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Electrochemical mechanism of CO2 reduction mediated by NiII(tpa) (tpa = tris(2-pyridylmethyl)amine) complexes: An integral view.
- Source :
-
Electrochimica Acta . Dec2021, Vol. 400, pN.PAG-N.PAG. 1p. - Publication Year :
- 2021
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Abstract
- • Full characterization of NiII( tpa ) complexes gives information about its electronic structure which corelates with electrochemical behavior. • NiII( tpa ) complexes presented tunable redox potential for the NiII/NiI reduction. • NiII complex with more negative redox potential presented the high catalytic activity for CO 2 reduction. • Theoretical approach was useful for the analysis and description of electrochemical mechanisms. In this paper, we report the synthesis, characterization, as well as electrochemical, spectroelectrochemical, and density functional theory (DFT) calculations of a series of novel NiII complexes with a flexible tetradentate ligand, tris(2-pyridylmethyl)amine) ( tpa ). The complexes [NiII( tpa )(H 2 O)(MeCN)](BF 4) 2 , [NiII( tpa )(NO 3) 2 ], and [NiII( tpa )Cl 2 ] were studied for their ability to electrochemically reduce CO 2. These complexes were compared with the tris-chelate complex [Ni(bpy) 3 ](BF 4) 2 to understand the role of flexible tetradentate ligands containing a pyridinic ring in the electrochemical reduction of CO 2. Spectroelectrochemical experiments and theoretical studies were performed to rationalize the electrochemical reductions occurring and to predict the redox potential and pathway of CO 2 reduction. The electrochemical behavior of Ni(II) complexes with the ligand tris(2-pyridylmethyl)amine) was studied, in order to explore its ability to reduce electrochemically CO 2. Theoretical studies allowed to rationalize where the electrochemical reductions occur and predict redox potential and the pathway of CO 2 reduction. [Display omitted] [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00134686
- Volume :
- 400
- Database :
- Academic Search Index
- Journal :
- Electrochimica Acta
- Publication Type :
- Academic Journal
- Accession number :
- 153707646
- Full Text :
- https://doi.org/10.1016/j.electacta.2021.139465