Characterization of Beech Wood Pellets as Low-Emission Solid Biofuel for Residential Heating in Serbia

This study evaluated the suitability of two types of beech wood pellets as renewable, low-emission biofuel sources in order to combat the energy mix and poor air quality in Serbia. Key solid biofuel characteristics, including the heating values (18.5–18.7 MJ/kg), moisture content (5.54–7.16%), and volatile matter (82.4–84.4%) were assessed according to established standards. The elemental composition (mass fractions of 48.26–48.53% carbon, 6% hydrogen, 0.12–0.2% nitrogen, 0.02% sulfur, non-detected chlorine) and ash content (0.46–1.2%) demonstrated that the analyzed beech pellets met the criteria for high-quality classification, aligning with the ENplus A1 and ENplus A2 standards. The emissions of O2, CO2, CO, NOx, SO2, and TOC were quantified in the flue gas of an automatic residential pellet stove and compared with the existing literature. While combustion of the beech pellets yielded low emissions of SO2 (6 mg/m3) and NOx (188 mg/m3), the fluctuating CO (1456–2064 mg/m3) and TOC (26.75–61.46 mg/m3) levels were influenced by the appliance performance. These findings underscore the potential of beech wood pellets as a premium solid biofuel option for Serbian households, offering implications for both end-users and policymakers.