Silver-halophenylethynide and silver-nitrophenylethynide supramolecular synthons for the construction of coordination networks.

Wang, Minji.
Thesis (M.Phil.)--Chinese University of Hong Kong, 2009.
Includes bibliographical references (leaves 91-97).
s in English and Chinese.
Acknowledgement --- p.i
p.ii
摘要 --- p.iii
Chapter Chapter 1. --- Introduction --- p.1
Chapter 1.1 --- Weak Intermolecular Interactions --- p.1
Chapter 1.1.1 --- Van der Waals Interaction --- p.1
Chapter 1.1.2 --- Hydrogen Bonds --- p.2
Chapter 1.1.3 --- π…π Interactions --- p.4
Chapter 1.1.4 --- Lone-Pair…Aromatic Interactions --- p.5
Chapter 1.1.5 --- Halogen…Halogen Interactions --- p.6
Chapter 1.2 --- Argentophilic Interaction --- p.7
Chapter 1.3 --- Silver Acetylenediide and Silver Arylethynide --- p.11
Chapter 1.3.1 --- "C2@Agn(n = 6, 7, 8, 9, 10)" --- p.11
Chapter 1.3.2 --- "Ag4eC=C-C=Cz>Ag4 and R-C=C@=)Agn, (n = 4, 5; R = Aryl, t-Bu)" --- p.12
Chapter 1.4 --- Research Strategy --- p.14
Chapter Chapter 2. --- "Coordination Networks Constructed with the Supramolecular Synthon System Rx-CsCzAgn (n = 4,5; Rx = halophenyl)" --- p.16
Chapter 2.1 --- Crystal Structure of AgC=CC6H4l-4 ´Ø 2AgCF3COO (2.1) --- p.17
Chapter 2.2 --- Crystal Structure of AgC=CC6H4l-4 . 3AgNO3 (2.2) --- p.20
Chapter 2.3 --- "Crystal Structure of 2AgC=CC6H3Cl2-3,4 . 5AgCF3COO ´Ø 2CH3CN . H20 (2.3)" --- p.25
Chapter 2.4 --- Crystal Structure of 4AgC=CC6H4Cl-3 . 6AgC2F5COO ´Ø 5CH3CN (2.4) & 4AgOCC6H4Br-3 ´Ø 6AgC2F5COO ´Ø 5CH3CN (2.5) --- p.28
Chapter 2.5 --- Crystal Structure of 2AgC=CC6H4Cl-2 . 4AgCF3COO ´Ø NC(CH2)4CN (2.6) & 2AgOCC6H4Cl-2 ´Ø 4AgCF3COO ´Ø 2CH3CN (2.7) --- p.32
Chapter 2.6 --- Crystal Structure of AgC=CC6H4F-2 ´Ø 2CF2(CF2COOAg)2 ´Ø 2CH3CN (2.8) --- p.36
Chapter 2.7 --- Crystal Structure of 4AgC=CC6H4N02-2 ´Ø 10AgC3F7COO ´Ø 4CH3CN . 4H20 (2.9) --- p.39
Chapter 2.8 --- Summary --- p.41
Chapter Chapter 3. --- Network Assembly with the Supramolecular Synthon System Rx-C=C3Agw (/i = 3 to 5; Rx = nitrophenyl) --- p.43
Chapter 3.1 --- Crystal Structure of AgC=CC6H4N02-2 ´Ø 3AgC2F5COO . 2CH3CN (3.1) --- p.44
Chapter 3.2 --- Crystal Structure of AgC=CC6H4N02-4 ´Ø 3AgC2F5COO ´Ø CH3CN (3.2) --- p.47
Chapter 3.3 --- Crystal Structure of AgC=CC6H4N02-4 ´Ø 4AgCF3COO ´Ø 2CH3CN (3.3) --- p.50
Chapter 3.4 --- Crystal Structure of AgC=CC6H4N02-4 ´Ø 3AgCF3COO . CH3CN ´Ø 0.5NC(CH2)4CN (3.4) --- p.53
Chapter 3.5 --- Crystal Structure of AgC=CC6H4N02-4 ´Ø 3AgC2F5COO ´Ø 2CH3CN (3.5) --- p.56
Chapter 3.6 --- Crystal Structure of AgC=CC6H4N02-4 ´Ø 3AgC2F5COO ´Ø CH3CN ´Ø NC(CH2)4CN (3.6) --- p.59
Chapter 3.7 --- Crystal Structure of 4AgC三CC6H4NOr4 ´Ø 4AgC3F7COO ´Ø 3CH3CN (3.7) --- p.62
Chapter 3.8 --- Crystal Structure of 3AgC=CC6H4N02-4 ´Ø 3AgCF3COO ´Ø 3CH3CN (3.8) --- p.66
Chapter 3.9 --- Crystal Structure of 7AgC三CC6H4NOr4 ´Ø 17AgCF3COO ´Ø 11CH3CN ´Ø H20 (3.9) --- p.68
Chapter 3.10 --- Crystal Structure of AgC=CC6H4N02-4 ´Ø CF2(CF2COOAg)2. AgCFsCOO . H2O (3.10) --- p.72
Chapter 3.11 --- Summary --- p.76
Chapter 3.12 --- Further Development --- p.77
Chapter 3.12.1 --- Elongation of Ethynide Ligands --- p.77
Chapter 3.12.2 --- Incorporating More Ethynide Ligands into One Compound --- p.78
Chapter Chapter 4. --- Experimental --- p.79
Chapter 4.1 --- Synthesis --- p.79
Chapter 4.2 --- X-Ray Crystallography --- p.84
References --- p.91
http://library.cuhk.edu.hk/record=b5896881
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