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Rational strategies for the selective functionalization of calixarenes

Authors :
Lavendomme, Roy
Zahim, Sara
De Leener, Gaël
Inthasot, Alex
Mattiuzzi, Alice
Luhmer, Michel
Reinaud, Olivia
Jabin, Ivan
Lavendomme, Roy
Zahim, Sara
De Leener, Gaël
Inthasot, Alex
Mattiuzzi, Alice
Luhmer, Michel
Reinaud, Olivia
Jabin, Ivan
Source :
Asian journal of organic chemistry, 4 (8
Publication Year :
2015

Abstract

Calixarenes are widely used as molecular platforms in supramolecular chemistry. Their efficient modification is key for appending functional moieties such as binding, sensing, chiral, or hydrophilic subunits. Due to the presence of multiple identical functional groups, selective functionalization of such macrocyclic compounds is highly challenging. Indeed, the control of the chemo-, regio-, stereo- as well as iteroselectivity is required. This review describes rational methods leading to a high degree of regio- and/or iteroselectivity and classifies them into specific strategies. Many of these strategies are conceptually very general and hopefully will be a source of inspiration for developing selective methods for other macrocyclic platforms.<br />SCOPUS: re.j<br />FLWNA<br />info:eu-repo/semantics/published

Details

Database :
OAIster
Journal :
Asian journal of organic chemistry, 4 (8
Notes :
1 full-text file(s): application/pdf, English
Publication Type :
Electronic Resource
Accession number :
edsoai.ocn921612961
Document Type :
Electronic Resource