1. Cobalt-doped molybdenum disulfide in-situ grown on graphite paper with excellent electrocatalytic activity for triiodide evolution.
- Author
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Zheng, Fang, Huang, Niu, Peng, Rongcheng, Ding, Yuyue, Li, Guowang, Xia, Zhifen, Sun, Panpan, Sun, Xiaohua, and Geng, Jiguo
- Subjects
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COBALT , *MOLYBDENUM disulfide , *GRAPHITE , *ELECTROCATALYSIS , *DENSITY functional theory - Abstract
Molybdenum disulfide (MoS 2 ) is considered as a promising candidate to Pt-based catalysts. Literatures report the active centers of MoS 2 locate at its edges, while the perfect in-plane domains are not active. In this study, a simple Co Mo S precursor decomposition approach is used to synthesize Co-doped MoS 2 in-situ grown graphite paper (GP) substrate. Electrochemical analyses reveal the Co-doped MoS 2 possesses excellent electrocatalytic activity comparable to Pt. Density functional theory (DFT) calculations indicate the inert in-plane S atoms neighboring the doped Co atoms become active towards triiodide reduction, as revealed by the adsorption energies ( E ad ) of iodine atom decreasing from 0.36 eV to −0.52 eV, identical with value obtained from Pt (−0.52 eV). Due to increased active sites, highly conductive of GP, and excellent electrical connection between Co-doped MoS 2 and GP substrate, the dye-sensitized solar cell fabricated using Co-doped MoS 2 /GP as counter electrode (CE) shows higher photoelectric conversion efficiency (7.26%) than those based on MoS 2 /GP CE (6.57%) and platinized F-doped tin oxide (Pt/FTO) electrode (6.87%). [ABSTRACT FROM AUTHOR]
- Published
- 2018
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