Synthesis, Crystal Structure, and Characterization of the first Organic Cation Hexaoxoperiodate

Authors :: Wacharine, I.
Smirani, Wajda Sta
Rzaigui, M.
Wacharine, I.
Smirani, Wajda Sta
Rzaigui, M.
Source :: JOURNAL OF ADVANCES IN CHEMISTRY; Vol. 9 No. 1 (2014); 1776-1782; 2321-807X
Publication Year :: 2013
Abstract: The title compound is an organic-inorganic hybrid material. The single crystal X-ray diffraction investigation reveals that the studied compound crystallizes in the monoclinic system, space group P21/c with the following lattice parameters: Â Â Â Â Â Â Â Â Â Â Â Â Â Â ð‘Ž = 7.551 (2) Ã…, ð‘ = 6.694 (3) Ã…, ð‘ = 14.783 (2) Ã…, Î² = 97.61 (2)Â° and ð‘ = 2. The crystal lattice is composed of a discrete (H4IO6)âˆ’ anion surrounded by piperazinium cations and water molecules. Complex hydrogen bonding interactions between the different chemical spices form a three-dimensional network. Room temperature IR, 13C NMR spectroscopy, thermogravimetric analysis and optical absorption of the title compound were recorded and analyzed.Â

Database :: OAIster
Journal :: JOURNAL OF ADVANCES IN CHEMISTRY; Vol. 9 No. 1 (2014); 1776-1782; 2321-807X
Notes :: application/pdf, English
Publication Type :: Electronic Resource
Accession number :: edsoai.on1134120001
Document Type :: Electronic Resource

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