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Small RNAs (sRNAs) control a wide range of development and physiological pathways in plants. To address the response of sRNA biogenesis to drought stress, we identified sRNA biogenesis genes, including 11 encoding argonautes (AGO), 8 encoding Dicer-like proteins (DCL), and 9 encoding RNA-dependent RNA polymerases (RDR) in the peach genome. Notably, the largest numbers of sRNA biogenesis genes are located to chromosome 1. The PAZ, PIWI, and MID domains were identified in PpAGOs, while the ribonuclease IIIa and IIIb domains were characterized in PpDCLs. The RDRP domain was recognized in PpRDRs. Orthologous similarity and collinearity analyses between Arabidopsis and peach revealed 5, 1, and 2 collinear blocks in AGOs, DCLs, and RDRs, respectively. Moreover, 41, 40, and 42 cis-acting elements were located in the promoters of PpAGOs, PpDCLs, and PpRDRs, respectively, with the majority related to drought stress response. Analysis of RNA sequencing (RNA-seq) data revealed that sRNA biogenesis genes were involved in drought stress response in different tissues. Furthermore, the expression of candidate genes was verified in two peach cultivars, Beijing 2-7 (BJ2-7) and Sinai (SN), which are tested as drought-tolerant and sensitive cultivars, respectively, based on the physiological and biochemical analyses, which revealed that the Chinese peach cultivar 'BJ2-7' exhibits greater drought resistance compared to the Egyptian peach cultivar 'SN'. Interestingly, the expression of PpAGO2b, PpDCL2b, PpDCL4, and PpRDR4 genes was induced in 'BJ2-7' but inhibited in 'SN' under drought stress. Overall, this study provides insight into the roles of sRNA biogenesis genes in response to drought stress in peach. [ABSTRACT FROM AUTHOR]

This study investigates the Darcy-Brinkman flow of micropolar fluid through an anisotropic porous channel, a configuration relevant to various industrial and natural processes involving complex fluid flow. The anisotropy of the porous medium is characterized by its permeability aligned along two principal axes, with one axis forming an angle with the horizontal direction. The model applies no-slip and no-spin boundary conditions at the channel's impermeable walls. Using a combination of analytical techniques and graphical analysis, we explore how key parameters such as the Darcy number, anisotropy angle, permeability ratio, and micropolar material parameters affect the flow behavior. Results reveal that increasing the anisotropy angle and permeability ratio leads to a reduction in both fluid velocity and micro rotational velocity, while the Darcy number promotes an increase in flow velocity. Additionally, the study discusses the impact of these parameters on shear stress and couple stress at the channel walls. The findings contribute to a deeper understanding of micropolar fluid behavior in porous media, with potential applications in filtration, lubrication, and subsurface fluid dynamics. [ABSTRACT FROM AUTHOR]

The flavonoid diosmin (diosmetin 7-O-rutinoside) is used as a therapeutic agent for disorders of the blood vessels such as hemorrhoids and varicose veins. Diosmin is commercially produced using semi-synthetic methods involving the oxidation of hesperidin, the most abundant flavonoid in citrus fruits. However, this method produces byproducts that are toxic to the environment, and new sustainable methods to produce diosmin are required. Here, we used a synthetic biology approach to produce diosmin without generating toxic byproducts through reconstitution of the diosmin biosynthetic pathway in Nicotiana benthamiana. We first established that N. benthamiana leaves co-infiltrated with all seven genes in the flavonoid biosynthesis pathway produced high levels of luteolin, a precursor of diosmetin. We then compared the activity of modification enzymes such as methyltransferases, glucosyltransferases, and rhamnosyltransferases in Escherichia coli and in planta and selected genes encoding enzymes with the highest activity for producing diosmetin, diosmetin 7-O-glucoside, and diosmin, respectively. Finally, we reconstructed the entire diosmin biosynthetic pathway using three constructs containing ten genes encoding enzymes in this pathway, from phenylalanine ammonia lyase to rhamnosyltransferase. N. benthamiana leaves transiently co-expressing all these genes yielded 37.7 µg diosmin per gram fresh weight. To our knowledge, this is the first report of diosmin production in a heterologous plant system without the supply of a precursor. Successful production of diosmin in N. benthamiana opens new avenues for producing other commercially important flavonoids using similar platforms. [ABSTRACT FROM AUTHOR]

Introduction: Salt stress is one of the significant challenges in sorghum production, greatly impacting the yield of S. bicolor. L-type lectin receptor kinases (LLRKs) are essential for plant stress tolerance, yet a comprehensive genome-level analysis in this species has not been conducted. Materials and methods: Members of the SbLLRLK gene family were identified using bioinformatics methods. Gene structures, motifs, and phylogenetic relationships were analyzed. Subsequently, expression profiles under various stress conditions were examined using transcriptome data. Furthermore, functional validation was performed through homologous gene alignment and transgenic analysis, focusing on the gene SORBI_3004G304700. Results: This study identified 49 SbLLRLK genes in Sorghum bicolor, categorized into four groups based on their lectin domain characteristics. Expression analyses revealed diverse patterns under salt, drought, and heat stresses. SORBI_ 3004G304700 was identified as a negative regulator of salt stress tolerance, with three unique haplotypes identified through haplotype analysis, suggesting a role in salt stress adaptation. Haplotype analysis of SORBI_3004G304700 revealed three unique haplotypes, with haplotype1 being the most prevalent, possibly due to selective advantages for salt stress tolerance. Discussion: These findings offer valuable insights into the biological research on the role of the LLRLK gene family in Sorghumbicolor's response to salt stress. The functional characterization of SORBI_3004G304700 and the identification of haplotypes associated with salt tolerance provide valuable insights for molecular breeding and genetic enhancement of sorghum. [ABSTRACT FROM AUTHOR]

Through the advancement of the contemporary web and the rapid adoption of social media platforms such as YouTube, Twitter, and Facebook, for example, life has become much easier when dealing with certain highly personal problems. The far-reaching consequences of online harassment require immediate preventative steps to safeguard psychological wellness and scholarly achievement via detection at an earlier stage. This piece of writing aims to eliminate online harassment and create a criticism-free online environment. In the paper, we have used a variety of attributes to evaluate a large number of Bengali comments. We communicate cleansed data utilizing machine learning (ML) methods and natural language processing techniques, which must be followed using term frequency and reverse document frequency (TF-IDF) with a count vectorizer. In addition, we used tokenization with padding to feed our deep learning (DL) models. Using mathematical visualization and natural language processing, online bullying could be detected quickly. Multi-layer Perceptron (MLP), K-Nearest Neighbors (K-NN), Extreme Gradient Boosting (XGBoost), Adaptive Boosting Classifier (AdaBoost), Logistic Regression Classifier (LR), Random Forest Classifier (RF), Bagging Classifier, Stochastic Gradient Descent (SGD), Voting Classifier, and Stacking are employed in the research we conducted. We expanded our investigation to include different DL frameworks. Deep Neural Networks (DNN), Convolutional Neural Networks (CNN), Convolutional-Long Short-Term Memory (C-LSTM), and Bidirectional Long Short-Term Memory (BiLSTM) are all implemented. A large amount of data is required to precisely recognize harassing behavior. To rapidly recognize internet harassment written material, we combined two sets of data, producing 94,000 Bengali comments from different points of view. After understanding the ML and DL models, we can see that a hybrid model (MLP+SGD+LR) performed more effectively when compared to other models, its evaluation accuracy is 99.34%, precision is 99.34%, recall rate is 99.33%, and F1 score is 99.34% on multi-label class. For the binary classification model, we got 99.41% of accuracy. [ABSTRACT FROM AUTHOR]

Sunflower (Helianthus annuus L.) plays an essential role in meeting the demand for edible oil worldwide. The yield of sunflower seeds encompasses several component traits, including the disc diameter. Over three consecutive years, 2019, 2020, and 2022, we assessed phenotypic variation in disc diameter across a diverse set of sunflower accessions (N = 342) in replicated field trials. Upon aggregating the phenotypic data from multiple years, we estimated the broad sense heritability (H2) of the disc diameter trait to be 0.88. A subset of N = 274 accessions was genotyped by using the tunable genotyping‐by‐sequencing (tGBS) method, resulting in 226,779 high‐quality SNPs. Using these SNPs and the disc diameter phenotype, we conducted a genome‐wide association study (GWAS) employing two statistical approaches: the mixed linear model (MLM) and the fixed and random model circulating probability unification (farmCPU). The MLM and farmCPU GWAS approaches identified 106 and 8 significant SNPs located close to 53 and 21 genes, respectively. The MLM analysis identified two significant peaks: a prominent signal on chromosome 10 and a relatively weaker signal on chromosome 16, both of which were also detected by farmCPU. The genetic loci associated with disc diameter, as well as the related candidate genes, present promising avenues for further functional validation and serve as a basis for sunflower oil yield improvement. [ABSTRACT FROM AUTHOR]

Although the leather processing industry is vital in terms of employment creation, revenue generation, consumption of by‐products from the meat industry, and the production of the valuable commodity called leather, the industry is considered "red marked" due to the discharge of solid, liquid, and gaseous wastes from each unit operation. In addition, different cleaner production options were investigated to mitigate the negative effects of the leather industries. Cleaner options in curing were mostly focused on the use of plant extracts and the sodium chloride‐free preservation method, which eliminates the salinity and 70% TDS of the discharged water. The application of enzymes in the soak and unhairing facilitates the operation, reduces COD, BOD, and TDS in the effluent, and yields better results than the conventional method. Saltless and waterless pickling with nonswelling acid and chrome‐free tanning was considered cleaner options for pickling with salts and conventional tanning methods. This article provides an in‐depth analysis and review of conventional leather processing, hazardous chemicals in each unit operation, the environmental impact of conventional operations from curing to tanning, and cleaner leather production approaches in each unit operation. [ABSTRACT FROM AUTHOR]

Purpose: Circularity has acted as an essential phenomenon for small and medium enterprises (SMEs) in emerging economies, pressuring entrepreneurs to its adoption in their businesses. During the adoption and implementation of circularity, entrepreneurs or circular entrepreneurs (to be precise) are facing various challenges to its effective functioning. However, the scholarly literature has offered limited research into this phenomenon. Thus, the purpose of this research is to identify the various barriers and sub-barriers for circular entrepreneurs to adopt circularity in SMEs of emerging economies. Design/methodology/approach: A combined qualitative and quantitative approach was employed to achieve the objectives of the study. In the first stage, through an extensive literature review, a list of barriers was identified and in the second stage, a deductive approach was employed to finalize the barriers. Finally, Best-Worst Method (BWM), a multi-criteria decision-making (MCDM) method, was used to analyse the significant importance of the barriers. Findings: The findings of the study suggested the "financial barrier" as the first-ranked barrier in the adoption of Circular Business Models (CBMs), followed by the "regulatory and operational barrier" as the top second and third barriers. In terms of sub-barriers, "lack of access to funding and capital" has been identified as the top sub-barrier in the adoption of CBM, followed by "excessive regulations and red tape" and "challenges due to ambiguity of the concept". Practical implications: To transition from a circular to a linear business approach considerably quicker and smoother, entrepreneurs may utilize the findings of this study as a blueprint for the steps to overcome the barriers in a linear to a circular transition. Originality/value: This research differentiates from other studies due to solicited input directly from the people who are most familiar with the challenges of making the transition from linear to CBM, i.e. the entrepreneurs themselves. [ABSTRACT FROM AUTHOR]

Copyright of Environmental & Social Management Journal / Revista de Gestão Social e Ambiental is the property of Environmental & Social Management Journal and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

In many intricate processes, ranging from astronomy to biology, entropy generation is important. In order to enhance mechanical networks, such as heat radiators, components of atomic and thermal energy facilities, respiration, and refrigeration equipment, the entropy generation minimization approach could be used. In this paper, we examine entropy formation in a 3D stretching sheet involving titanium dioxide and copper utilizing a Cattaneo-Christov heat flux model. By utilizing the appropriate transformations, multiple sets of affiliated PDEs were transformed into ODEs. Equations that have been transformed are resolved by OHAM. On a graphic representation, aspects of physical specifications on speed, temperature, and concentration, as well as entropy generation, are described. It should be observed that improvement in fluid variables behaves in opposition to fluid velocity when related to temperature and concentration. Furthermore, thermal profiles improve when Eckert and Prandtl numbers are larger. It is observed that entropy increases with higher magnetic parameters, the Brinkman number, thermal radiation, the Eckert number, and the Reynolds number. [ABSTRACT FROM AUTHOR]

Cd-contaminated saline soil is now becoming a serious threat affecting sustainable agriculture throughout the world. In this study, organic amendments (OA) were applied to Cd-contaminated saline soils to, firstly, reduce the bioavailability of Cd in soil and, secondly, minimize Cd accumulation in red amaranth (Amaranthus gangeticus) plant. The soil was treated with 1% and 2% of cow dung (CD), vermicompost (VC), waste tea (WT), saw dust (SD), rice hull (RH), and compost. Red amaranth (Amaranthus gangeticus) plant was grown using a pot experiment in control and OA-treated soil stressed with both salinity (4 dsm -1 and 8 dSm -1 ) and Cd (5 mgkg -1 ). In slightly saline conditions (4 dSm -1 ), the addition of 1% CD and VC reduced the bioavailable Cd in the soil to 17.44% and 15.12%, respectively. The reduction increased to 24.42% and 25.58% with 2% rate of application in the same soil. However, in moderately saline soil (8 dSm -1 ), the reduction varied significantly only with the higher rate. Shoot Cd content was reduced by 85.86% using 2% VC in low saline soil. The bioconcentration factor was also lowered with the addition of CD and VC; however, the performance proved to be better in low saline soil at 2% rate of application. The health risk index (HRI) value for the adults was observed to be < 1 only when the soil with low salinity was treated with 2% VC. Consequently, VC can be used in Cd-contaminated saline soils for red amaranth cultivation to reduce risks to people's health., Competing Interests: Declarations. Competing interests: The authors declare no competing interests., (© 2024. The Author(s), under exclusive licence to Springer Nature Switzerland AG.)

Cracking is an important factor affecting the performance and life of large structures. In order to maximize personal safety and reduce costs, it is highly necessary to carry out research on crack monitoring technology. Sensors based on Radio Frequency Identification (RFID) antennas have the advantages of wireless and low cost, which makes them highly competitive in the field of structure health monitoring (SHM). Thus, this study systematically summarizes the research progress of crack monitoring based on RFID technology in recent years. Firstly, this study introduces the causes of cracks and the traditional monitoring methods. Further, this study summarizes several main RFID-based crack monitoring and detection methods, including crack monitoring based on chipless RFID technology, passive RFID technology, and ultra-high-frequency (UHF) RFID technology, including the implementation methods, as well as the advantages and disadvantages of those technologies. In addition, for RFID-based crack monitoring applications, the two most commonly used materials are concrete materials and metal materials, which are also illustrated in detail. In general, this study can provide technical support and a theoretical basis for crack monitoring and detection to ensure the safety of engineering structures. [ABSTRACT FROM AUTHOR]

The COVID-19 pandemic has widely disrupted manufacturing industries. This research focuses on how project management, Industry 4.0 technologies, and the Circular Economy contribute to Sustainable Supply Chain development during the pandemic. A multiple case study focusing on three companies in the metals industry, covering small-, medium-, and large-size companies from Thailand, is adopted to investigate the impact of the pandemic on companies using the dimensions of demand, production, and distribution disruptions. The result shows that project management supports Industry 4.0 technologies and Circular Economy adoption. Moreover, the COVID-19 pandemic also expedites Industry 4.0 technologies adoption. Product customization is one of the key focuses of the companies to differentiate from the competitors and create long-term competitive advantages. Industry 4.0 technologies and the Circular Economy have a positive influence on Sustainable Supply Chain development. [ABSTRACT FROM AUTHOR]

Lectin receptor-like kinases (LecRLKs) are a significant subgroup of the receptor-like kinases (RLKs) protein family. They play crucial roles in plant growth, development, immune responses, signal transduction, and stress tolerance. However, the genome-wide identification and characterization of LecRLK genes and their regulatory elements have not been explored in a major cereal crop, barley (Hordeum vulgare L.). Therefore, in this study, integrated bioinformatics tools were used to identify and characterize the LecRLK gene family in barley. Based on the phylogenetic tree and domain organization, a total of 113 LecRLK genes were identified in the barley genome (referred to as HvlecRLK) corresponding to the LecRLK genes of Arabidopsis thaliana. These putative HvlecRLK genes were classified into three groups: 62 G-type LecRLKs, 1 C-type LecRLK, and 50 L-type LecRLKs. They were unevenly distributed across eight chromosomes, including one unknown chromosome, and were predominantly located in the plasma membrane (G-type HvlecRLK (96.8%), C-type HvlecRLK (100%), and L-type HvlecRLK (98%)). An analysis of motif composition and exon-intron configuration revealed remarkable homogeneity with the members of AtlecRLK. Notably, most of the HvlecRLKs (27 G-type, 43 L-type) have no intron, suggesting their rapid functionality. The Ka/Ks and syntenic analysis demonstrated that HvlecRLK gene pairs evolved through purifying selection and gene duplication was the major factor for the expansion of the HvlecRLK gene family. Exploration of gene ontology (GO) enrichment indicated that the identified HvlecRLK genes are associated with various cellular processes, metabolic pathways, defense mechanisms, kinase activity, catalytic activity, ion binding, and other essential pathways. The regulatory network analysis identified 29 transcription factor families (TFFs), with seven major TFFs including bZIP, C2H2, ERF, MIKC_MADS, MYB, NAC, and WRKY participating in the regulation of HvlecRLK gene functions. Most notably, eight TFFs were found to be linked to the promoter region of both L-type HvleckRLK64 and HvleckRLK86. The promoter cis-acting regulatory element (CARE) analysis of barley identified a total of 75 CARE motifs responsive to light responsiveness (LR), tissue-specific (TS), hormone responsiveness (HR), and stress responsiveness (SR). The maximum number of CAREs was identified in HvleckRLK11 (25 for LR), HvleckRLK69 (17 for TS), and HvleckRLK80 (12 for HR). Additionally, HvleckRLK14, HvleckRLK16, HvleckRLK33, HvleckRLK50, HvleckRLK52, HvleckRLK56, and HvleckRLK110 were predicted to exhibit higher responses in stress conditions. In addition, 46 putative miRNAs were predicted to target 81 HvlecRLK genes and HvlecRLK13 was the most targeted gene by 8 different miRNAs. Protein-protein interaction analysis demonstrated higher functional similarities of 63 HvlecRLKs with 7 Arabidopsis STRING proteins. Our overall findings provide valuable information on the LecRLK gene family which might pave the way to advanced research on the functional mechanism of the candidate genes as well as to develop new barley cultivars in breeding programs. [ABSTRACT FROM AUTHOR]

Even though the traction towards a circular economy (CE) is on the rise, and the benefits a CE has across ecological, economic, and social frontiers have been undeniable, still, CE-related developments and its adoption have not been appealing. This study conducts a systematic literature review of the CE-related literature in line with the 'umbrella framework' to find the current state of the diffusion and diversification of CE concepts both in the academic context as well as in application. Using a thematic and content analysis of the sampled literature, the study (i) develops a comprehensive and inclusive CE definition and (ii) examines the level of diffusion of CE in the economy. The study concludes that, even though CE-related developments are positive and promising, it is still in the validity phase of the umbrella framework and recommends focusing more on the application-based intervention of the CE. [ABSTRACT FROM AUTHOR]

In recent decades, the study of non-Newtonian fluids has attracted the interest of numerous researchers. Their study is encouraged by the significance of these fluids in fields including industrial implementations. Furthermore, the importance of heat and mass transfer is greatly increased by a variety of scientific and engineering processes, including air conditioning, crop damage, refrigeration, equipment power collectors, and heat exchangers. The key objective of this work is to use the mathematical representation of a chemically reactive Casson-Maxwell fluid over a stretched sheet circumstance. Arrhenius activation energy and aspects of the magnetic field also have a role. In addition, the consequences of both viscous dissipation, Joule heating, and nonlinear thermal radiation are considered. The method transforms partial differential equations originating in fluidic systems into nonlinear differential equation systems with the proper degree of similarity which is subsequently resolved utilizing the Lobatto IIIA technique's powerful computing capabilities. It is important to recall that the velocity profile drops as the Maxwell fluid parameter increases. Additionally, the increase in the temperature ratio parameter raises both the fluid's temperature and the corresponding thickness of the boundary layer. [ABSTRACT FROM AUTHOR]

Copyright of Leather & Footwear Journal / Revista de Pielarie Incaltaminte is the property of INCDTP and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

In different regions of the world, cowpea (Vigna unguiculata (L.) Walp.) is an important vegetable and an excellent source of protein. It lessens the malnutrition of the underprivileged in developing nations and has some positive effects on health, such as a reduction in the prevalence of cancer and cardiovascular disease. However, occasionally, certain biotic and abiotic stresses caused a sharp fall in cowpea yield. Major RNA interference (RNAi) genes like Dicer-like (DCL), Argonaute (AGO), and RNA-dependent RNA polymerase (RDR) are essential for the synthesis of their associated factors like domain, small RNAs (sRNAs), transcription factors, micro-RNAs, and cis-acting factors that shield plants from biotic and abiotic stresses. In this study, applying BLASTP search and phylogenetic tree analysis with reference to the Arabidopsis RNAi (AtRNAi) genes, we discovered 28 VuRNAi genes, including 7 VuDCL, 14 VuAGO, and 7 VuRDR genes in cowpea. We looked at the domains, motifs, gene structures, chromosomal locations, subcellular locations, gene ontology (GO) terms, and regulatory factors (transcription factors, micro-RNAs, and cis-acting elements (CAEs)) to characterize the VuRNAi genes and proteins in cowpea in response to stresses. Predicted VuDCL1, VuDCL2(a, b), VuAGO7, VuAGO10, and VuRDR6 genes might have an impact on cowpea growth, development of the vegetative and flowering stages, and antiviral defense. The VuRNAi gene regulatory features miR395 and miR396 might contribute to grain quality improvement, immunity boosting, and pathogen infection resistance under salinity and drought conditions. Predicted CAEs from the VuRNAi genes might play a role in plant growth and development, improving grain quality and production and protecting plants from biotic and abiotic stresses. Therefore, our study provides crucial information about the functional roles of VuRNAi genes and their associated components, which would aid in the development of future cowpeas that are more resilient to biotic and abiotic stress. The manuscript is available as a preprint at this link: doi:10.1101/2023.02.15.528631v1. [ABSTRACT FROM AUTHOR]

The purpose of this study is to replace chrome tannins with ecofriendly vegetable tannins as an alternative solution to prevent the public health and the environmental pollution. Vegetable tannin was extracted from Cassia singueana bark using an aqueous extraction method and applied on sheep pickle pelt. Optimum tannin extraction parameters were identified at powder concentration of 80 g/L, extraction temperature of 100°C, and extraction time of 120 mins. Chemical functionality of Cassia singueana extracted tannins was evaluated via FT-IR spectroscopy. Hence, the FT-IR spectrum confirmed the presence of wide band of phenolic hydroxyl (OH−) and carboxyl (C-O) groups connected with the aromatic ring. Moreover, physicochemical performance of the Cassia singueana extract tanned leather sample was scientifically examined and showed comparable results to conventional Mimosa tanned leather sample. The shrinkage temperature of Cassia singueana extract tanned leather recorded 83°C which is slightly higher than that of Mimosa extract (standard), 80°C. The results of mechanical properties such as tensile strength, tear strength, and elongation at break of Cassia singueana extract tanned leather sample are 15.6 N/mm2, 24.2 N/mm, and 45.3%, respectively, which are relatively higher than those of Mimosa extract tanned leather sample. A relatively higher reduction level of pollution load (BOD, COD, and TDS) was observed in the wastewater released from Cassia singueana bark extract compared to the Mimosa extract (standard). Finally, findings from this study revealed that Cassia singueana bark extract could be considered as an alternative source of vegetable tannins to reduce the consumption of chrome tanning in the leather tanning industry. [ABSTRACT FROM AUTHOR]

Finished tanned leather is usually covered by a thin polymeric layer. This layer has the scope to change the morphological aspect of the last leather layer as well as improve the impermeabilization properties. Often, the finished product is refused by the final client, and tanneries must restore significant quantities of materials. Therefore, it is very important to remove this finished polymeric layer, recover the underneath tanned leather, and predispose it to a new finishing. The bonding between the polymeric film and leather is so strong that, today, only a blade shaving process can perform this separation at the expense of also removing a layer of tanned leather and consequently reducing the leather thickness. Here, a novel separation method was developed based on the significant difference in the dilation properties between the tanned hide and the polymeric film at low temperatures. The use of cryogenic fluids, in particular the direct application of liquid nitrogen, can freeze the polymeric layer below the glass transition temperature, inducing brittle behavior. The result is an easy separation without any alteration of the tanned leather layer; for a demonstration of that, some techniques were used, such as FTIR, SEM, Tensile strength evaluation, DSC, and TGA. By this last analysis, it is possible to check how a decrease of weight to 90% happened for the polymeric layer at about 400 °C against the complete blank at about 600 °C. A similar great distance of results exists in the case of tensile strength, where an average value of 34.5% is the deformation stress for blank samples, against 34.8% for processed samples. Thus, the process here developed allows the reuse of the tanned leather towards a new life in respect of the principles of the circular economy. [ABSTRACT FROM AUTHOR]

The integration of innovative technologies creates a circular economy (CE) system that enhances the value and legitimacy of their trade. Recently, many global industries have shifted their focus towards product‐service system (PSS) to perpetuate in today's competitive market without negatively influencing the environmental detrition and retaining the extended producer responsibility (EPR). Thus, this study will advance an understanding of how I4.0 technologies derivate renewables from waste to create sustainable energy sources rather than consuming virgin resources (normally considered a linear model) from a data management and product lifecycle perspective. This research used the Systematic Literature Review (SLR) methodology to analyse and categorise a literature survey of 126 research articles published over the years (2013–2022). The analysis indicates that the early research is mostly focused on defining the key variables (CE, I4.0 and PSS) and developing various frameworks to promote eco‐efficient services and sustainable development using I4.0 technologies and is engineering focused. It is established that two propositions leverage CE; the first one is value co‐creation, which enhances perceived value. In contrast, the other one is related to the application of data‐driven platforms using I4.0 technologies for sculpting the strategy and other decision support. More studies need to be analysing CE, I4.0 and PSS. To support researchers, managers and policymakers, this study has analysed the applicability of theoretical propositions regarding the application of I4.0 technologies with CE and PSS and presented a theoretical framework for the I4.0‐enabled share platform that may be tested using empirical data. [ABSTRACT FROM AUTHOR]

Copyright of Leather & Footwear Journal / Revista de Pielarie Incaltaminte is the property of INCDTP and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Copyright of Leather & Footwear Journal / Revista de Pielarie Incaltaminte is the property of INCDTP and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Polymeric biocomposites based on TPU/recycled TPUW/mixed leather and SBR rubber waste unmodified/modified with polydimethylsiloxane/PE-g-MA in different percentages were made via the mixing technique on a Plasti-Corder Brabender mixer with an internal capacity of 350 cm3. The waste, which came from the shoe industry, was cryogenically ground with the help of a cryogenic cyclone mill at micrometric sizes and different speeds. For the tests, standard plates of 150 × 150 × 2 mm were obtained in a laboratory-scale hydraulic press via the method of compression between its plates, with well-established parameters. The biocomposites were tested physico-mechanically and rheologically (MFI) according to the standards in force on polymer-specific equipment, also via FT-IR spectroscopy and microscopy, as well as via differential scanning calorimetry—DSC. Following the tests carried out, according to the standard for use in the footwear industry, at least two samples present optimal values (of interest) suitable for use in the footwear industry by injection or pressing in forming moulds. [ABSTRACT FROM AUTHOR]

The literature presents a review of the current application of lean and green practices and highlights the context, barriers, drivers, tools, and critical success factors and tools for the integration of lean and green practices within the Sub-Saharan African (SSA) manufacturing industry. In addition, the current state, gaps in the existing literature, and future perspectives on the current challenges of the industry have been suggested for the integration of both paradigm and sustainability of the industry. Integration of lean-green provides means to addressing issues faced by manufacturing industries for improved competitiveness. This study demonstrates that the application of lean and green practice is critical to be identified and applied within the region through the analysis of research papers published in both operational and sustainability journals. The findings of this review indicate that the synergy of lean and green practices is an effective initiative for resolving the operational and sustainability challenges of the manufacturing industry within SSA. To achieve operational excellence and mitigate environmental concerns, industries must implement the right tools and consider the critical success factors. By applying appropriate tools and models, the SSA region can address the current challenges and achieve a reduction in cost significantly. [ABSTRACT FROM AUTHOR]

Autism spectrum disorder (ASD) presents a neurological and developmental disorder that has an impact on the social and cognitive skills of children causing repetitive behaviours, restricted interests, communication problems and difficulty in social interaction. Early diagnosis of ASD can prevent from its severity and prolonged effects. Federated learning (FL) is one of the most recent techniques that can be applied for accurate ASD diagnoses in early stages or prevention of its long-term effects. In this article, FL technique has been uniquely applied for autism detection by training two different ML classifiers including logistic regression and support vector machine locally for classification of ASD factors and detection of ASD in children and adults. Due to FL, results obtained from these classifiers have been transmitted to central server where meta classifier is trained to determine which approach is most accurate in the detection of ASD in children and adults. Four different ASD patient datasets, each containing more than 600 records of effected children and adults have been obtained from different repository for features extraction. The proposed model predicted ASD with 98% accuracy (in children) and 81% accuracy (in adults). [ABSTRACT FROM AUTHOR]

Raw materials with significant levels of nutrients, such as protein and carbohydrates, phenolics, and antioxidant compounds were considered as hop replacements in the brewing process. In this study, the composition of Rubim (Leonurus sibiricus L.) and Mastruz (Chenopodium ambrosioides L.) for the partial (25%, 50%, and 75%) or total replacement of hops in beers was explored. The beers formulated with high levels of Rubim and Mastruz resulted in an increase in antioxidant activity and bioactive compounds. The bioactive compounds, antioxidant activity, and International Bitterness Units (IBU) were analyzed in wort before fermentation and in beers. Beer with hops replaced by 25% Rubim and beer with 100% Mastruz presented higher total phenolic compounds. Replacing hops with 100% Rubim and Mastruz presented higher antioxidant activity by DPPH, and the IBU decreased with the replacement of hops by Rubim and Mastruz. Pearson correlation was performed to establish the relationship between bioactive compounds and antioxidant activity, and principal components analysis was performed to understand the interrelationships among the measured bioactive compounds and antioxidant activity. The beers with hop replacement were sensorially accepted, and the bitterness intensity was experienced by consumers. [ABSTRACT FROM AUTHOR]

Increasing environmental awareness and stringent environmental norms of developed countries have demanded eco-friendly industrial practices from the leather industry. On the path to achieving sustainable development goals (SDGs), the concept of circular bio-economy (CBE) practices has gained significant attention from the leather industry with regards to waste management. CBE practices encourage the potential of recovering value from leather waste. However, the CBE concept has not been well received by the leather industries of developing countries for various reasons. Hence, this study aims to identify and evaluate various barriers to CBE practices from the context of the Indian leather industry. Twenty-five barriers to CBE practices in the leather industry are identified through literature review and interaction with managers. Then, a rough decision-making trial and evaluation laboratory (R-DEMATEL) was utilized to reveal the interrelationships among the barriers to CBE practices. Restrictiveness to change, difficulty in forming a reliable supplier network, difficulty in developing customers, lack of vision, and unclear and partial understanding of the CBE concept have been identified as the five most critical barriers to CBE practices in the leather industry. Furthermore, in the current study, nine barriers fall into the cause group and sixteen barriers fall into the effect group. The outcome of the study reveals the causal interrelationships among the barriers to CBE practices to the industrial management and policymakers. This study is the first of its kind to analyze the barriers to CBE practices in the Indian leather industry context. [ABSTRACT FROM AUTHOR]

Azo dyes, which are the most commonly used dyes in the textile industry, are aromatic compounds with N═N– groups. The treatment of these pollutants has been receiving considerable attention due to their persistence and release of dyes into the environment. The existing treatment approaches are not only expensive but also result in the production of concentrated sludge, which creates a secondary disposal issue. Under particular ecological conditions, a variety of microbes, including bacteria, fungi, algae, and yeasts, can not only decolorize numerous dyes but can also degrade them. In this respect, microbial degradation is a successful, cost‐effective, biologically friendly, and ecologically sustainable treatment strategy. This review paper discusses research articles identified in the ScienceDirect bibliographic database for the last 10 years (from January 1, 2010 to June 29, 2022). Only the most appropriate research articles were included in the review process which was identified by searches with keyword phrases Azo‐dye degradation with bacteria, fungi, algae, yeast, and microbial consortia. The review paper also emphasizes the constraints that persist and the future scope for the degradation of dyes via genetic engineering. [ABSTRACT FROM AUTHOR]

The recent coronavirus (COVID-19) pandemic has affected the manufacturing industry's entire supply chain system. It is important to investigate the strategic drivers to deal with the impacts of COVID-19 in the manufacturing industry. Accordingly, this study aims to identify the strategic drivers to overcome the impacts of the COVID-19 pandemic and improve the resiliency of the Bangladeshi footwear industry, an emerging economy. The strategic drivers are identified after reviewing research papers, reports, blogs, and discussions on social media platforms. The main drivers and their respective sub-drivers are finalized by discussing with domain experts. To offer strategic plans for building resiliency, it is crucial to know the importance of the main drivers and sub-drivers; therefore, the best–worst method is applied to determine the priority importance of the strategic drivers. The findings indicate that the top five drivers to defeat the impacts of COVID-19 are "high capability of reconfigurability," "enhance the relationship with suppliers," "develop health protocols to continue manufacturing," "government support through incentives, subsidy, tax rebate, etc.," and "set a policy to stable material supply". Based on the findings, this study also provides practical implications with proposed research themes for policymakers and operations managers towards mitigating the impacts of the COVID-19 pandemic. The study's contribution is unique and important for the footwear supply chain as the research on COVID-19 in the context of resiliency focusing on the footwear supply chain is non-existent. [ABSTRACT FROM AUTHOR]

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Sustainability is a strategic approach to develop a more sustainable economy to support the environment and socio-economic development. Literature on sustainability has been concerned mainly with global warming and environmental degradation issues, whereas the Circular Economy (CE) concept has recently been suggested as an alternative solution to support market sustainability and deal with both environmental and socio-economic challenges. In order to tackle these challenges, countries must switch from linear economies that follow the "take-make-dispose" principle to circular and sustainable economies. This study applies a structural and conceptual literature review to elucidate the most decisive determinants in the formation of circular strategies, particularly in the context of the energy sector. This study examines obstacles that hinder CE adoption and formulates drivers and measures to overcome them. The strategic literature review shows that the circular approach is critical in achieving sustainable development. Circularity can be considered a novel and innovative approach to alleviating the contradiction between rapid economic growth and energy and raw materials shortages. The CE structure must be considered as a sustainable foundation to enhance economic growth by avoiding waste, preserving natural capital, managing resource scarcity, recycling materials, maximizing energy efficiency, and recirculating them into the economy. Analysis reveals that the circular system is a key pillar of sustainability, security, and efficiency in the energy sector. The sustainable energy transition requires incorporating the CE principles in the design process. It also revealed that both public and private sectors must move away from the linear paradigm towards circularity to achieve CE implementation. [ABSTRACT FROM AUTHOR]

The present study was focused on the synthesis of brinjal waste activated carbon (BWAC) from the dry woody part of brinjal plant by chemical activation method. The BWAC was used as adsorbent to remove acid yellow 17 (AY-17) from the synthetic solution. For BWAC synthesis, phosphoric acid was used as a chemical reagent for chemical activation at a ratio of 1:1, followed by pyrolysis of chemically treated biomass in N2 atmosphere at high temperatures in a vertical reactor for improved chemical and surface properties of BWAC. The BWAC was characterized by several techniques such as BET surface area, pore distribution, SEM, FTIR, XRD, and point of zero charge (pHPZC). Various affecting parameters such as equilibrium time, initial pH, BWAC dose, AY-17 concentrations, and temperature for dye removal by BWAC were also investigated in the batch experiment. The maximum of 99.58% removal of AY-17 dye by BWAC occurred at pH 3. More than 97% dye was removed by BWAC from aqueous solution for initial 15 mg/L AY-17 dye concentration with other conditions such as 2 g/L dose, 5.00 ± 0.2 pH, 80 min equilibrium time, and 25 °C temperature. Therefore, further experiments were carried out at pH 5. Equilibrium data were fitted with the isotherm models such as Langmuir, Freundlich, and Temkin, and according to the correlation coefficient (R2), the Langmuir model was best fitted among them. The experimental kinetic data was well-validated with the pseudo-second-order kinetic model. The mass transfer studies of the dye onto BWAC were described by three models, such as Weber-Morris (intra-particle diffusion), Banghum's, and liquid film diffusion models, and the result reported that all steps were involved for the adsorption process. The order for the rate-determining step, according to R2, was intra-particle diffusion > Bangham's model > liquid film diffusion model. Recovery and recycling of dye-treated BWAC with desorption efficiency of ~ 73% was possible by 1 M NaOH treatment after 5th cycles. The simulated dye solution after treatment by BWAC was used in seed germination for toxicity assessment. [ABSTRACT FROM AUTHOR]

Bangladesh, like many developing countries, has taken various aquaculture product quality and safety control measures. However, it is little is known about Bangladeshi consumers' preferences, and in particular, whether they are willing to pay a price premium for safety improvements and what are the determinants of their WTP. This paper assesses consumers' preferences and WTP for Hazard Analysis Critical Control Point (HACCP) of certified frozen farmed fish (major carps). Findings indicate that Bangladeshi consumers, on average, are ready to pay a premium of 24.62% more for HACCP-certified frozen major carps. Results also indicate that education, income, consumption frequency, perceived fish safety risk, taste, and freshness are the significant determinants of consumers' WTP for HACCP certified frozen major carps. [ABSTRACT FROM AUTHOR]

Purpose – The paper focuses on the identification of disparities in the development of the macroeconomic environment across the member states of the European Union and problematic factors impacting the business environment’s level. Research methodology – To find the disparities in the development of the EU countries, the TOPSIS method was used. Based on this analysis, the crucial factors influencing the development of the macroeconomic environment were determined. The discriminant analysis was then used to form a model, which could help assess and examine the relationship between the business environment and significant determinants of development. Findings – Based on the methods applied, the determinants influencing the development of the macroeconomic environment and key factors and aspects affecting the rate of development of the economic and business environment were identified and the analysis of the economic and business environment was performed through selected statistical techniques. Practical implications – The analysis confirmed that some countries have certain gaps in its assessment of the dynamics of economic development in EU countries in terms of the sustainability and competitiveness of small and medium-sized businesses, and that the business climate is not entirely conducive to these businesses. Originality/Value – The additional value of the paper is the formation of the model, which helps identify the countries with appropriate business environment and those where the economic development is not sufficiently developed which may be useful for enterprises, investors, and creditors. [ABSTRACT FROM AUTHOR]

In the present time of speedy developments and industrialization, heavy metals are being uncovered in aquatic environment and soil via refining, electroplating, processing, mining, metallurgical activities, dyeing and other several metallic and metal based industrial and synthetic activities. Heavy metals like lead (Pb), mercury (Hg), cadmium (Cd), arsenic (As), Zinc (Zn), Cobalt (Co), Iron (Fe), and many other are considered as seriously noxious and toxic for the aquatic environment, human, and other aquatic lives and have damaging influences. Such heavy metals, which are very tough to be degraded, can be managed by reducing their potential through various processes like removal, precipitation, oxidation–reduction, bio‐sorption, recovery, bioaccumulation, bio‐mineralization etc. Microbes are known as talented bio‐agents for the heavy metals detoxification process and fungi are one of the cherished bio‐sources that show noteworthy aptitude of heavy metal sorption and metal tolerance. Thus, the main objective of the authors was to come with a comprehensive review having methodological insights on the novel and recent results in the field of mycoremediation of heavy metals. This review significantly assesses the potential talent of fungi in heavy metal detoxification and thus, in environmental restoration. Many reported works, methodologies and mechanistic sights have been evaluated to explore the fungal‐assisted heavy metal remediation. Herein, a compact and effectual discussion on the recent mycoremediation studies of organic pollutants like dyes, petroleum, pesticides, insecticides, herbicides, and pharmaceutical wastes have also been presented. [ABSTRACT FROM AUTHOR]

Developing nations, such as Bangladesh, face an enormous crisis in maintaining natural sustainability due to heavy metal contamination by the peripheral rivers. Frequent heavy metals discharged from tanneries, dyeing, and potential anthropogenic activities in Savar city pollute the Dhaleshwari river, which is an important river of the capital city, Dhaka. The present study aimed to assess the heavy metals contamination in the Dhaleshwari river sediment and evaluate the subsequent ecological risk indices emerging from the deposits. The contamination levels of heavy metals such as lead (Pb), cadmium (Cd), chromium (Cr), and nickel (Ni) were analyzed in the Dhaleshwari River sediment. Various environmental indices, such as Potential Enrichment Risk (PER), Geo-accumulation Index (Igeo), Enrichment factor (EF), Toxic unit analysis (TUs), etc., were observed in various compartments. The concentration of heavy metals ranged as follows: Lead (Pb), 297.3-414.6 mg/L; Cadmium (Cd), 1.5-4.4 mg/L; chromium (Cr), 97.9 -282.4 mg/L; Nickle (Ni), 85.1-264.5 mg/L; Iron (Fe), 11800-14375 mg/L. The metal concentrations were higher than the threshold effect level (TEL) and probable effect level (PEL) standards. Based on the TUs, the probability of toxicity is about 76% (TU > 2.3) at the Dhaleshwari river. Comparative evaluation of different environmental indices between present and past studies indicated progressive deterioration of sediments by heavy metals. Linear correlations of heavy metals in sediment samples demonstrated toxic accumulation of heavy metals in the surrounding ecosystem. The study outcomes emphasize the necessity of systematic investigation in the Dhaleshwari river and warranting effective prioritization to ensure river health over industrial wastewater discharge. [ABSTRACT FROM AUTHOR]

The tanning industry generates significant amounts of solid waste and post-production wastewater, which should be managed in accordance with the principles of the circular economy. Waste is generated at various technological stages of production. This comprises mainly solid waste and leachate. A comprehensive solution to the problem of disposal of this waste is very important from economic and environmental points of view. This work presents research for a technological production line designed for the comprehensive processing of post-production residues. In the present paper, the authors present an analysis related to the possibility of processing leather flesh side (mizdra) as a substrate for methane fermentation. The study showed an increased biogas production from solid waste after enzymatic hydrolysis up to 248 Nm3/Mg. Preliminary research on the system designed for pre-treatment of sewage from the technological line is also presented. The study showed a COD reduction of more than 30%. The possibility of energy management of the solid fraction directly from the processes carried out is demonstrated. [ABSTRACT FROM AUTHOR]

The phenomenon of bioconvective transport through the manipulation of motile microorganisms is considered a promising process control technique in several biological processes and microdevices. Inducing convective transport in self-propelling microbes could be tailored to improve mixing, reaction propensity, and concentration transport within the media. This paper examined the combined effect of magnetic and rotational fields on the argumentation of bioconvective transport in the nanofluid-mediated plasma flow. A detailed analysis of the transport and dynamics of reactive forces during bioconvection in a rotary disc-like microchannel is presented. The physics of the problem was described by coupled nonlinear ordinary differential equations, which were numerically computed using the spectral relaxation scheme of the spectral homotopy analysis method. It was observed that the imposition of a magnetic field constituted viscous drag in the plasma-nanofluid media, which consequently increases the thermophoretic parameter in the bioconvective flow. It was ascertained that coupled magnetic and rotational effects significantly augmented the motility of microorganisms and translated to growth in momentum and concentration fields which is noticeable in the generation of stretching effect on the bacterium-containing plasma-nanofluid flow. The findings of this study could provide an essential basis for the design of bioreactors, centrifugal microfluidics technologies, and microdevices for use in a broad spectrum of biotechnology. [ABSTRACT FROM AUTHOR]