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18 results on '"Crosthwaite, Jacob M."'

9. Design and evaluation of nonfluorous C[O.sub.2]-soluble oligomers and polymers

Author

Yang Wang, Lei Hong, Tapriyal, Deepak, In Chul Kim, Paik, Ik-Hyeon, Crosthwaite, Jacob M., Hamilton, Andrew D., Thies, Mark C., Beckman, Eric J., Enick, Robert M., and Johnson, J. Karl

Subjects
Acetates -- Chemical properties, Carbon dioxide -- Chemical properties, Solvation -- Analysis, Vinyl polymers -- Structure, Vinyl polymers -- Chemical properties, Chemicals, plastics and rubber industries
Published
2009

10. Liquid phase behavior of ionic liquids with alcohols: Experimental studies and modeling

Author

Crosthwaite, Jacob M., Muldoon, Mark J., Aki, Sudhir N.V.K., Maginn, Edward J., and Brennecke, Joan F.

Subjects
Ionic solutions -- Chemical properties, Ionic solutions -- Research, Pyridinium compounds -- Chemical properties, Alcohols -- Chemical properties, Chemicals, plastics and rubber industries
Abstract

The effect of chemical and structural factors on the phase behavior of ionic liquids with alcohols is examined, focusing on pyridinium ionic liquids (ILs) for comparison to imidazolium ILs from previous studies. The nonrandom two-liquid (NRTL) equation with binary interaction parameters with linear temperature dependence has provided a good fit of the experimental data for all the systems.

Published
2006

11. Liquid phase behavior of imidazolium-based ionic liquids with alcohols

Author

Crosthwaite, Jacob M., Aki, Sudhir N.V.K., Maginn, Edward J., and Brennecke, Joan F.

Subjects
Alcohols -- Properties, Ionic solutions -- Properties, Imidazole -- Research, Imidazole -- Behavior, Chemicals, plastics and rubber industries
Abstract

The impact of different characteristics of the ionic liquids (ILs) and the alcohols on the liquid-liquid phase equilibrium of imidazolium-based ionic liquids and alcohols is examined. The ionic liquid-water mutual solubility data for a number of ionic liquids is discussed.

Published
2004

13. Design and Evaluation of Nonfluorous CO2-Soluble Oligomers and Polymers

Author

Wang, Yang, primary, Hong, Lei, additional, Tapriyal, Deepak, additional, Kim, In Chul, additional, Paik, Ik-Hyeon, additional, Crosthwaite, Jacob M., additional, Hamilton, Andrew D., additional, Thies, Mark C., additional, Beckman, Eric J., additional, Enick, Robert M., additional, and Johnson, J. Karl, additional

Published
2009
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15. Phase equilibrium measurements for the I2–H2O and I2–HI–H2O systems of the sulfur–iodine cycle using a continuous-flow apparatus

Author

Mena, Sarah E., Cervo, Eduardo G., Crosthwaite, Jacob M., and Thies, Mark C.

Subjects
*LIQUID-liquid equilibrium, *THERMOCHEMISTRY, *DISTILLATION, *HYDROGEN production, *IODINE, *CHEMICAL reactions, *TEMPERATURE effect
Abstract

Abstract: Liquid–liquid equilibrium (LLE) phase behavior was investigated for the binary iodine–water (I2–H2O) and the ternary iodine–hydroiodic acid–water (I2–HI–H2O) at the elevated temperatures and pressures of interest for the reactive distillation column of the Sulfur–Iodine Cycle. A continuous-flow apparatus, with wetted parts fabricated from tantalum-tungsten alloys, was designed and constructed for the highly corrosive conditions of this work. A central feature of the apparatus is the equilibrium view cell, which allows for the observation and discernment of vapor-liquid, liquid-liquid, and liquid–liquid–vapor equilibria for HIx systems. For the I2–H2O system, LLE was observed at temperatures and pressures to 300°C and 104 bar. Based on our observations, we estimate that the upper critical solution temperature for this system occurs at 310–315°C. For the I2–HI–H2O ternary, VLE, LLE, and LLVE were all observed at 160 and 200°C, and three compositions on the water-rich side of the LLE phase envelope were determined. [Copyright &y& Elsevier]

Published
2010
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16. Liquid Fuels As Jet Fuels and Propellants: A Review of Their Productions and Applications

Author

Mohammad Hossein Keshavarz and Mohammad Hossein Keshavarz

Subjects
Rockets (Aeronautics)--Fuel, Liquid fuels, Jet planes--Fuel
Abstract

In recent years, it has been important for scientists and chemical industries to introduce and develop new liquid fuels as jet fuels and propellants for propulsion purposes. Different aspects should be considered for the selection of a good candidate such as combustion performance, desired physical properties, noncarcinogenic and less toxicity. New synthetic hydrocarbon fuels with favorable combustion performance and physical properties have been considered as desirable jet fuels. They can be used in aircrafts such as military jets because of their higher volumetric energy density. A liquid-propellant rocket uses liquid propellants for propulsion. Liquid propellants should have the desirable properties of high energy density per unit mass, high specific impulse, and short ignition delays. Hypergolic propellants as important classes of liquid propellants are characterized by spontaneous reaction upon fuel and oxidizer mixing and high energy yield. Moreover, they should be relatively ignitable and have a small ignition time delay. This book reviews some efforts that have been done to introduce new candidates to replace conventional hydrazine fuels because they are acutely toxic and suspected carcinogens, costly safety precautions and handling procedures are required. This book reviews the latest advances in liquid fuels, which may be used as jet fuels and liquid propellants. Important properties for assessment of a suitable liquid are demonstrated. This book can be used for graduate students in the field of chemistry and chemical engineering. It may also be useful for scientists and researchers who work on the development of new liquid fuels with high performance as well as those that are noncarcinogenic or have less toxicity.

Published
2018

17. Ionic Liquids III A: Fundamentals, Progress, Challenges, and Opportunities

Author

Robin D. Rogers, Kenneth R. Seddon, Andrea Mele, Mark P. Jensen, James V. Beitz, Jörg Neuefeind, S. Skanthakumar, L. Soderholm, Antonia E. Bradley, Christopher Hardacre, Mark Nieuwenhuyzen, William R. Pitner, David Sanders, Robert C. Thied, Maggel Deetlefs, Peter B. Hitchcock, Charles L. Hussey, Thamer J. Mohammed, Jan-Albert van den Berg, Jalal A. Zora, Hiro-o Hamaguchi, Satyen Saha, Ryosuke Ozawa, Satoshi Hayashi, Ralf Giernoth, Nikolaos I. Sakellarios, Sergei G. Kazarian, Alison M. Funston, James F. Wishart, Jones de Andrade, Elvis S. Böes, Hubert Stassen, J. N. Canongia Lopes, J. Deschamps, A. A. H. Pádua, Johnny Deschamps, Agilio A. H. Pádua, Joseph W. Magee, Gennady J. Kabo, Michael Frenkel, C. A Cerdeiriña, J. Troncoso, C. Paz Ramos, L. Romani, V. Najdanovic-Visak, H. J. R. Guedes, J. M. S. S. Esperança, Z. P. Visak, M. Nunes da Ponte, L. P. N. Rebelo, Andreas Heintz, Wojciech Marczak, Sergey P. Verevkin, Douglas M. Fox, Walid H. Awad, Jeffrey W. Gilman, Paul H. Maupin, Paul C. Trulove, Hugh C. De Long, M. F. Costa Gomes, P. Husson, J. Ja, Robin D. Rogers, Kenneth R. Seddon, Andrea Mele, Mark P. Jensen, James V. Beitz, Jörg Neuefeind, S. Skanthakumar, L. Soderholm, Antonia E. Bradley, Christopher Hardacre, Mark Nieuwenhuyzen, William R. Pitner, David Sanders, Robert C. Thied, Maggel Deetlefs, Peter B. Hitchcock, Charles L. Hussey, Thamer J. Mohammed, Jan-Albert van den Berg, Jalal A. Zora, Hiro-o Hamaguchi, Satyen Saha, Ryosuke Ozawa, Satoshi Hayashi, Ralf Giernoth, Nikolaos I. Sakellarios, Sergei G. Kazarian, Alison M. Funston, James F. Wishart, Jones de Andrade, Elvis S. Böes, Hubert Stassen, J. N. Canongia Lopes, J. Deschamps, A. A. H. Pádua, Johnny Deschamps, Agilio A. H. Pádua, Joseph W. Magee, Gennady J. Kabo, Michael Frenkel, C. A Cerdeiriña, J. Troncoso, C. Paz Ramos, L. Romani, V. Najdanovic-Visak, H. J. R. Guedes, J. M. S. S. Esperança, Z. P. Visak, M. Nunes da Ponte, L. P. N. Rebelo, Andreas Heintz, Wojciech Marczak, Sergey P. Verevkin, Douglas M. Fox, Walid H. Awad, Jeffrey W. Gilman, Paul H. Maupin, Paul C. Trulove, Hugh C. De Long, M. F. Costa Gomes, P. Husson, and J. Ja

Subjects
Ionic structure--Congresses, Ionic solutions--Congresses, Solution (Chemistry)--Congresses
Published
2005

18. Ionic Liquids As Green Solvents

Author

Robin D. Rogers, Kenneth R. Seddon, John D. Holbrey, Megan B. Turner, Adrian J. Carmichael, Maggel Deetlefs, Martyn J. Earle, Ute Fröhlich, Philip E. Rakita, Christine J. Bradaric, Andrew Downard, Christine Kennedy, Allan J. Robertson, Yuehui Zhou, Peter Wasserscheid, Roy van Hal, Andreas Bösmann, Jochen Eßer, Andreas Jess, Rex X. Ren, Rajender S. Varma, M. Aresta, I. Tkatchenko, I. Tommasi, James H. Davis, Phillip A. Fox, Jennifer L. Anthony, Jacob M. Crosthwaite, Daniel G. Hert, Sudhir N. V. K. Aki, Edward J. Maginn, Joan F. Brennecke, W. Matthew Reichert, Ramana G. Reddy, Andreas Heintz, Jochen K. Lehmann, Sergey P. Verevkin, D. T. Bowron, C. Hardacre, J. D. Holbrey, S. E. J. McMath, M. Nieuwenhuyzen, A. K. Soper, Timothy I. Morrow, Orlando Acevedo, Jeffrey D. Evanseck, Roger A. Sheldon, F. van Rantwijk, R. Madeira Lau, Nicole Kaftzik, Sebastian Neumann, Maria-Regina Kula, Udo Kragl, Gary A. Baker, Sheila N. Baker, T. Mark McCleskey, James H. Werner, Seongsoon Park, Fredrik Viklund, Karl Hult, Romas J. Kazlauskas, Pedro Lozano, Teresa De Diego, Robin D. Rogers, Kenneth R. Seddon, John D. Holbrey, Megan B. Turner, Adrian J. Carmichael, Maggel Deetlefs, Martyn J. Earle, Ute Fröhlich, Philip E. Rakita, Christine J. Bradaric, Andrew Downard, Christine Kennedy, Allan J. Robertson, Yuehui Zhou, Peter Wasserscheid, Roy van Hal, Andreas Bösmann, Jochen Eßer, Andreas Jess, Rex X. Ren, Rajender S. Varma, M. Aresta, I. Tkatchenko, I. Tommasi, James H. Davis, Phillip A. Fox, Jennifer L. Anthony, Jacob M. Crosthwaite, Daniel G. Hert, Sudhir N. V. K. Aki, Edward J. Maginn, Joan F. Brennecke, W. Matthew Reichert, Ramana G. Reddy, Andreas Heintz, Jochen K. Lehmann, Sergey P. Verevkin, D. T. Bowron, C. Hardacre, J. D. Holbrey, S. E. J. McMath, M. Nieuwenhuyzen, A. K. Soper, Timothy I. Morrow, Orlando Acevedo, Jeffrey D. Evanseck, Roger A. Sheldon, F. van Rantwijk, R. Madeira Lau, Nicole Kaftzik, Sebastian Neumann, Maria-Regina Kula, Udo Kragl, Gary A. Baker, Sheila N. Baker, T. Mark McCleskey, James H. Werner, Seongsoon Park, Fredrik Viklund, Karl Hult, Romas J. Kazlauskas, Pedro Lozano, and Teresa De Diego

Published
2003

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