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The electronic structure of f-element Prussian blue analogs determined by soft X-ray absorption spectroscopy.

Authors :
Dumas, Thomas
Dumas, Thomas
Guillaumont, Dominique
Moisy, Philippe
Shuh, David K
Tyliszczak, Tolek
Solari, Pier Lorenzo
Den Auwer, Christophe
Dumas, Thomas
Dumas, Thomas
Guillaumont, Dominique
Moisy, Philippe
Shuh, David K
Tyliszczak, Tolek
Solari, Pier Lorenzo
Den Auwer, Christophe
Source :
Chemical communications (Cambridge, England); vol 54, iss 86, 12206-12209; 1359-7345
Publication Year :
2018

Abstract

In molecular solids derived from Prussian blue, intermetallic charge transfer is fostered through a cyano bridge two metal ions. In this study, isostructural trivalent lanthanide and tetravalent actinide Prussian blue analogs' valence orbitals are probed by soft X-ray absorption measurements.

Details

Database :
OAIster
Journal :
Chemical communications (Cambridge, England); vol 54, iss 86, 12206-12209; 1359-7345
Notes :
application/pdf, Chemical communications (Cambridge, England) vol 54, iss 86, 12206-12209 1359-7345
Publication Type :
Electronic Resource
Accession number :
edsoai.on1367413004
Document Type :
Electronic Resource