Decoupling Epitaxial Graphene from Metals by Potential-Controlled Electrochemical-Oxidation of the Substrate

High-quality epitaxial graphene can be efficiently grown on metal substrates. Unfortunately, the strong interaction with the supporting metal quenches graphene¿s outstanding properties, thus transfer protocols to insulating surfaces are nowadays routinely used. These transfer processes are cost inefficient and some can severely degrade the properties of graphene by introducing structural and chemical defects. In this work we have used cyclic voltammetry to decouple epitaxial graphene from Pt(111) and polycrystalline Cu metal surfaces. A multitechnique structural characterization (STM, AFM and Raman) combined with theoretical studies (ab-initio calculations) of the different steps of the process show that an atom thick metal-oxide layer is intercalated on the interface between the Ultra High Vacuum (UHV) grown graphene and the surface. Epitaxial graphene has been grown in UHV by thermal decomposition of aromatics, following the procedure described in [1]. Fig. 1a shows a representative STM image of a wide scan area as well as the typical LEED pattern obtained for Gr on Pt(111) [2, 3]. It is possible to clearly distinguish a wrinkle, some nanobubbles and the contour of the Gr domains. Fig. 1b shows a high resolution STM image acquired on a terrace, where the representative z(¿44x¿44)R15°Gr Moiré superstructure is observed with atomic resolution. The Moiré superstructure is a fingerprint for single-layer graphene on the platinum surface [2]. Thus, the STM together with the LEED confirm the high quality of the graphene layer used for the experiments. After in-situ characterization the sample was removed from UHV and characterized by AFM, SEM and Raman spectroscopy before and after electrochemical treatments. Fig. 2 shows important changes in the Raman spectra of the graphene layer induced by the electrochemical treatment. In the untreated sample only atmospheric O2 and N2 bands can be observed, and no evidence of the characteristic graphene bands (G and 2D) are found, c