The Velardeña Zn–(Pb–Cu) skarn-epithermal deposits, central-northern Mexico: new physical-chemical constraints on ore-forming processes

The Velardeña mining district is economically the most important of Durango state. The ore deposits occur in different skarn zones developed within the intrusive contact between Mesozoic limestones and Eocene granitic stocks and dikes. The most important ore deposits are related to the Santa María dike and Reyna de Cobre porphyritic stock (separated from each other by 10 km). They occur as irregularly shaped replacement masses developed near the intrusive contact and have a skarn paragenesis dominated by calc-silicates and sulfides. The mineral assemblages show replacement textures and are dominated by calcic clinopyroxene (Di97-53Hd42-02Jh04-01) and garnet (Ad100-57Grs43-00) in the exoskarn, with wollastonite particularly abundant in the endoskarn. Hydrous silicates are actinolite, epidote, and chlorite, whereas sulfides include pyrite, sphalerite, pyrrhotite, galena, chalcopyrite, and sulfosalts. Scheelite, hematite, quartz, and calcite are also present. According to sphalerite geobarometry, the skarns formed at hypabyssal depths (~3–4 km). They developed by a succession of replacive mineralizing events, including (a) a prograde stage at temperatures from =470 to 335 °C in conditions of low f(CO2), followed by (b) a retrograde stage from 335 to 220 °C. There was a general increase in f(O2), accompanying the temperature decline during the formation of the system, which accounts for a process of mixing with cooler, oxidizing, and dilute water. During the retrograde stage, wollastonite calcic garnet and clinopyroxene formed. On the other hand, hydrous silicates, sulfides, sulfosalts, scheelite, and hematite crystallized during the retrograde stage. Skarn mineralization is crosscut by veins of calcite, fluorite, adularia, and sphalerite. The vein mineralization formed at temperatures below 200 °C. The different ore deposits of Velardeña constitute a telescoped skarn–epithermal mineral system.
This project was sponsored by Industrias Peñoles, S.A. de C.V., and the stable isotope measurements were supported by the Catalan project 2014-SGR-1661. The SEM-EDS and WDS analyses and BSE images were obtained with the assistance of Carlos Linares. Teresa Pi Puig is thanked for the XRD analyses. We thank Thomas Bissig, Bernd Lehmann, Teresa Ubide and Lisard Torró i Abat and for helpful comments on the manuscript. We also thank the anonymous reviewers for constructive comments.
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