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Spin states of C603- and C120On- (n = 2, 3, 4) anions using electron spin transient nutation spectroscopy
- Source :
- Journal of Physical Chemistry B; vol 107, iss 41, 11353-11359; 1520-6106
- Publication Year :
- 2003
-
Abstract
- Electron spin transient nutation (ESTN) experiments show that the spin multiplicity of the ground state of C603- in frozen solution is a doublet with S = 1/2. In purified samples, there is no evidence for excited states or other species with higher multiplicity. In the anions of C120On- (n = 2, 3, 4), where the CW EPR experiments have shown that a mixture of species is present, ESTN experiments confirm that a doublet with S = 1/2 is associated with the 3- anion and triplets with S = 1 are associated with the 2- and 4- anions. A weak nutation peak attributable to ms = -1/2 ↔ 1/2 transitions within a quartet state may arise from association of anions with spins of 1/2 and 1 in solute aggregates.
Details
- Database :
- OAIster
- Journal :
- Journal of Physical Chemistry B; vol 107, iss 41, 11353-11359; 1520-6106
- Notes :
- application/pdf, Journal of Physical Chemistry B vol 107, iss 41, 11353-11359 1520-6106
- Publication Type :
- Electronic Resource
- Accession number :
- edsoai.on1287323076
- Document Type :
- Electronic Resource