilibrating silicate masses (for canonical accretion scenarios), and is likely <0.55 if the Moon formed later than 65 Ma. These values of k typically correspond to an effective equilibration depth of ∼0.5–0.7× the evolving core–mantle boundary pressure as the planet grows. The average mass of equilibrating silicate was likely at least 3× the impactor's silicate mass. Equilibration temperature, initial f O 2 , initial differentiation time, semimajor axis, and planetary mass (above ∼0.9 M ⊕ ) have no systematic effect on the 182 W anomaly, or on f Hf/W (except for f O 2 ), when applying the constraint that the model must reproduce Earth's mantle W abundance. There are strong tradeoffs between the effects of k , equilibrating silicate mass, depth of equilibration, and timing of core formation, so the terrestrial Hf–W isotopic system should be interpreted with caution when used as a chronometer of Earth's core formation. Because of these strong tradeoffs, the Earth's tungsten anomaly can be reproduced for Moon-forming impact timescales spanning at least 10–175 Ma. Early Moon formation ages require a higher degree of metal–silicate equilibration to produce Earth's 182 W anomaly. [ABSTRACT FROM AUTHOR]

Palaeo-exposure surfaces are common geologic features in the Cretaceous sedimentary record of the Middle East. Two important disconformity surfaces have influenced the Cenomanian-Turonian intervals of the Sarvak Formation in the Abadan Plain. These surfaces had substantial controls on reservoir quality of their underlying succession. In this study obtained data from macroscopic core descriptions, microscopic petrography, geochemical analysis, spectral gamma ray log signatures, and clay minerals frequency in three hydrocarbon fields are combined and used for interpretations. Dissolution, cementation and recrystallization are the main diagenetic features related to the disconformity surfaces. Intensity and development of these diagenetic alterations are highly dependent on depositional facies characteristics of the underlying sequences. In mud-dominated facies, the main diagenetic process is recrystallization, while the grain-dominated facies were highly subjected by dissolution and cementation. Based on the geochemical analysis, there is an increase in Al 2 O 3 , SiO 2 , Fe 2 O 3 , Al, Fe, Mn, and Rb content beneath the disconformities. In contrast, the Sr concentration displays a decreasing trend towards the disconformities. On spectral gamma ray logs, depletion of the uranium and high values of CGR/SGR and TH/U ratios are attributed to the meteoric diagenesis. In addition, obtained data from SEM and XRD analysis indicate that the montmorillonite is the most abundant clay mineral in uppermost part of the Sarvak Formation. It shows the highest concentration at the disconformity surfaces which can be quoted to the impact of meteoric diagenesis and development of palaeo-soil horizons. These results are used for reconstruction of diagenetic sequence of the upper Sarvak Formation in subsurface sections of the Abadan Plain. [ABSTRACT FROM AUTHOR]

In order to explore the marine redox structure on the earliest Cambrian (ca. 542–529 Ma) Yangtze Platform, South China, new Fe-Mo-C-S geochemical data from the slope Xugongping section for the Liuchapo and the base of Niutitang Formation are reported here. Integrated Fe speciation and Mo abundance data from the Xugongping section, in combination with previously published data from slope-basinal Longbizui section and others, suggest oxic surface waters and ferruginous deep waters coexisting with occasional mid-depth euxinic waters during the Fortunian Stage, and with widespread euxinic waters during the early Stage 2 marine transgression. A compilation of new and published sulfur isotope data of pyrite for the Liuchapo and the base of Niutitang Formations presents high isotopic values (mostly >+10‰) and distinctly different spatiotemporal gradient characteristics during the Fortunian Stage and the beginning of the Stage 2. We propose that redox stratification developed in the earliest Cambrian protected basin, and eustatic change and the connectivity of the protected basin with the open ocean controlled the materials supply from riverine input and open ocean reservoir and thus spatiotemporal variability of ocean chemistry. [ABSTRACT FROM AUTHOR]

This study aims to establish the diagenetic evolution of carbonate rocks of the Barremian-Aptian Tirgan Formation (Kopet-Dagh Basin, NE Iran), with special emphasis in their impact on reservoir quality to be used as analog for their equivalent carbonate reservoirs. To achieve this target, basic petrography complemented by elemental and stable isotopic (δ 18 O and δ 13 C) analyses of the studied carbonate rocks was used. In addition, the visible porosity was detected. The recognized carbonate diagenetic processes include micritization, cementation, dolomitization, compaction, dissolution, stylolitization, fracturing, silicification and neomorphism. These diagenetic processes took place in four diagenetic environments: marine-phreatic, meteoric-phreatic, meteoric-vadose and burial. Early dolomitization of lime muds, micritization of skeletal allochems and cementation by isopachous equant calcite represent marine-phreatic diagenesis. The meteoric-phreatic diagenesis was accompanied with the development of granular non-ferroan calcite cement, neomorphosed carbonate matrix and recrystallized bioclasts. The meteoric-vadose diagenesis led to prevalence of dissolution process and sparry calcite infilling the fractures. Late dolomitization, ferroan blocky and poikilotopic calcite cement, stylolitization and silicification processes were developed during burial diagenesis. An integration of the petrographic study with the geochemical analysis confirms that the studied carbonate rocks were originally composed of aragonite, which was eventually recrystallized to calcite and replaced by dolomite during diagenesis. In terms of reservoir quality, the recognized diagenetic alterations and visible porosities show that the diagenetic processes have a direct effect on modification of both inter- and intra-granular/crystalline porosity. In this manner, it is found that the calcite cementation, micritization and compaction decline the pore spaces, whereas the dolomitization, dissolution, formation of moldic pores and fracturing increase the pore volumes. Consequently, prevalence of dolomitization, dissolution, occurrence of moldic pores and fracturing in the Tirgan carbonate rocks gives the Tirgan Formation and its equivalent rocks a good opportunity to be an excellent reservoirs. [ABSTRACT FROM AUTHOR]

The timing and mechanisms of continental crust formation represent major outstanding questions in the Earth sciences. Extinct-nuclide radioactive systems offer the potential to evaluate the temporal relations of a variety of differentiation processes on the early Earth, including crust formation. Here, we investigate the whole-rock 182 W/ 184 W and 142 Nd/ 144 Nd ratios and zircon Δ 17 O values of a suite of well-studied and lithologically-homogeneous meta-igneous rocks from the Acasta Gneiss Complex, Northwest Territories, Canada, including the oldest-known zircon-bearing rocks on Earth. In the context of previously published geochemical data and petrogenetic models, the new 142 Nd/ 144 Nd data indicate that formation of the Hadean–Eoarchean Acasta crust was ultimately derived from variable sources, both in age and composition. Although 4.02 Ga crust was extracted from a nearly bulk-Earth source, heterogeneous μ 142 Nd signatures indicate that Eoarchean rocks of the Acasta Gneiss Complex were formed by partial melting of hydrated, Hadean-age mafic crust at depths shallower than the garnet stability field. By ∼3.6 Ga, granodioritic–granitic rocks were formed by partial melting of Archean hydrated mafic crust that was melted at greater depth, well into the garnet stability field. Our 182 W results indicate that the sources to the Acasta Gneiss Complex had homogeneous, high-μ 182 W on the order of +10 ppm—a signature ubiquitous in other Eoarchean terranes. No significant deviation from the terrestrial mass fractionation line was found in the triple oxygen isotope ( 16 O– 17 O– 18 O) compositions of Acasta zircons, confirming homogeneous oxygen isotope compositions in Earth's mantle by 4.02 Ga. [ABSTRACT FROM AUTHOR]

The roof, floor and gangue samples of coal seams were collected from a borehole in the Gujiao mining area. The vertical distribution of major elements, trace elements and rare earth elements (REEs) was tested through X-ray fluorescence spectrometry and inductively coupled plasma-mass spectrometry (ICP-MS). The formation environment and material source of the strata were analysed. The results showed that the major elements of the coal seam roof, floor and gangue are Si and Al, followed by Fe, K, and Ti. In the Shanxi Formation, Sn, B, Ta, Bi, Th, U, Li, Be, Nb, In, Cs and Hf are enriched. In the Taiyuan Formation, B, Bi, U, Li, Sr, Mo and Sb are enriched. Sn, B, Th, U, and Be of the Shanxi Formation and B, U, Mo, and Sb of Taiyuan Formation are enriched hazardous elements. The ratios of Sr/Ba, U/Th, Ni/Co and V/Cr could indicate the paleosalinity and redox conditions. The Shanxi Formation was mainly formed in an oxic environment. The roof and floor of the No. 7 coal and the roof of the No. 8 coal are limestone, indicating anoxic and suboxic to dysoxic environments. The lithology of the Shanxi Formation and Taiyuan Formation material source is complex, including sedimentary rocks, granite and alkaline basalt. Most samples are distributed at the intersection of the granite and alkaline basalt, indicating dual sourcing from the granite and alkaline basalt. [ABSTRACT FROM AUTHOR]

The tectonic evolution and Paleoposition of the North China Craton (NCC) in the Columbia supercontinent during Mesoproterozoic is still not well constrained owing to scarce outcrops of the Mesoproterozoic geological records. Here we present detailed U-Pb geochronological study on detrital zircons and trace elemental geochemistry of the Mesoproterozoic meta-sedimentary rocks from the Sanxiatian Formation, the upper Huade Group, in the northern NCC. The youngest cluster of detrital zircons from the Sanxiatian Formation has U-Pb age peak at ∼1357 Ma, which constrains the deposition of the Sanxiatian Formation after ∼1400 Ma. We suggest a stratigraphic correlation among the Sanxiatian, Baiyinbaolage, Liuhongwan and Xiamaling formations, all of which were deposited simultaneously in the northern NCC. The small portion of ∼2530 Ma zircons possibly corresponds with the growth of juvenile crust in the NCC at the late Neoarchean. The distinct ∼1850 Ma population may have originated from the syn-and post- tectonic granites distributed in the Trans-North China Orogen (TNCO), which is related with the collision between the Western and Eastern blocks in the NCC. The ∼1750–∼1600 Ma zircon populations were also sourced from the NCC and are possibly characterized by the post-collisional magmatic events after the amalgamation of the NCC. The zircon clusters younger than 1600 Ma with peaks at ∼1575 Ma and ∼1357 Ma, were interpreted as exotic sources, while the latter possibly related with the final breakup of the supercontinent Columbia. With the compilation of the detrital zircon dataset from the North India, the West Australia, the North Australia, the Siberia blocks and the northwestern Laurentia, the final fragmentation of the supercontinent Columbia is suggested to be characterized by the separation between the NCC, the Australia or the India blocks during the late Mesoproterozoic. [ABSTRACT FROM AUTHOR]

The South Anhui ophiolite (SAO) and the Northeast Jiangxi ophiolite (NJO) are the only two known Precambrian ophiolite suites within the eastern segment of the Jiangnan Orogen, South China. These ophiolites may provide significant insights into the convergence history of the South China Block during the Rodinia supercontinent cycle. SHRIMP zircon U–Pb dating indicates that the SAO formed at 831 ± 5 Ma whereas the NJO formed at ca. 1000 Ma. Modal mineral assemblages and the preservation of relict primary mineral assemblages indicate that serpentinized peridotites from both ophiolites were mainly harzburgite in protolith. Relict olivine and orthopyroxene fragments within both ophiolite suites yield similarly high Mg# values. The serpentinized peridotite samples yield U-shaped rare earth element patterns and contain high-Cr# spinel, both of which are indicative of supra-subduction zone ophiolites. However, serpentinized peridotites within the SAO contain olivine and clinopyroxene with slightly higher Mg# values, and have lower platinum-group element (PGE) and trace element concentrations than peridotites from the NJO. The SAO peridotites are also depleted in Ir, Pt, and Pd, in contrast to the flat and chondrite-like PGE patterns of the NJO peridotites. These observations indicate that compared with the NJO, SAO peridotites were subjected to a greater degree of melt extraction prior to emplacement. Furthermore, gabbro and basalt from the SAO have N-MORB- or arc-like geochemical characteristics that reflect the incorporation of crustal materials into the mantle source, suggesting that this ophiolite formed in a continental marginal back-arc basin setting. In comparison, the less pronounced depletions in trace elements and PGEs, as well as the restricted 187 Os/ 188 Os isotopic compositions of NJO serpentinized peridotites, suggest that they formed in a fore-arc setting. The contrasting geochemical characteristics of the two ophiolite suites indicate that they were generated during distinct stages of convergence along the southeastern margin of the Yangtze Block. Our results show that ophiolite suites produced within a single orogenic cycle could preserve diverse geochemical characteristics, and may provide insights into the initiation and cessation of continental amalgamation. [ABSTRACT FROM AUTHOR]

An integrated study of zircon U-Pb geochronology and geochemistry, together with Nd-Hf isotopes, have been carried out on the rhyodacite and rhyolitic tuff of the Jingtan Formation in the eastern part of the Jiangnan orogen. SIMS zircon U-Pb dating of two samples yielded weighted mean 206 Pb/ 238 U ages of 784 ± 6 Ma and 788 ± 6 Ma, respectively. Geochemically, they are peraluminous (A/CNK mostly around 1.2) and are characterized by enrichments in Rb, Th, REEs and HFSEs (e.g. Zr and Y) but depletions in Ba, Sr, P, Eu and Ti. The volcanic rocks show a clear A-type granite geochemical signature with high total alkalis (K 2 O + Na 2 O = 5.3–7.64 wt%), FeO t /MgO ratios and low CaO, MgO and TiO 2 contents. They have negative whole-rock ε Nd (t) (−4.2 to −1) and positive zircon ε Hf (t) (+1.26 to +11.6) values, illustrating decoupled Nd-Hf isotopes which may be genetically related to their petrogenesis process. The positive ε Hf (t) values and juvenile T Hf DM1 (0.89–1.3 Ga) of zircons indicate that the volcanic rocks may have been derived from the partial melting of the Neoproterozoic to late Mesoproterozoic crustal materials. Combined with the occurrence of significant volumes of contemporary bimodal volcanic rocks in eastern section of the Jiangnan orogen, it is inferred that the Jingtan felsic volcanic rocks formed during post-collisional extension shortly after the final amalgamation of Yangtze and Cathaysia blocks. [ABSTRACT FROM AUTHOR]

Xenotime (YPO4) is a trace component in many metasedimentary and some igneous rocks, altered rocks and many hydrothermal ore assemblages, where it forms in response to a range of different processes from igneous crystallisation to low-temperature early diagenesis. Due to its wide range of formation temperatures, its suitability and isotopic robustness for reliable U-Pb geochronology, dissolution/precipitation characteristics during overprint events, and widespread occurrence, it is one of the most valuable minerals for U-Pb geochronology leading to four-dimensional (4D) studies of many terranes. The formation environment of xenotime can be deduced from careful petrography and reliable U-Pb in-situ geochronology within a 4D framework. Further, xenotime is a physically robust mineral during sediment transport and may carry distinctive geochemical fingerprints, including age, to secondary environments. From published works, we review the U-Th-contents of well-characterised examples of xenotime formation to provide chemical fingerprints, which assist in identifying the xenotime formation environment. Although the U-Th characteristics of xenotime from all formation environments show considerable overlap, we make the following observations which may be distinctive of some ore formation environments: (i) hydrothermal xenotime formed from low salinity ore fluids (e.g. iron ore and orogenic gold deposits) trend to have the lowest U-contents (< 100 ppm U) and U/Th (< 4), in contrast to xenotime formed from higher salinity ore fluids (Sn-W and base metal deposits); (ii) xenotime associated with unconformity-related U-ores have the highest U-contents at U/Th > 10; (iii) diagenetic xenotime has the most variable and highest U/Th, whereas (iv) xenotime from Precambrian orogenic gold deposits has the least variable and lowest U/Th. Petrogenetic inferences from these observations for ore deposit research and exploration include: (i) support for the homogenising effect of the crustal scale of the fluid system in Precambrian orogenic gold deposits, and (ii) the potential for distinctive U-Th geochemical fingerprints for U ores and some Au ores. These characteristics may be reflected in detrital xenotime grains recovered from routine exploration sampling programs. [ABSTRACT FROM AUTHOR]

Subduction of sediments affects the composition of the Earth's mantle and the formation of melts in subduction zones. The sediment thickness of ~8 km along the Hellenic Trench is the largest observed globally and significant volumes of these sediments are subducted. Magmas erupting in the Aegean Arc reflect sediment subduction but they also assimilated sediments during ascent, making distinction of the two processes difficult. In this study, we present geochemical data from olivines in lavas and enclaves from the peninsula of Methana in the western Aegean Arc. The olivines have high forsterite (Fo) contents of 90–92% and contain Cr-spinel with Cr# >60 originating from a primitive melt in equilibrium with a highly depleted mantle wedge. The high δ 18 O VSMOW of ~6.5‰ of the olivines imply input of up to 6.5% sediment component into the mantle wedge. Incompatible element and radiogenic isotope ratios suggest that the sediment component is added as a carbonate-rich melt. Low Ni contents and small rounded sulphide inclusions in the Fo-rich olivines indicate the formation of an immiscible sulphide liquid during olivine crystallization. The input of carbonate-rich sediment reduced the mantle and the co-existing primitive melts, and possibly added S leading to sulphide saturation. This study shows that olivine crystals and their inclusions provide important insights into the mantle wedge, sediment subduction and its effects on the primary magma composition and can indeed be used to distinguish between a mantle and crustal origin of the sediment signature. [ABSTRACT FROM AUTHOR]

Measurements of TOC, Rock-Eval pyrolysis, carbon isotope composition, solvent extract, extract fractionation, and the gas chromatography-mass spectrum (GC-MS) of the saturated fraction were conducted on the Lower Permian Fengcheng Formation carbonate-bearing shales and argillaceous dolomites of Well FN7 in the northwestern Junggar Basin to understand the geochemistry and depositional environmental evolution of the carbonate-bearing lacustrine source rocks. The results indicate that the Fengcheng Formation carbonate-bearing shales are fair to good source rocks with Type II kerogen for generating oil and minor gas, and the argillaceous dolomites are poor source rocks. The thermal mature shales contain more residually generated hydrocarbon, whereas the argillaceous dolomites contain more migrated hydrocarbon. This property is favorable for shale oil or tight oil accumulation in the Fengcheng Formation. Biomarker analyses indicate that the Fengcheng Formation source rocks were formed in the anoxic reducing lacustrine depositional environment with a stratified water column and high salinity. The source rock organic matter has major aquatic phytoplankton and algae input and less terrestrial organic matter input. During the Fengcheng Formation period, oxidation had a weak increasing tendency and salinity had a weak decreasing tendency from the early to late periods under the background of a reducing environment. Except for poor source rocks in upper and lower parts, the good source rocks are primarily in the middle part of the Fengcheng Formation. [ABSTRACT FROM AUTHOR]

Constructing an accurate timeline is critical for reconstructing the Earth systems through critical transitions in climate, geochemistry, and life. Existing dates constrain synchronous initiation (ca. 717 Ma) and termination (ca. 660 Ma) of the Sturtian glaciation from multiple continents. The termination of the younger Marinoan glaciation is also well dated at ca. 635 Ma, but the onset of this glaciation is only roughly constrained as ≤ ca. 654 Ma (South China) and ≥ ca. 639 Ma (Namibia). To test if the Marinoan glaciation started close to ca. 654 Ma or ca. 639 Ma, we have conducted a cyclostratigraphic study on the Cryogenian non-glacial Datangpo Formation that conformably overlies and underlies Sturtian and Marinoan glacial diamictites, respectively, in a deep-water basin section in South China. A total of 28,765 magnetic susceptibility (MS) measurements from a drillcore of the 292-m-thick, muddy siltstone- and shale-dominated Datangpo Formation are used for cyclostratigraphic analysis. The results reveal significant decameter- to meter-scale sedimentary cycles of 16–12 m, 3.6–3.0 m, 1.0–0.8 m, and 0.6–0.4 m. The ratios of these cycle wavelengths match well with those of the Milankovitch cycles calibrated for the Cryogenian Period. The established astrochronologic time scale suggests that the duration of the Datangpo Formation is about 9.8 million years. Together with the radiometric age of ca. 660 Ma for the termination of the Sturtian glaciation, the cyclostratigraphic data suggest that the Nantuo (Marinoan) glaciation in South China initiated at ca. 650 Ma, which is slightly younger than but consistent with the ca. 654 Ma U–Pb age from the top of the Datangpo Formation in shelf sections. This age, however, is significantly older than the ages obtained from Marinoan-age glacial diamictites in South China (ca. 636 Ma) and Namibia (ca. 639 Ma). Given that most of the shelf sections may have suffered from glacial erosion, obtaining the onset age of the Marinoan glaciation should focus on relatively complete, deep-water successions. [ABSTRACT FROM AUTHOR]

Source rock screening analysis was performed on four stratigraphic units from the Muglad basin namely; Abu Gabra, Zarqa, Ghazal, and Baraka formations using pyrolysis and Vitrinite Reflectance (Ro). Results, integrated with the chromatographic and isotopic data from these rocks extracts and a Tertiary oil from El Mahafir-1 wild cat, were used to determine the origin of the oil. A good organic source within the Middle Abu Gabra Formation is observed in wells El Toor-6 and Neem Deep-1 (TOC, 1.0–2.0% & S2 5.0–10.0 mg C/g rock), with mixed kerogens I, II, & III, and thermally mature (% Ro = 0.74–0.94). The Campanian-Early Maastrichtian sequence, i.e. Zarqa and Ghazal formations are generally poor (TOC, <0.5% & S2 <2.5 mg C/g rock), dominated by type III kerogens, and immature at the studied locations. The Baraka shale nevertheless, is good at El Mahafir-1 well (avg. TOC 1.8% & S2 5.0–10.0 mg C/g rock) and fair at Timsah-1 well (Avg. TOC 0.69% & S2 2.5–5.0 mg C/g rock) with a Kerogen that is predominantly Sapropellic at the former, and an exclusively Humic at the later. The formation is mature at Timsah (% Ro = 0.77–1.16) and early mature at El Mahafir-1 (% Ro = 0.64–0.81). Consistent with the pyrolysis, chromatographic data of the rock extracts confirms the mixed source nature of the Abu Gabra Formation which consists of both algal [prominent LMW n-alkanes & elevated C 27 steranes (36–47%)], as well as terrigenous material [higher diasterane/regular sterane ratios (0.50–0.56), abundant rearranged hopanes, & relatively high CPIs (1.22–1.9)], accumulated in an oxic to sub-oxic environment (Pr/Ph, 1.3–3.0). Abu Gabra further shows low C 29 /C 30 hopanes (0.45–0.54), low C 28 steranes (21–26%) with high Gammacerane index (20.3). In contrast, the environment during the Late Cretaceous was strongly reducing (Pr/Ph, 0.37–1.0), associated with a wide organic diversity, both in space and time and is characterized by dominant algal input at some areas and or stratigraphic intervals [Elevated tricyclics, higher C 29 /C 30 hopanes (0.5–1.14), and relatively low Gammacerane indices (4.6–14.4)], while mixed with abundant terrigenous material at others. A direct correlation between El Mahafir oil and the Abu Gabra extracts is thus inferred based on: its mixed organic source nature, oxic to sub-oxic depositional environment (Pr/Ph 1.22), relatively low C 29 /C 30 hopanes (0.54), low C 28 steranes (29%), and a high gammacerane index (20.5). This is largely supported by the maturity modeling results which suggest generation is only from the Abu Gabra at this location. [ABSTRACT FROM AUTHOR]

New detailed lithological, sedimentological, chemostratigraphic data were obtained from exploration drilling samples on the C5 carbonate-dominated formation of the Neoproterozoic Lukala Subgroup (former Schisto-Calcaire Subgroup) from the West Congo Belt (WCB) in the Democratic Republic of Congo. This formation records the last post-Marinoan sea-level events that occurred in the whole basin, followed by the development of the Araçuaï-West Congo Orogen between 630 and 560 Ma. The C5 Formation consists of back-reef lagoonal and peritidal/sabkha cycles of ∼2.0 m in thickness, that record a short-time marine regression, rapidly flooded by a marine transgression with deposition of organic-rich argillaceous carbonates or shales under dysoxia and anoxia conditions. These dysoxic/anoxic waters were rapidly followed by a regional-scale marine transgression, favouring mixing with well-oxygenated waters, and the development of benthic Tonian to Cambro-Ordovician Obruchevella parva -type ‘seagrasses’ in the nearshore zones of the lagoons. New δ 13 C and 87 Sr/ 86 Sr isotopic data in the C5 Formation of the Lukala Subgroup are used in the frame of a correlation with the Sete Lagoas Formation in Brazil. Relatively comparable negative to positive δ 13 C excursions point to marine flooding of the whole basin and allow extension of the debatable Late Ediacaran age of the uppermost Sete Lagoas and C5 formations. Sr isotope “blind dating” failed due to low Sr concentration related to a dolomitization event close 540 Ma. Several tentative datings of the C5 Formation converge to a Late Ediacaran age ranging between 575 and 540 Ma. As the overlying Mpioka folded Subgroup, the C5 series suffered the Pan African deformation, dated at 566 ± 42 Ma. Unlike the previously generally accepted interpretation, our data suggests that the Mpioka Subgroup was deposited in the Early Cambrian. [ABSTRACT FROM AUTHOR]

Subaerial volcanic flank and floodplain facies of the 3.46 Ga Panorama Formation have been recognized on the basis of trough cross-bedded sandstones, lapilli tuffs, and abundant nodularized barite sand crystals, like those noted in other Archean non-marine facies. These barite-nodular layers are interpreted as alluvial paleosols for the following reasons. They show different degree of bedding disruption scaled to nodule size beneath a sharp upper boundary, like desert soil profiles. They show multiple generations of cracking, clay skins, and up-profile destruction of feldspar and rock fragments, compatible with weathering of labile constituents of the parent material. Loss of alkali and alkaline earth elements and phosphorus up profile are also features of chemical weathering. Geochemical mass balance calculations (tau analysis) shows that the profiles lost mass and labile elements, unlike unaltered sediments and tuffs. Rare earth element analysis also shows light rare earth retention as in weathering, as opposed to sedimentation or hydrothermal alteration. Barite of nodules in the paleosols is mobilized to concentration under very acidic conditions (pH < 3) and is very stable under less acidic conditions. These Archean alluvial paleosols may have formed by acid sulfate weathering by sulfuric acid, rather than the currently more common hydrolysis by carbonic acid. This archaic system of widespread acid sulfate weathering has since been marginalized to a few playa lakes, deep water tables, and sulfur springs. [ABSTRACT FROM AUTHOR]

Although Xujiahe Formation source rocks in the central Sichuan Basin, China were determined to have low gas-generation intensity, several large-scale gas fields have been found associated with this formation. Thus origins and formation mechanisms of natural gas in the Xujiahe Formation have attracted attentions of many researchers. In this study, geochemistry techniques were deployed to analyze natural gas and formation water in the Xujiahe Formation tight gas reservoir, central Sichuan Basin. By considering geologic background of the gas reservoir, its formation mechanism was investigated. Research results show that the Xujiahe Formation reservoir contains an independent petroleum system, with its natural gas exclusively originated from coal-measure source rocks in the Xujiahe Formation. The formation water was determined to be CaCl 2 type with high salinity. H and O isotope values are largely deviated from those of meteoric water line, indicating favorable preservation conditions for the formation water. The Xujiahe Formation is composed of multiple coal-measure source rocks and superimposed by tight sandstones. The well-developed formation water provides favorable conditions for generating water-dissolved gas. Structural movements during the Himalayan period induced significant uplifting of the central Sichuan Basin with overlying formations denudated. Consequently, natural gas dissolved in formation water experienced depressurization and exsolution. The released natural gas formed free gas phase in structural highs or provided additional natural gas supplies to existing gas reservoirs. [ABSTRACT FROM AUTHOR]

Organic-rich shale deposited in a marine-continental transitional facies was well developed in the upper Yangtze area during the Late Permian. It is considered to contain a large amount of shale hydrocarbon resources. This paper takes the Upper Permian Longtan shale in the central Guizhou uplift as an example to characterize the transitional shale reservoir. Based on organic geochemistry data, X-ray diffraction (XRD) analysis, and scanning electron microscopy (SEM) observation, the geochemical characteristics of this transitional shale were systematically studied and the shale gas potential was investigated. The results indicate that the Longtan shale has fair to good hydrocarbon potential with high total organic carbon (TOC) and contains type III gas-prone organic matter. Its high thermal maturity favors the generation of gas (Ro, 1.10%–2.74%). XRD analyses show that the mineral components of the transitional shale are dominated by high clay content (58.7 wt%). The clay minerals are dominated by illite (44%) and mixed illite/smectite (43%). SEM observation shows that intra-particle pores, inter-particle pores and microfracture were well developed in the Longtan shale, which can provide reservoir space for the accumulation of shale gas. Organic matter pores appear rare due to its organic type. In summary, the Longtan shale has high organic content, high maturation, and high gas content, all of which demonstrate its great potential as a shale-gas resource. But the high clay content of the Longtan shale may be a challenge to shale-gas production. [ABSTRACT FROM AUTHOR]

Source rock potential of 108 representative samples from 3 m intervals over a 324 m thick shale section of middle Eocene age from the north Cambay Basin, India have been studied. Variation in total organic carbon (TOC) and its relationship with loss on ignition (LOI) have been used for initial screening. Screened samples were subjected to Rock-Eval pyrolysis and organic petrography. A TOC log indicated wide variation with streaks of elevated TOC. A 30 m thick organic-rich interval starting at 1954 m depth, displayed properties consistent with a possible shale oil or gas reservoir. TOC (wt%) values of the selected samples were found to vary from 0.68% to 3.62%, with an average value of 2.2. The modified van Krevelen diagram as well as HI vs. T max plot indicate prevalence of Type II to Type III kerogen. T max measurements ranged from 425 °C to 439 °C, indicating immature to early mature stage, which was confirmed by the mean vitrinite reflectance values (%R o of 0.63, 0.65 and 0.67 at 1988 m, 1954 m, and 1963 m, respectively). Quantification of hydrocarbon generation, migration and retention characteristics of the 30 m source rock interval suggests 85% expulsion of hydrocarbon. Oil in place (OIP) resource of the 30 m source rock was estimated to be 3.23 MMbbls per 640 acres. The Oil saturation index (OSI) crossover log showed, from a geochemical perspective, moderate risk for producing the estimated reserve along with well location for tapping the identified resource. [ABSTRACT FROM AUTHOR]

The Eğrikar Fe–Cu skarn type mineralization is located approximately 100 km NW of Gümüşhane in NE Turkey. Geochemical analyses of diorite, which is thought to cause skarn, indicate medium K calc-alkaline (1.3 to ~ 2.3 wt% K 2 O), metaluminous to peraluminous (A/CNK = 0.76 to 1.13) and resembles a continental arc granite. The age of U–Pb zircon obtained from diorite is 42.3 ± 1.0 Ma, which reflects the age of skarn metasomatism after intrusion into Late Cretaceous sandy carbonates. Skarn formation zones are recognized as endo - and exoskarn. The endoskarn zone mainly consists of pyroxene with hedenbergite (Di 4.31–28.14 Hd 59.29–80.82 Jo 5.0–35.55 ) at prograde stage. Mn content of pyroxene increases a slight from endo to exoskarn. Pyroxene is replaced by epidote and hornblende at the retrograde stage. The exoskarn zone comprises garnet with andradite (Ad 91-99 Gr 01–07 ) and grossular-andradite (Ad 44-95 Gr 05–54 ), epidote and quartz as silicate minerals, and magnetite and hematite as ore minerals. Magnetite is the abundant ore mineral and is accompanied by chalcopyrite and minor pyrite at retrograde stage. On the basis of fluid inclusion values of minerals, the temperature range for hedenbergite in endo -exoskarn is 350 °C–425 °C, for epidote in exoskarn is 365 °C–376 °C, and for quartz in exoskarn 200 °C–380 °C. NaCl equivalent salinity for hedenbergite 6.88–10.73 wt% and for quartz is 3.9–15.38 wt. The δ 18 O values of hedenbergite is 4.1 to 4.7‰ and for garnet 3.4‰ at prograde stage, for epidote 7.9–9.2‰, for magnetite 1 to 4.4‰, for hematite − 2.9 to − 1.6‰ and for quartz range between 8.5‰ and 15.2‰. The δ 18 O value of epidote suggests that oxygen is a magmatic fluid whereas hedenbergite, garnet, quartz and magnetite show the mixing of magmatic and meteoric fluids. In addition, the C isotope values (− 3.2 to 2.8‰) of calcite and marble in Eğrikar Fe–Cu skarn reflect those of metamorphic, and skarns. Based on oxygen isotope data from mineral pairs, the retrograde skarn formation is characterized by epidote–magnetite assemblage formed at 255 °C–438 °C. Fluid oxygen isotope compositions of magnetite and epidote pairs of the exoskarn skarn zone indicate a mixing of magmatic and meteoric fluids with narrow δ 18 O values between 7.17‰ and 8.9‰. The δ 34 S values of the pyrites exhibit a narrow range of 3‰ and 4.4‰, thereby indicating that sulfur were probably leached from magmatic rocks. Based on the field and laboratory observation, mineral chemistries, fluid inclusion studies and isotope composition analysis, it is suggested that the Eğrikar Fe–Cu skarn mineralization occurs in a magmatic origin fluids being initially under reduced conditions, subsequently under oxidized conditions, and at shallow depth. [ABSTRACT FROM AUTHOR]

A combined investigation of bulk geochemistry and molecular geochemistry was carried out on 31 source rock samples from the Lower Permian Lucaogou Formation, in the Jimsar Sag of the Junggar Basin, northwestern China. Geochemical characterization reveals the depositional environments and other factors favorable for the generation and accumulation of β-carotane, an important hydrocarbon precursor. Many core samples have a total organic carbon content > 1%, and Rock-Eval S 2 values > 2 mg HC/g rock, suggesting relatively high hydrocarbon generation potential. Biomarkers in the Lucaogou source rock extracts are characterized by short- to long-chain n-alkanes, a wide range of Pr/Ph ratios (0.74–1.42) and β-carotane index values (β-carotane/C max , 0.16–1.92), high concentrations of C 29 sterane, relatively low tricyclic terpane content, and moderate gammacerane index values (0.14–0.29). This is consistent with a weakly oxidizing to weakly reducing depositional environment, with fresh to brackish water conditions, rapid input of terrigenous organic matter, and a relatively small contribution of aquatic algal-bacterial organic matter. Cross-plots of biomarker parameters and the β-carotane index show that β-carotane in the Lucaogou source rocks is mainly derived from terrigenous organic matter, and is found predominantly in sediments deposited in weakly reducing, brackish environments. It does not appear to have been affected by thermal maturation. [ABSTRACT FROM AUTHOR]

An integrated study using bulk chemical composition, mineralogy and mineral chemistry of sedimentary rocks from the Tukau Formation of Borneo Island (Sarawak, Malaysia) is presented in order to understand the depositional and tectonic settings during the Neogene. Sedimentary rocks are chemically classified as shale, wacke, arkose, litharenite and quartz arenite and consist of quartz, illite, feldspar, rutile and anatase, zircon, tourmaline, chromite and monazite. All of them are highly matured and were derived from a moderate to intensively weathered source. Bulk and mineral chemistries suggest that these rocks were recycled from sedimentary to metasedimentary source regions with some input from granitoids and mafic-ultramafic rocks. The chondrite normalized REE signature indicates the presence of felsic rocks in the source region. Zircon geochronology shows that the samples were of Cretaceous and Triassic age. Comparable ages of zircon from the Tukau Formation sedimentary rocks, granitoids of the Schwaner Mountains (southern Borneo) and Tin Belt of the Malaysia Peninsular suggest that the principal provenance for the Rajang Group were further uplifted and eroded during the Neogene. Additionally, presence of chromian spinels and their chemistry indicate a minor influence of mafic and ultramafic rocks present in the Rajang Group. From a tectonic standpoint, the Tukau Formation sedimentary rocks were deposited in a passive margin with passive collisional and rift settings. Our key geochemical observation on tectonic setting is comparable to the regional geological setting of northwestern Borneo as described in the literature. [ABSTRACT FROM AUTHOR]

The origin of anhydrite caprocks found in many evaporite basins is currently under debate. Existing models in the literature for anhydrite formation include rotated stratigraphic layering, rotated crestal caprock and diagenetic anhydrite. In this work, we interpret high-quality 2D seismic reflection data to understand the processes associated with anhydrite caprock formation. Our study focuses on anhydrite caprock formation in the Tromsø Basin, which represents one of several underexplored salt basins in the Arctic. We use well log data and seismic stratigraphic as well as seismic attribute analyses to characterize the ‘anhydrite’ layers associated with salt diapirs. Our results reveal that the anhydrite layers are high-amplitude reflections at the crests, which are often found close to the seabed and lateral caprocks on the flanks of salt diapirs. A third class of anhydrite layers is folded, faulted and boudinaged intrasalt stringers encased by the salt diapirs. Lateral caprocks in the Tromsø Basin are formed in response to rotated crestal caprock failure. The crestal caprocks are secondary in origin, occur at shallow depths, and are formed as insoluble residues from the dissolution of halite by the ingress of basinal fluids into the tops of diapirs. Anhydrite stringers, or floaters, originate from tectonic-related multi-dimensional salt flow. Salt diapirs in the Tromsø Basin are associated with varied anhydrite caprocks; their formation cannot be fully explained using a single model. Our work demonstrates from seismic reflection data the occurrence of caprock events that formed progressively on the flanks of salt diapirs due to local folding. [ABSTRACT FROM AUTHOR]

The orbicular granitoid of Caldera, located at the northern part of the Chilean Coastal Range, is a spectacular example of radial textures in orbicular structures. The orbicular body crops out as a 375 m 2 tabular to lensoidal intrusive sheet emplaced in the Lower Jurassic Relincho pluton. The orbicular structures are 3–7 cm in diameter ellipsoids hosted in a porphyritic matrix. The orbicules are comprised by a Qtz-dioritic core (3–5 cm in diameter) composed by Pl + Hbl + Qtz + Bt ± Kfs with equiaxial textures and a gabbroic shell (2–3 cm in diameter) characterized by feathery and radiate textures with a plagioclase + hornblende paragenesis. The radial shell crystals are rooted and orthogonally disposed in the irregular contact with the core. The radial shell, called here inner shell, is in contact with the granodioritic equiaxial interorbicular matrix through a 2–3 mm wide poikilitic band around the orbicule (outer shell). The outer shell and the matrix surrounding the orbicules are characterized by the presence of large hornblende and biotite oikocrystals that include fine-grained rounded plagioclase and magnetite. The oikocrystals of both the outer shell and the matrix have a circumferential arrangement around the orbicule, i.e. orthogonal to the radial inner shell. The coarse-grained granodioritic interorbicular matrix present pegmatitic domains with large acicular hornblende and K-feldspar megacrysts. This work presents a review of the textural characteristics of the orbicules and a complete new mineral and whole-rock geochemical study of the different parts of the orbicular granitoid, together with thermobarometric and crystallographic data, and theoretical modeling of the crystallization and element partitioning processes. We propose a model for the formation of the orbicular radial textures consisting of several processes that are suggested to occur fast and consecutively: superheating, volatile exsolution, undercooling, geochemical fractionation and columnar and equiaxial crystallization. According to the obtained results, the formation of the orbicular granitoid of Caldera may have initiated 1) during the generation of a magmatic fracture in the crystallization front of the Relincho pluton, where the water released by the host crystal mush was dissolved in the new batch of dioritic magma. 2) The high influx of water-rich liquids induced superheating conditions in the newly intruding magma that became a depolymerized liquid, where the only solid particules were the small irregular fragments of the host mush dragged from the fracture walls. 3) Volatile exsolution promoted crystallization under undercooling conditions. 4) Undercooling and nucleation around the core (cold germs) involved the physical and geochemical fractionation between two sub-systems: a gabbroic sub-system that comprises the solid paragénesis with a residual water-rich liquid and a granodioritic sub-system. 5) The orbicules, including core and inner shell, behaved as viscous bodies (crystals + residual liquid) floating in the granodioritic magma. 6) Higher undercooling rates occurred at the starting stage, close to the liquidus, promoting columnar crystallization around the cores and formation of the shells. Conversely, in the granodioritic matrix sub-system, equiaxial crystallization was promoted by low relative crystallization rates. 7) The rest of the crystallization process evolved later in the outer shell and the matrix, as suggested by the poikilitic textures observed in both sides of the orbicule contact, and under conditions close to the solidus of both sub-systems (shell and matrix). The water-rich residual liquid expelled during the orbicular shell crystallization was mingled with the partially crystallized matrix magma, generating the pegmatitic domains with large Kfs megacrysts. [ABSTRACT FROM AUTHOR]

Understanding the geological history of the Lhasa Terrane prior to the India–Asia collision (~ 55 ± 10 Ma) is essential for improved models of syn-collisional and post-collisional processes in the southern Lhasa Terrane. The Miocene (~ 18–10 Ma) adakitic magmatism with economically significant porphyry-type mineralization has been interpreted as resulting from partial melting of the Jurassic juvenile crust, but how this juvenile crust was accreted remains poorly known. For this reason, we carried out a detailed study on the volcanic rocks of the Yeba Formation (YF) with the results offering insights into the ways in which the juvenile crust may be accreted in the southern Lhasa Terrane in the Jurassic. The YF volcanic rocks are compositionally bimodal, comprising basalt/basaltic andesite and dacite/rhyolite dated at 183–174 Ma. All these rocks have an arc-like signature with enriched large ion lithophile elements (LILEs; e.g., Rb, Ba and U) and light rare earth elements (LREEs) and depleted high field strength elements (HFSEs; e.g., Nb, Ta, Ti). They also have depleted whole-rock Sr–Nd and zircon Hf isotopic compositions, pointing to significant mantle isotopic contributions. Modeling results of trace elements and isotopes are most consistent with the basalts being derived from a mantle source metasomatized by varying enrichment of subduction components. The silicic volcanic rocks show the characteristics of transitional I–S type granites, and are best interpreted as resulting from re-melting of a mixed source of juvenile amphibole-rich lower crust with reworked crustal materials resembling metagraywackes. Importantly, our results indicate northward Neo-Tethyan seafloor subduction beneath the Lhasa Terrane with the YF volcanism being caused by the initiation of back-arc rifting. The back-arc setting is a likely site for juvenile crustal accretion in the southern Lhasa Terrane. [ABSTRACT FROM AUTHOR]

The Yanchang Formation in the Ordos Basin is the most important petroleum play not only for conventional oil and gas accumulations, but also for newly emerging shale oil and tight gas resources. The molecular characterization of the basinwide source rocks predicts three groups of generative petroleum types: Paraffinic High Wax Oil, mixed base (Paraffinic-Naphthenic-Aromatic) Low Wax Oil, and Gas and Condensate. Supplementary to previous work, 68 samples including the crude oils, source bitumens and reservoir extracts from the Yanchang petroleum play are analyzed. The distribution of two terpane classes (eight tricyclic terpanes and eight pentacyclic terpanes) are determined with subsequent simultaneous RQ-mode factor analysis for a composite data set of these samples alongside 216 published crude oils worldwide with known facies descriptions. Thermal maturity has been evaluated as a consistent distribution at first using a combined method of a maturity-related biomarker [Ts / (Ts + Tm)] and aromatic parameters (Methyldibenzothiophene Ratios) to alleviate the maturity differences effect when discussing geochemical characterization. The R-mode factor analysis consists of the first two factors that are describing 45 present of the cumulative total variance in the data set, and presents a sample grouping pattern in Q-mode factor analysis which is determined by different contributions of terpane associations, i.e., the tricyclic C 21 coupled with pentacyclic C 26 , C 27 , C 28 and C 30 , in the same factor space. Three terpane associations, the C 26 and C 28 terpanes, the C 21 and C 30 terpanes and the C 27 pentacyclic terpenes, are respectively responsible for discriminating crude oil, reservoir extracts and source bitumens in RQ-mode factor analysis. Molecular compositions further address more detailed interrelationships among three sample groups that crude oils and reservoir extracts are sharing close genetic relationships both in depositional environment typing and C 27 -C 28 -C 29 sterane distribution. Samples from source rocks vary much significantly. A mixing process which occurs after oils has been expelled from host source rocks into carrier units during accumulation. In addition, the migration-contamination of C 29 sterols when oils are cross through the Chang 7–2 unit along migration pathways might also explain this lack of correlation between source rocks and oil-reservoir system. [ABSTRACT FROM AUTHOR]

The Cayman Formation (Miocene), ~ 140 m thick on Grand Cayman, is incompletely dolomitized with the most of the dolomite restricted to the peripheral part of the island. These calcium-rich dolomites, with 50–60 mol%CaCO 3 (%Ca), are divided into low-calcium dolomite (LCD, %Ca < 55%) and high-calcium dolomite (HCD, %Ca > 55%). Despite the small size of the island (6.8 km wide), the percentages of LCD and HCD, the %Ca, and the geochemical properties of the dolomites show geographic variations relative to the surrounding shelf edge. Accordingly, the Cayman Formation on the east end of the island is divided into the peripheral dolostone (shelf edge–1.5 km inland), transitional dolostone (1.5–2.7 km inland), and the interior limestone and dolostone (2.7 km to island center). From the peripheral dolostone to the interior limestone and dolostone, there is an increase in the percentage of HCD and %Ca in the dolomite, and decreases in the δ 18 O and δ 13 C values of the dolomite. Interpretations based on the oxygen and carbon isotopic compositions indicate that seawater is the source of Mg for dolomitization. The concentric pattern of dolomitization on the island reflects the fact that seawater flowed into the island from all directions during dolomitization. The lateral inland variations in the dolomite stoichiometric and isotopic properties reflect the gradual modification of seawater by water-rock interaction along the flow path from the shelf edge to the island center. 87 Sr/ 86 Sr ratios indicate that two phases of dolomitization (late Miocene–early Pliocene and late Pliocene–early Pleistocene) were responsible for dolomitization of the Cayman Formation. It is very likely that during both phases, the carbonate platform was subaerially exposed and that the pump for circulating the seawater through the island was related to the seawater/freshwater mixing zone. The dolomitization model developed from Grand Cayman may be applicable to many other island dolostones affected by long-term sea-level changes. Given that the diagenetic potential of dolostone is directly linked to its stoichiometry, the distribution of the LCD-HCD will influence the petrographic properties, geochemical signatures, and reservoir potential of the dolostones. [ABSTRACT FROM AUTHOR]

Continental breakup in magma-poor rifted margins can develop, in some instances, after the formation of a wide exhumed domain that can be several hundreds of km wide. As exhumation of the continental mantle occurs serpentinization, due to seawater circulation, can extend as far down as 5–6 km, as observed in refraction seismic data. The impact caused by the process of serpentinization within the evolving ocean may have the potential to change: (i) seawater chemistry; (ii) sustain the evolution of primitive life; (iii) control depositional environments; and (iv) form weak zones preferentially used during the formation, reactivation and subduction of distal rifted margins. Based on geological observations, and geophysical and geochemical data from present-day and fossil zones of exhumed continental mantle, we present a first-order quantification showing that approximately 0.380 km 3 of water per km 2 can be stored in the mantle. Using simple methods, it can be shown that serpentinization may account for a significant loss of Si, Mg, Fe, Mn, Ca, Ni and Cr during serpentinization of mantle rocks. In particular during latest stages of rifting, when basins are often restricted and seaways are not yet connected, exhumation and the serpentinization of large areas of continental mantle may result in a major transfer of elements between the main Earth reservoirs, such as the mantle and seawater. [ABSTRACT FROM AUTHOR]

Precambrian banded iron formations (BIFs) represent an important source of mineable iron, as well as an archive recording secular changes in the chemistry of the Earth’s early oceans. Here we report petrographic and geochemical characteristics of unweathered drill core samples from the Bikoula BIF, a virtually uncharacterized oxide facies iron formation, hosted in the Mesoarchean Ntem complex, southern Cameroon. The BIF is cross-cut with syenitic veins. The entire succession is highly deformed and metamorphosed under granulite facies conditions. The BIF is characterized by alternating micro-bands of magnetite, quartz and pyroxene. Sulfides (pyrite, pyrrhotite, and chalcopyrite), oligoclase, ferro-pargasite, biotite and ilmenite occur as minor phases. The presence of pyroxene, ferro-pargasite and oligoclase, relatively high contents of major elements such as Al 2 O 3 (0.76–7.52 wt.%), CaO (1.95–4.90 wt.%), MgO (3.78–5.59 wt.%), as well as positive correlations among Al 2 O 3 , TiO 2 , HFSEs, LILEs and transition metals (V, Cr, Ni, Cu and Zn), suggest that the BIF protolith included a significant amount of clastic material. Several samples have preserved seawater-like PAAS-normalized REE-Y patterns, including LREE depletion, and positive La and Y anomalies. Positive Eu anomalies observed in some of the analyzed samples indicate influx of hydrothermal fluids (possibly including Fe and Si) within the basin where the BIF precipitated. However, few samples show unusual negative Eu anomalies that likely result from a large proportion of clastic contamination. The lack of Ce anomalies suggests that the Bikoula BIF was deposited in a basin that was (at least partly) anoxic or suboxic, where it was possible to transport and concentrate dissolved Fe 2+ . [ABSTRACT FROM AUTHOR]

The Mn-Ba-Pb deposit at Aspro Gialoudi in NW Milos is shown to be a fossil inhalative-exhalative hydrothermal deposit that represents the deepest part of the Vani succession at the western extremity of the main Vani manganese deposit. The geology of the Vani-Aspro Gialoudi area is characterized by Upper Pliocene-Lower Pleistocene dacitic and rhyodacitic lava domes, which are overlain by the Vani volcaniclastic unit considered to be part of the 2.66–1.44 Ma magmatic event at Milos Island. The presence of in-situ and intrusive hyaloclastite breccias surrounding the coherent lava domes at Aspro Gialoudi and Vani areas indicates submarine emplacement for the domes. The dacitic-rhyodacitic domes are variously altered (mainly propylitic and/or argillic alteration, silicified and in some cases locally exhibiting adularia alteration). Both Aspro Gialoudi and main Vani deposit are located proximal to fault systems: the main Vani manganese deposit is adjacent to the NW-trending Kondaros-Katsimouti-Vani Dome fault, whereas the Aspro Gialoudi deposit is adjacent to the relatively minor NE-trending fault on the west coast of Milos. At Aspro Gialoudi, mineralization took place in a subseafloor and/or seafloor environment and is characterized by a stratabound Mn-barite-rich deposit mainly within a package of propylitized intrusive hyaloclastites and within the overlying sandstones. Banded epithermal veins trending NE-SW and composed of chalcedonic silica/quartz + barite + Mn-oxide ± sulfides crosscut the dacitic lavas, the hyaloclastites and the overlying volcaniclastic sequence at Aspro Gialoudi and are considered to represent the feeder zones of the manganese-barite mineralization. Within the veins, early sulfide (galena-sphalerite) barite and quartz deposition is followed by manganese oxides and aragonite, thus resembling the epithermal-style Pb-Zn-Ag-Mn mineralization across the NW-trending Katsimoutis-Kondaros-Vani fault. Mineralization in Aspro Gialoudi and Vani deposits seems to be controlled by alternating cycles of deposition of sulfides and hydrothermal manganese oxides within the faults. Manganese deposition in both deposits formed in a similar manner, namely by transport of hydrothermal fluids through the adjacent fault systems into a reservoir of volcanoclastic sandstone and hyaloclastites to produce a deposit initially consisting of principally of pyrolusite and occasionally ramsdellite, which were subsequently replaced by cryptomelane, hollandite, coronadite and hydrohaeterolite. Precipitation of hydrothermal manganese oxides took place very quick and under microbial Mn(II) oxidation. Compositional data show that metallic elements most enriched in the Aspro Gialoudi and Vani manganese deposits relative to the average continental crust, lie in the sequences Pb > Cd > Mn > As > Sb > Zn > W > Tl > Ba > Cu > Mo > Co > Bi and As > Sb > Pb > Mn > Tl > Cd > Zn > W > Cu > Ba > Mo > Co, respectively. Mineralogical and geochemical (e.g. REE) data from both Aspro Gialoudi and main Vani deposit are taken to indicate mainly a seawater source for the hydrothermal fluids. These two deposits are genetically and spatially related to base- and precious metal intermediate-sulfidation epithermal mineralization. They formed successively by similar processes and are considered to be integral parts of the same hydrothermal system. [ABSTRACT FROM AUTHOR]

The Kouambo iron deposit contains banded iron formations (BIFs) and is located in the northwestern margin of the Congo craton. The BIFs are hosted in Palaeoproterozoic Nyong series, a dominantly metasedimentary formations, which were metamorphosed into greenschist to granulite facies. The Kouambo BIFs are medium- to coarse-grained banded rocks consisting of alternation of Si-rich and Fe-rich mesobands, and belong to oxide facies iron formations. Geochemistry analyses reveal that these iron formations are composed of > 96 wt% Fe 2 O 3 and SiO 2 and have low concentrations of Al 2 O 3 , TiO 2 and trace HFSE, suggesting chemical precipitates of silica and iron. Moreover, these BIFs have low concentrations of Al 2 O 3 , TiO 2 and trace HFSEs (high field strength elements, e.g., Zr, Hf, Ta, Pb and Th), suggesting that terrigenous detrital materials contributed insignificantly to the sedimentation. The Post-Archean Australian Shale (PAAS)-normalized REE-Y patterns display seawater-like profile: minor LREE depletion and HREE enrichment, positive Y anomalies. However, they display positive Eu and negative Ce anomalies, and low Y/Ho ratio (average 29), which suggest the influence of the hydrothermal fluids. The weak positive Eu/Eu*( PAAS ) ratio (average 1.5), associated with the low V (17.5 ppm), Co (6.1 ppm) and Ni (27.5 ppm) contents similar to other Superior-type BIFs worldwide, are consistent with the deposition of the Kouambo BIFs in continental marginal sea or back-arc basin environment. In summary, the Kouambo BIFs show a seawater-like REE + Y signature, however, the positive Eu anomalies and reduced Y/Ho ratios relative to seawater indicates a possible mixing with hydrothermal fluids (∼ 0.5%). [ABSTRACT FROM AUTHOR]

The hinterland of Campo is marked by Archean, Paleoproterozoic, and Cretaceous geological formations. Petrographic, mineralogical and geochemical analyzes of beach sediment samples were performed to determine the origin, alteration, and paleoclimate of the various coastal sediment layers and to reconstruct the structural context of the source region. The beach sediments are fine to medium-grained in size. Morphoscopic examination showed a predominance of very angular and shiny quartz grains. These data reflect a relatively close source with transport in a fluvial environment. The Chemical Index of Alteration (CIA: average = 79.94%), Plagioclase Index of Alteration (PIA: average = 85.31%), as well as the A–CN–K and (A-K)-C-N triangular diagram, show that the weathering affected the source area rocks. The ratios of SiO 2 /Al 2 O 3 , K 2 O/Na 2 O, and the chemical composition variation index (ICV ∼ 1.32) show that the sediment samples are immature to mature in terms of texture and chemical composition. Al 2 O 3 /TiO 2 ratio values ranged from 3.04 to 33.44, indicating an intermediate to felsic rock signature, confirmed by Zr vs TiO 2 , La/Sc, and Th/Co binary diagrams. Geochemical results reveal a passive marginal continental environment. The passive margin emerged during the opening of the South Atlantic Ocean, which is compatible with the overall geology and structural setting of the studied area. • Campo beach sediment textural vary from clays to silt. • Beach sediments derived from moderate to intense source area weathering. • The source rocks vary from felsic to mafic rocks. • Campo beach sediments are compositionally immature to mature. • The source rock is controlled by sedimentary processes and diagenetic impacts. [ABSTRACT FROM AUTHOR]

The long-standing dilemma between two extremes in palaeogeographic interpretation is resolved for the basal 115 m of the eastern exposures of the Lower Cretaceous Bhuj Formation, at the top of the hydrocarbon prospective Mesozoics of Kutch, India. An explicit record of a mega-scale event of relative sea level rise is found sandwiched between two fluvial stratigraphic intervals that amalgamate only at the eastern extremity of the exposure of the Formation. A localized estuary in the middle had its axis roughly parallel to the pre and post-inundation river channels, although a tributary made a significant detour. Variation in the fine sandstone-mudstone lithology documents decline in depositional energy in the mid-estuary amenable to coal formation. Sediment within the estuary had been routed through both the ends, palaeocurrent turning shore-parallel only at the estuary-mouth. Exception arises in case of some isolated lenses of very poorly sorted and coarse-grained deposits depicting flash floods in the tributary. Burrow characteristics change delicately in response to the inferred changes in the depositional scenario along the estuary. Resting on a coarsening upward ramp the initially fining and then coarsening upward estuarine succession is prograding, though not steadily. It was wave-dominated, but tide left imprint behind the estuary mouth bar gaining in intensity because of valley constriction. Macroscale changes in relative sea level, perhaps eliciting local tectonics, are recorded in the transient hysteresis in the stratigraphic trend with or without palaeocurrent diversions. The fluvial stratigraphic intervals encasing the marine interval have, in terms of architectural elements, many commonalities, but also some significant disparities. The latter indicates channel meandering in the pre-inundation period and braiding after inundation. Unlike the marine sandstones, bar-channel sandstones of the riverine deposits are distinctly less sorted, bimodal, even polymodal in grain-size distribution. Mineralogical composition identifies the sandstones as craton-derived, but their geochemical distinctions point to variation in parent rock composition under the maze of palaeogeographic overprints. [ABSTRACT FROM AUTHOR]

The Early-Middle Miocene succession in the Çankırı-Çorum Basin (ÇÇB) represents a potentially large bituminous shale resource in Turkey. In order to elucidate paleoredox conditions during deposition of the Hançili Formation and to evaluate the role of anoxia in accumulation of the organic-rich shales, a total of 70 samples were collected using channel-profile sampling strategy. Rock Eval pyrolysis data indicates that the majority of the samples have excellent generative potential. Total organic carbon (TOC) content of the Hançili ranges from 0.61 to 13.91 wt% (5.59 wt% on average). Pyrolysis data as well as microscopic and isotopic studies of the samples indicate that the organic matter in the Hançili bituminous shales is immature to early mature, predominantly oil prone (Types I and II), and algal in origin. Moreover, the isotopic (δ 13 C org ) and geochemical studies suggest that the studied samples were deposited in a lacustrine setting which is consistent with the previous sedimentological inferences. Based on average enrichment factors (EF) of redox-sensitive elements, Ni (∼2.18), V (∼1.58), Cu (∼1.47) and Mo (∼1.1) are only slightly enriched relative to the average shale, whereas U (∼0.76), Pb (∼0.71) and Zn (∼0.73) are depleted. Such an enrichment pattern for redox sensitive trace elements reflects an environment with an oxic-dysoxic water column. Well-known redox-sensitive geochemical ratios (e.g., V/(V+Ni), Ni/Co) also show small-scale fluctuations in redox conditions during deposition of the Hançili Formation. TOC-S-Fe relationships suggest that the Hançili Formation were deposited under oxic-dysoxic water conditions. However, high TOC and HI along with low OI values of the samples suggest that the samples have not weathered under oxic-dysoxic regime. To investigate the role of anoxia in accumulation of the Hançili organic-rich shales, TOC content of 41 samples were plotted against the paleoredox ratios. Lack of correlation between the TOC content and redox indicators suggests that the redox conditions were not a controlling factor in accumulation of the organic-rich shales of the Hançili Formation. Other factors such as high sedimentation rate and periodic eutrophication (e.g., algal bloom) may have influenced accumulation of organic matter (OM) and compensated for the lack of preservative anoxic conditions. [ABSTRACT FROM AUTHOR]

Hydrothermal sedimentation occurred in the Triassic Yanchang Formation, Ordos Basin, China. However, their macroscopic features at the scale of the stratum and hydrothermal sources still lack correlational research. This paper performed element geochemical study on a large number of core samples collected from the Yanchang Formation of a new drilling well located in the south Ordos Basin. The SiO 2 /(K 2 O + Na 2 O) vs. MnO/TiO 2 crossplot and Fe vs. Mn vs. (Cu + Co + Ni) × 10 ternary diagram demonstrate that the Yanchang stratum in the study area has, in general, hydrothermal components. The Al/(Al + Fe + Mn) and (Fe + Mn)/Ti ratios of the core samples range from 0.34 to 0.84 and 4.81 to 50.54, averaging 0.66 and 10.67, respectively, indicating that the stratum is a set of atypical hydrothermal sedimentation with much terrigenous input. Data analysis shows that the hydrothermal source in the study area was from the deep North Qinling Orogen around the south margin of the basin, where some active tectonic and volcanic activities took place, rather than from the relatively stable internal basin. Early Indosinian movement and volcanic activities activated basement faults around the southern margin of the basin, providing vents for the deep hydrothermal fluid upwelling. The hydrothermal indicators suggest that the study area experienced 4 episodes of relatively stronger hydrothermal activity, namely during the Chang 10, Chang 9–1, Chang 7–3 and Chang 6–2 periods. We also propose a new hydrothermal sedimentation model of hydrothermal fluids overflowing from basin margin faults, for the Yanchang Formation, which is reported here for the first time. [ABSTRACT FROM AUTHOR]

One of the most relevant characteristics of the Pennsylvanian shallow-water carbonates of the Amazonas Basin is its diverse and well preserved invertebrate fossiliferous assemblages. In order to better understand the origin of these fossil concentrations, taphonomic data were obtained along well exposed areas of the uppermost part of the Monte Alegre Formation and basal part of the Itaituba Formation, which, based on conodonts, fusulinids and palynomorphs is of Atokan age. The taphonomic data focused on invertebrate organisms were supported by petrographic analysis. The understanding of the stacking pattern of the strata in the studied section allowed the identification of five type taphofacies, which contributed in the development of regional palaeoecological models, expressed as block-diagrams. These characterize the distribution of the environmental parameters, the composition of the faunal associations and the distribution and amplitude of the taphonomic processes that created the taphonomic signatures of the bioclastic elements throughout the supratidal to lower intertidal/deep subtidal depositional environments pertinent to the studied depositional environment. The regional palaeoecological models here presented are related to the particularities of the depositional environments of the studied rocks and are exclusive for the characterization of this intracratonic basin set influenced by high frequency climatic variations. Lithofacies, biofacies and taphofacies associations also reflect depositional conditions pertinent to the studied regional context, differing from the elements observed in modern intracratonic contexts analogous to the one studied, from different sedimentary basins around the world. Therefore, invertebrate taphonomy, supported by the analysis of sedimentary facies, fulfills the purposes recommended in this work, demonstrating its potential as a tool for palaeoecological analysis in the Pennsylvanian outcropping section in the southern platform of the Amazonas Basin. [ABSTRACT FROM AUTHOR]

The Urucum iron and manganese formation (IF and MnF) in the Neoproterozoic Santa Cruz Formation, Brazil, provides unique insights into Neoproterozoic seawater and the habitat for the evolution of the Ediacaran fauna. Pure Urucum IF drill core samples, i.e. chemical sediments that are devoid of any syn- or post-depositional alteration, are reliable and robust archives of Neoproterozoic seawater proxies. They display low concentrations of rather immobile elements and shale-normalized r are e arths and y ttrium (REY SN ) patterns similar to those of modern seawater. Positive La SN and Gd SN anomalies, enrichment of heavy relative to light REY SN , negative Ce SN anomalies and super-chondritic Y/Ho ratios indicate a depositional environment dominated by open ocean water masses and oxic atmosphere–hydrosphere conditions. The REY SN patterns of manganese-rich chemical sediments from the Mn1 and Mn2 horizons, however, show significantly different REY distributions between and within these units. While REY SN patterns from the Mn2 unit are similar to those of the IF, the REY systematics of the Mn1 horizon can be subdivided into two different groups. Fe-poor group A shows rather flat REY SN patterns with large negative Ce SN anomalies, while Fe-rich group B shows insignificant to positive Ce SN anomalies, Yb SN /Pr SN ratios below unity and sub-chondritic Y/Ho ratios, suggesting that trace element distributions are controlled by the mineralogical composition rather than by sedimentation rate. Pure IF samples, reflecting Urucum seawater, yield ε Nd 0.635Ga values between −4.56 and −4.08, and are more positive than those of the MnF (−5.52 to −4.66) and associated siliciclastic rocks (−8.35 to −7.69), and are considerably more radiogenic than the crystalline Rio Apa Basement (−13.7). While clastic sediments originated from the Amazonia Craton, the dissolved REY budget of Urucum seawater was derived from terrigenous material of the nearby Neoproterozoic Brasília Belt. There is no evidence for any REY input via high-temperature, hydrothermal fluids or for REY input from a mantle source. [ABSTRACT FROM AUTHOR]

The Ediacaran period was critical in the evolution of the biosphere and ocean in the history of the Earth. Shales rich in organic matter (OM) are well developed for this period in the Yangtze Block, China, and have recently been related to shale gas exploration in South China. To date, detailed characterisation of the Ediacaran shales is not available. The present work sets out a detailed investigation of the composition and pore characteristics of samples from a shallow drill core in the Ediacaran Lantian Formation in the Lower Yangtze area, and the effects of shale composition on the pore growth are discussed. The 90-m-thick Lantian black shales are highly over-mature (equivalent vitrinite reflectance (EVRo) value approximately 4.0%) with a total organic carbon (TOC) content up to 12%. They are dominated by quartz (33–72%), generally with low clay or feldspar content (<20%) and highly varied carbonate content (up to 60%). The Lantian shales are also notable for their high pyrite content (up to 19%), suggesting a depositional environment of an anoxic water body rich in sulphates; greatly enriched OM is facilitated in deep-water environments. Bulk porosities of the shales range from 1.0% to 7.9%, and are positively correlated with TOC content. High-magnification scanning electron microscopy (SEM) images support the crucial importance of OM content on pore development. Generally, pore volume shows excellent, positive correlation with TOC content for micropores, good correlation for mesopores, and relatively poor correlation for macropores. Two samples with mostly high TOC content showed very low macropore volume and medium mesopore volume. These results suggest a close relationship between OM with relatively small pores, and enhanced compaction effect on large pores in highly OM-enriched shales. [ABSTRACT FROM AUTHOR]

A diverse and well-preserved non-marine and marine palynomorph assemblage was recovered from the Lower Cretaceous Yamama, Ratawi and Zubair formations in southern Iraq. A distinctive monospecific assemblage of the dinocyst Subtilisphaera in the Ru-19 Well, in addition to its frequent occurrence in other wells in the Zubair Formation, reflects an ecologically stressed, marginal-marine environment. This assemblage constitutes the first record of the Subtilisphaera ecozone in Iraq and Arabian realm and indeed only the second one east of Morocco. The palynofacies composition of the studied rock units has been related to previous organic geochemical analyses. Each rock unit has its own palynofacies characteristics and in general, samples dominated by amorphous kerogen have the highest total organic carbon (TOC) and hydrogen index (HI), as is the case for some samples from the studied Yamama Formation and samples belonging to palynofacies PF2 from the Zubair Formation. Samples that are mostly retrieved from the Zubair Formation, containing abundant phyoclasts, have the lowest TOC and HI values. [ABSTRACT FROM AUTHOR]

Although the annual production of shale gas in China was 13 × 10 8 m 3 in 2014, a systematic study on geochemical and isotopic characteristics of these unconventional gases has not been well addressed. In the present study, almost all shale gas samples available in China, including marine shale gas from the Wufeng-Longmaxi Formation in the Sichuan Basin (O 3 w–S 1 l) and terrestrial shale gas from Chang 7 Member (T 3 y 7 ) in the Ordos Basin, were collected and analyzed for their geochemical and isotopic compositions. The shale gas from the Wufeng-Longmaxi Shale is dry gas with an average methane content of 98.38% and records a highest content of CH 4 in the world (99.59%), which is consistent with the very high thermal maturity levels of the gas shales that have equivalent vitrinite reflectance (EqVRo) values between 2.4 and 3.6%. The δ 13 C 1 values are correspondingly heavy and record a heaviest δ 13 C 1 values (−26.7‰) for the shale gases found in the world as well. The average values of δ 13 C 1 , δ 13 C 2 and δ 13 C 3 for the Wufeng-Longmaxi shale gas are −31.3‰, −35.6‰, and −47.2‰, respectively, displaying a complete carbon isotopic reversal (i.e., δ 13 C 1 > δ 13 C 2 > δ 13 C 3 ). δ 2 H CH4 and δ 2 H C2H6 has an average value of −148‰ and −173‰, respectively, also yielding a hydrogen isotopic reversal (i.e., δ 2 H CH4 > δ 2 H C2H6 ). The Chang 7 shale has an average TOC content of 13.81% with vitrinite reflectance (VRo) values between 0.7 and 1.2%. The Chang 7 shale gas is wet gas with an average methane content of 84.90% and is rich in heavy gaseous hydrocarbons (C 2 –C 5 ). The respective values of δ 13 C 1 , δ 13 C 2 and δ 13 C 3 are −48.7‰, −36.4‰ and −31.3‰, displaying a positive carbon isotopic distribution pattern (i.e., δ 13 C 1 < δ 13 C 2 < δ 13 C 3 ). The average δ 2 H CH4 , δ 2 H C2H6 and δ 2 H C3H8 values are −256‰, −244‰ and −188‰, respectively, and are characterized by a positive distribution pattern (i.e., δ 2 H CH4 < δ 2 H C2H6 < δ 2 H C3H8 ). The differences in gas wetness and carbon and hydrogen isotopic distribution patterns between the shale gases from the Wufeng-Longmaxi and Chang 7 shale are attributed to variations in thermal maturity levels. CO 2 is present in low content in both the Wufeng-Longmaxi and Chang 7 shale gases, mostly less than 1%. δ 13 C values for the CO 2 in the Wufeng-Longmaxi Formation are between 8.9 and −9.2‰, indicating an inorganic origin from the cracking of carbonate mineral in the shales under high temperatures. In contrast, δ 13 C values of the CO 2 in the Chang 7 shale gas range from −8.2 to −22.7‰, indicating an organic origin from the thermal degradation of organic matter. Helium in both the Wufeng-Longmaxi and Chang 7 shale gases is dominantly of curst origin in terms of their R/Ra ratios that vary from 0.01 to 0.08. Positive carbon isotopic distribution pattern is typical of primitive thermogenic gas. However, it can be converted into complete or partial carbon isotopic reversal patterns due to secondary alteration. The causes that yield carbon isotopic reversal include (1) mixing of gases with the same source but different thermal maturity levels; (2) secondary cracking of oil or wet gas; (3) formation water-involved reactions; (4) gas diffusion; and (5) carbon isotope exchange between alkane gases at high temperature. Among them, carbon isotopic exchange between alkane gases at high temperature is a key factor. Nine plots have been drawn based on the shale gases from China, USA and Canada. Among them, the plot of δ 13 C 2 versus wetness demonstrates a “lying-S” shape with two inflection points on the gas wetness axis. The wetness value of 1.4% represents a critical point from pyrolytic gas (primary cracking gas) to cracking gas (secondary cracking gas) and whereas the wetness value of 6% marks the end of oil generation. On the diagram of wetness versus δ 13 C, shale gases with wetness values greater than 1.6% are characterized by positive carbon isotopic distribution pattern, whereas a complete or partial carbon isotopic reversals are observed for shale gases with wetness values less than 1.6%. [ABSTRACT FROM AUTHOR]

Organic-rich black shale of the Upper Yangtze Basin from the Late Ordovician and Early Silurian is considered an excellent source rock in South China. The formation and preservation conditions of this resource are revealed by its geochemical characteristics in this study. Geochemical indices, including redox indices (V/(V + Ni), V/Cr, V/Sc, and Ni/Co) and primary productivity indices (P/Ti and Ba/Al), and paleoclimate, clastic flux and sedimentary rate analyses are presented to investigate the accumulation mechanism of organic matter. Redox indices suggest that a stagnant, anoxic environment predominated in the Upper Yangtze Basin during accumulation of Wufeng and Longmaxi formations. In contrast, ventilated and oxygenated marine conditions pervaded the Upper Yangtze Basin during deposition of Linxiang and Guanyinqiao formations. The concentrations of V and U demonstrate that accumulation of organic matter was mainly controlled by redox conditions. Besides, such factors as clastic fluxes, fresh water inflows or a mixed deposition with a rapid sedimentary rate cannot be ignored due to their influences on organic matter enrichment and preservation. However, weak co-variance relationship of TOC content and productivity proxies, including P/Ti and Ba/Al, demonstrates that the accumulation of organic matter was not controlled by primary productivity. Results of the present study suggest a depositional model that stresses the importance of tectonic movements and glacial events on the accumulation and preservation of organic matter. The model shows that the Upper Yangtze Basin was a semi-restricted basin system influenced by the isolation of Xuefeng, but also it implies that oxygen-depleted bottom water of the basin favored the accumulation and preservation of sedimentary organic matter, resulting in the formation of organic-rich black shale. [ABSTRACT FROM AUTHOR]

Source rock formation influenced by river-delta system, especially in continental margin basins, is still poorly understood. This article aimed to reveal the effect of river-delta system on the formation of the source rock by taking the Baiyun Sag of the Pearl River Mouth Basin for example. Paleo-Pearl River began to develop since the Enping Formation, providing abundant organic matter beneficial for the formation of the source rocks in the Baiyun Sag. The main controlling factor of source rock formation in the Baiyun Sag is terrestrial organic matter supply rather than the paleoproductivity or redox conditions. Low Al/Ti and P/Ti ratios suggest low marine productivity, which may be associated with a large number of terrigenous detritus input, occupying about 43.04%–94.91%. There is a positive correlation between the oleanane/C 30 hopane ratio and the TOC value, showing that terrigenous organic matter controls the source rock formation. The size of the delta below Pearl River estuary determines the extent of terrestrial organic matter supply. Source rocks with high organic matter abundance mainly formed in delta environment, and those in neritic environment in Enping and Zhuhai Formations also have high TOC values as a result of adequate terrestrial organic matter supply. [ABSTRACT FROM AUTHOR]