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Molten metal closo-borate solvates

Authors :
Møller, K.T.
Paskevicius, Mark
Andreasen, J.G.
Lee, Juni
Chen-Tan, N.
Overgaard, J.
Payandeh, S.
Silvester-Dean, Debbie
Buckley, Craig
Jensen, T.R.
Møller, K.T.
Paskevicius, Mark
Andreasen, J.G.
Lee, Juni
Chen-Tan, N.
Overgaard, J.
Payandeh, S.
Silvester-Dean, Debbie
Buckley, Craig
Jensen, T.R.
Publication Year :
2019

Abstract

Solvated lithium closo-dodecaborate, Li2B12H12 with tetrahydrofuran and acetonitrile, show unexpected melting below 150 °C. This feature has been explored to melt-infiltrate Li2B12H12 in a nanoporous SiO2 scaffold. The ionic conductivity of Li2B12H12·xACN reaches 0.08 mS cm-1 in the liquid state at 150 °C making them suitable as battery electrolytes.

Details

Database :
OAIster
Publication Type :
Electronic Resource
Accession number :
edsoai.on1393087005
Document Type :
Electronic Resource