Long-Term Hygroscopic Thickness Swelling Rate of Hydrothermally Treated Beech Wood / Polypropylene Composites

Long-term hygroscopic thickness swelling rate of polypropylene (PP) composites filled with thermally treated wood flour was investigated. The beech wood chips were heat treated at 120 °C, 150 °C or 180 °C for 30 or 120 min using saturated steam in a digester. The composites based on PP, beech wood flour (BF), and coupling agents (PP-g-MA) were made by melt compounding and injection molding. The weight ratio of BF to PP was controlled at 50/47 for all blends. The amount of coupling agent was fixed at 3 wt.% for all formulations. Further study was conducted to model thickness swelling of the composites, a swelling rate parameter (KSR). The thickness swelling of thermally-treated samples at 120 ºC for 30 min and at 150 ºC for 30 min were lower than that of control samples, followed by thermally-treated samples at 180 ºC for 120 min, at 180 ºC for 30 min, at 120 ºC for 120 min, and at 150 ºC for 120 min, respectively. Furthermore, the thickness swelling of the BF/PP composites decreased with increasing time and temperature of the thermal-treatment. In addition, at 120 ºC for 30 min, the composites showed a lower swelling rate than control samples. The KSR of the composites was influenced both by the time and temperature of thermal treatment.
U radu je istražen dugotrajni stupanj higroskopskoga debljinskog bubrenja polipropilenskih (PP) kompozita punjenih toplinski obrađenim drvnim brašnom. Iverje od bukovine bilo je toplinski tretirano na 120, 150 ili 180 °C tijekom 30 ili 120 minuta uz pomoć zasićene pare u digestoru. Kompoziti na bazi PP-a, brašna od bukovine (BF)-a i veziva (PP-g-MA) izrađeni su taljenjem i injekcijskim prešanjem. Maseni je omjer BF/PP za sve smjese bio 50/47. Količina veziva za sve formulacije bila je na 3 wt.%. Nadalje, provedeno je modeliranje debljinskog bubrenja kompozita i parametra brzine bubrenja (KSR). Debljinsko bubrenje uzoraka toplinski tretiranih 30 min na 120 ºC i 30 min na 150 ºC bilo je niže nego na kontrolnim uzorcima, zatim slijede uzorci toplinski tretirani 120 min na 180 ºC, 30 min na 180 ºC, 120 min na 120 ºC, odnosno 120 min na 150 ºC. Nadalje, debljinsko bubrenje BF/PP kompozita smanjivalo se s povećanjem vremena i temperature toplinskog postupka. Osim toga, kompoziti su pri 30 min na 120 ºC pokazali niži parametar brzine bubrenja od kontrolnih uzoraka. Na parametar brzine bubrenja kompozita utjecali su vrijeme toplinskog tretmana i temperatura.