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Synthesis of 9,10-Dibenzoyl-phenanthrene Derivatives Through a Palladium-Catalyzed Domino Approach

Authors :
Arcadi, A.
Fabrizi, G.
Goggiamani, Antonella
Iazzetti, Antonia
Iavarone, Federica
Marrone, Francesco
Mazzoccanti, G.
Sferrazza, A.
Goggiamani A.
Iazzetti A. (ORCID:0000-0002-7792-774X)
Iavarone F. (ORCID:0000-0002-2074-5531)
Marrone F.
Arcadi, A.
Fabrizi, G.
Goggiamani, Antonella
Iazzetti, Antonia
Iavarone, Federica
Marrone, Francesco
Mazzoccanti, G.
Sferrazza, A.
Goggiamani A.
Iazzetti A. (ORCID:0000-0002-7792-774X)
Iavarone F. (ORCID:0000-0002-2074-5531)
Marrone F.
Publication Year :
2023

Abstract

A palladium-catalyzed domino approach toward synthetically challenging phenanthrene derivatives has been developed. The procedure involves a sequence of oxidative homocoupling, cyclization, and oxidation starting from deoxybenzoin derivatives halogenated in the ortho position. Good assembly efficiency and good functional group tolerance have been observed with yields from moderate to excellent. A plausible reaction mechanism has been proposed based on experimental results and literature data.image

Details

Database :
OAIster
Notes :
English
Publication Type :
Electronic Resource
Accession number :
edsoai.on1439662761
Document Type :
Electronic Resource