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Highly Enantioselective Extraction of Phenylglycine by a Chiral Macrocyclic Receptor Based on Supramolecular Interactions

Authors :
García Turiel, María
Garrido González, José J.
Simón, Luis
Sanz, Francisca
Lithgow, Anna M.
Rodríguez Morán, Joaquín
Fuentes de Arriba, Angel L.
María Victoria, María Victoria
García Turiel, María
Garrido González, José J.
Simón, Luis
Sanz, Francisca
Lithgow, Anna M.
Rodríguez Morán, Joaquín
Fuentes de Arriba, Angel L.
María Victoria, María Victoria
Source :
Organic Letters, ISSN 1523-7060, 2020-01-13, Vol. 22, No. 3
Publication Year :
2020

Abstract

Using supramolecular interactions, a novel macrocyclic receptor is able to selectively extract zwitterionic phenylglycine from neutral aqueous solutions into chloroform with up to 91.8% ee. Modeling studies, nuclear magnetic resonance experiments, and X-ray diffraction analysis were carried out to explain the high enantioselectivity observed.

Details

Database :
OAIster
Journal :
Organic Letters, ISSN 1523-7060, 2020-01-13, Vol. 22, No. 3
Notes :
application/pdf, English
Publication Type :
Electronic Resource
Accession number :
edsoai.on1420250302
Document Type :
Electronic Resource