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Direct observation of Mg2+ complexes in ionic liquid solutions by 31Mg β-NMR spectroscopy
- Source :
- Szunyogh , D , McFadden , R M L , Karner , V L , Chatzichristos , A , Day Goodacre , T , Dehn , M H , Formenti , L , Fujimoto , D , Gottberg , A , Kallenberg , E , Kálomista , I , Kiefl , R F , Larsen , F H , Lassen , J , Levy , C D P , Li , R , Macfarlane , W A , McKenzie , I , Morris , G D , Pallada , S , Pearson , M R , Sauer , S P A , Schaffer , P , Thulstrup , P W , Hemmingsen , L B S & Stachura , M 2018 , ' Direct observation of Mg 2+ complexes in ionic liquid solutions by 31 Mg β-NMR spectroscopy ' , Dalton Transactions , vol. 47 , no. 41 , pp. 14431-14435 .
- Publication Year :
- 2018
-
Abstract
- NMR spectra of Mg2+ ions in ionic liquids were recorded using a highly sensitive variant of NMR spectroscopy known as β-NMR. The β-NMR spectra of MgCl2 in EMIM-Ac and EMIM-DCA compare favourably with conventional NMR, and exhibit linewidths of ∼3 ppm, allowing for discrimination of species with oxygen and nitrogen coordination.
Details
- Database :
- OAIster
- Journal :
- Szunyogh , D , McFadden , R M L , Karner , V L , Chatzichristos , A , Day Goodacre , T , Dehn , M H , Formenti , L , Fujimoto , D , Gottberg , A , Kallenberg , E , Kálomista , I , Kiefl , R F , Larsen , F H , Lassen , J , Levy , C D P , Li , R , Macfarlane , W A , McKenzie , I , Morris , G D , Pallada , S , Pearson , M R , Sauer , S P A , Schaffer , P , Thulstrup , P W , Hemmingsen , L B S & Stachura , M 2018 , ' Direct observation of Mg 2+ complexes in ionic liquid solutions by 31 Mg β-NMR spectroscopy ' , Dalton Transactions , vol. 47 , no. 41 , pp. 14431-14435 .
- Notes :
- application/pdf, English
- Publication Type :
- Electronic Resource
- Accession number :
- edsoai.on1085119453
- Document Type :
- Electronic Resource