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Intermolecular N-H...O and C-H...O interactions form a two-dimensional network in (2S,4S,5R)-(-)-3,4-dimethyl-5-phenyl-2-(pyrrol-2-yl)-1,3-oxazolidine

Authors :
Gallagher, John F.
Fitzsimons, Lavelle M.
Gallagher, John F.
Fitzsimons, Lavelle M.
Source :
Gallagher, John F. ORCID: 0000-0003-4130-4556 <
Publication Year :
1999

Abstract

The title compound, C₁₅H₁₈N₂0, prepared from (1R,2S)- (-)-ephedrine, crystallizes in space group P1 with two molecules in the asymmetric unit. The oxazolidine rings of the two molecules adopt an envelope conformation, with the N atom 0.609 (6) and 0.623 (6)Å from the plane of the other four oxazolidine ring atoms. Intermolecular Npyrrole--H...O and Cphenyl--H...O interactions generate a two-dimensional hydrogen-bonded network with N...O and C...O distances of 3.004 (4) and 3.051 (4)Å, respectively, and 3.599 (5) and 3.632 (5)Å, respectively, for the two independent hydrogen-bonding systems.

Details

Database :
OAIster
Journal :
Gallagher, John F. ORCID: 0000-0003-4130-4556 <
Notes :
application/pdf, Gallagher, John F. ORCID: 0000-0003-4130-4556 and Fitzsimons, Lavelle M. (1999) Intermolecular N-H...O and C-H...O interactions form a two-dimensional network in (2S,4S,5R)-(-)-3,4-dimethyl-5-phenyl-2-(pyrrol-2-yl)-1,3-oxazolidine. Acta Crystallographica Section C, 55 (6). pp. 1000-1003. ISSN 0108-2701, English
Publication Type :
Electronic Resource
Accession number :
edsoai.on1135948963
Document Type :
Electronic Resource