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First Structural Characterization of a Protactinium(V) Single Oxo Bond in Aqueous Media
- Source :
- Inorganic Chemistry 44(2005), 9542-9546
- Publication Year :
- 2005
-
Abstract
- We report here the first structural characterization of Pa(V) adducts in concentrated sulfuric and hydrofluoric solutions. In sulfuric medium, X ray Absorption Spectroscopic data show that unlike the other early actinide elements as uranium or neptunium, protactinium doesnt form a transdioxo cation but a monooxo adduct. In contrast, concentrated hydrofluoric medium precludes the formation of any oxo bond.
Details
- Database :
- OAIster
- Journal :
- Inorganic Chemistry 44(2005), 9542-9546
- Notes :
- application/pdf, English
- Publication Type :
- Electronic Resource
- Accession number :
- edsoai.on1415617778
- Document Type :
- Electronic Resource