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Enantio‐, Regio‐ and Chemoselective Copper‐Catalyzed 1,2‐Hydroborylation of Acylsilanes
- Source :
- Chemistry – A European Journal, (2019)
- Publication Year :
- 2019
-
Abstract
- The enantioselective synthesis of synthetically significant ( -hydroxyallyl)silanes, ( -hydroxyaryl)silanes and ( hydroxyalkyl)silanes is reported. The present copper-catalysed 1,2hydroborylation of acylsilanes affords the aforementioned products in high yields and high enantiomeric excesses. This robust and scalable additive-free catalytic system relies on the use of low copper(II) acetate and diphosphine ligand loadings at room temperature in the presence of a commercially available and bench stable hydride source.
Details
- Database :
- OAIster
- Journal :
- Chemistry – A European Journal, (2019)
- Notes :
- English
- Publication Type :
- Electronic Resource
- Accession number :
- edsoai.on1130443871
- Document Type :
- Electronic Resource