Mechanism of tribo-chemical reactions of ionic liquids on titanium alloys

In this paper, the tribological, the tribo-chemical reaction mechanisms and desorption properties of three ionic liquids (ILs), [Bu3MeP][ Tf2N], [Bu3MeN][ Tf2N] and [Bu3MeP][ (MeO)2PO2], in contact with titanium and under vacuum conditions are studied with the CATRI © UHV Tribometer developed by IK4-TEKNIKER [1]. The two ILs containing the bis(trifluoromethanesulfonyl)amide anion presented lower coefficient of friction compared to that having the dimethyl phosphate anion. The tribodesorption study revealed that it is required an induction period to decrease the friction coefficient. The end of this period is accelerated in the case of trifluoromethane ionic liquids by the CF3+ release. Hence, the CF3+ reacts with the titanium surface generating a titanium fluoride tribolayer that could act like a catalyst to generate the tribodesorption of ionic liquid cation fragments (CH3+, C2H5+, C3H7+, C4H9+). The XPS analysis confirmed the generation of a boundary film, comprising of sulfide and inorganic fluoride, and being possibly the responsible of decreasing the friction coefficient. The [Bu3MeP][MeO)2PO2] ionic liquid required a long induction period, it did not form any tribolayer and no reduction of friction coefficient, yielding instead a high abrasion and adhesion mechanism. Thus, it can be concluded that bis(trifluoromethanesulfonyl)amide anion is more effective than dimethylphosphate in generating a surface protective film on the titanium surface under the selected test conditions and the testing methodology seems to be useful to understand the tribodesorption mechanism.