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<scp>l</scp>-Proline, a resolution agent able to target both enantiomers of mandelic acid: an exciting case of stoichiometry controlled chiral resolution
- Source :
- Chemical Communications, Vol. 58, no.61, p. 8560-8563 (2022)
- Publication Year :
- 2022
-
Abstract
- We present a thought-provoking development in chiral resolution. Using a resolving agent of a given handedness, L-proline, we show that both R- and S-enantiomers of mandelic acid can be resolved from a racemic mixture simply by varying the stoichiometry. We are the first to report this specific feature, achieved by the existence of stoichiometrically diverse cocrystal systems between R- and S-mandelic acid and L-proline.
Details
- Database :
- OAIster
- Journal :
- Chemical Communications, Vol. 58, no.61, p. 8560-8563 (2022)
- Notes :
- English
- Publication Type :
- Electronic Resource
- Accession number :
- edsoai.on1372933070
- Document Type :
- Electronic Resource