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1,3-Dipolar Addition Reactions of Some Bisdiazo Compounds with Mono and Diolefins
- Source :
- DTIC AND NTIS
- Publication Year :
- 1972
-
Abstract
- Bisdiazoterephthalaldehyde, para-bisdiazobenzoylbenzene and meta-bis-diazobenzoylbenzene were synthesized as dicarbene precursors. Simultaneous dicarbene formation and olefinic insertion was attempted. However, what was observed was 1,3-dipolar addition of the bisdiazo compounds and strained olefinic systems such as norbornene and norbornadiene. Nuclear magnetic resonance spectroscopy indicates that the stereo-chemistry of the adducts formed lead to some large chemical shifts. Polymerization was also attempted between meta-bisdiazobenzoylbenzene and norbornadiene.
Details
- Database :
- OAIster
- Journal :
- DTIC AND NTIS
- Notes :
- text/html, English
- Publication Type :
- Electronic Resource
- Accession number :
- edsoai.ocn831992952
- Document Type :
- Electronic Resource