Search

The photo-induced deoxygenative C2 arylation of quinoline N-oxides to 2-arylquinolines is achieved over a heterogeneous porous tubular graphitic carbon nitride (PTCN) catalyst with phenylhydrazines as arylation reagent. A wide range of quinoline N-oxides can be efficiently transformed into their corresponding 2-arylquinolines under visible light irradiation. Moreover, PTCN catalyst is easily separated and could be reused several times without loss to its original activity., (© 2024 Wiley-VCH GmbH.)

Photocatalytic (PC) CO2 reduction reaction (CO2RR) into value‐added oxygenated products is one of the most promising ways of solving climate warming change and energy crisis simultaneously. To reach higher selectivity and productivity of fuel products, it still remains great challenge in controlling both simultaneous sequential multi‐electron/proton shuttling through different transporting pathway, which determines the intermediates and final products. Consequently, a multifunctional nickel‐perylene‐carbon nitride nanosheet (NS‐P‐g‐C3N4‐Ni) are constructed rationally to strengthen the electron and proton transfer via different pathway at the same time through molecule‐level carbon backbone with excellent conductivity/charge capacity and proton transport via pendant functional group of ‐NH2 from water oxidation sites of Ni metal cluster on perylene skeleton. CO2 adsorption is enhanced and reduction energy is reduced by the complexation of N‐atom site of NS‐P‐g‐C3N4‐Ni and adjustment of co‐planarity, optimizing conduction band and band gap with energy controllable techniques. In situ FT‐IR/Raman/EPR spectra identified and verified the transformation of active intermediates (*CO2•−, *COOH and H*COO−) adsorbed on the NS‐P‐g‐C3N4‐Ni by complexation and highly selective production of formic acid (60%) is achieved. This work sheds light on the construction of effective well‐structured sites in photocatalytic CO2 reduction to produce value‐added products with higher selectivity and productivity. [ABSTRACT FROM AUTHOR]

The increasing use of fluorine‐containing bioactive molecules necessitates efficient strategies for fluorinated group installation. Despite the impressive development of photoinduced radical fluoroalkylation as a powerful tool for introducing fluorine, the persistent issues, including the recyclability and reaction specificity of homogeneous photocatalysts, still leave great room for further advancement in a sustainable and general fashion. Herein, we report a conceptually different approach toward multiple types of fluoroalkylations by using recoverable and versatile graphitic carbon nitride (g‐CN) nanosheets as a heterogeneous photocatalyst. This photocatalytic system enables diverse intermolecular fluoroalkylations of alkenes with fluoroalkanesulfinates and intramolecular fluoroalkyl migrations of alkenyl triflates. Detailed characterizations and mechanism studies substantiate the stability of this organic semiconductor and the crucial role of photogenerated electron‐hole pairs. [ABSTRACT FROM AUTHOR]

Stannous chloride and thiourea are used as source materials to prepare SnO2 quantum dots in the aqueous solution by a facile hydrolysis-oxidation process. The quantum dots have an average size of 1.9 nm with good dispersibility as well as long-term stability, and are validated to be an effective photocatalyst for the degradation of organic oil pollutants in contaminated water. The pollutant is removed by the quantum dots exposed to ultraviolet-visible irradiation at room temperature. The optimized condition is concluded to be a solution with quantum dot concentration of 10-3 mol/L and the degradation speed reaches the maximum at the 12 th hour after irradiation. After 48 hours, 91.9 % of octane is removed, concluding a high degradation efficiency. The prepared SnO2 quantum dots are potentially applicable in the remediation of marine environment as they hold the advantages of high efficiency, low cost and being environmental-friendly. The promotion and inhibition mechanisms of the photocatalytic SnO2 QDs at low and high concentrations are discussed.