Encapsulation of Chaotropic closo-Decahydrodecaborate Clusters Within Cyclodextrins: Synthesis, Solution Studies, and DFT Calculations

Authors :: Universitat Rovira i Virgili
Diab M; Floquet S; Haouas M; Abramov P; López X; Landy D; Damond A; Falaise C; Guérineau V; Touboul D; Naoufal D; Cadot E
Universitat Rovira i Virgili
Diab M; Floquet S; Haouas M; Abramov P; López X; Landy D; Damond A; Falaise C; Guérineau V; Touboul D; Naoufal D; Cadot E
Source :: European Journal Of Inorganic Chemistry; 10.1002/ejic.201900602; European Journal Of Inorganic Chemistry. 2019 (29): 3373-3382
Publication Year :: 2019
Abstract: © 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim This paper deals with the formation of host-guest systems between cyclodextrins and the closo-decahydrodecaborate cluster. The inclusion processes, although involving weak interaction, were evidenced in solution by ESI-MS and various NMR techniques. ITC measurements provided thermodynamic parameters, and DFT calculations gave some elements that help in understanding these processes.

Database :: OAIster
Journal :: European Journal Of Inorganic Chemistry; 10.1002/ejic.201900602; European Journal Of Inorganic Chemistry. 2019 (29): 3373-3382
Publication Type :: Electronic Resource
Accession number :: edsoai.on1443596283
Document Type :: Electronic Resource

Tools