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Surfactant modified carbon paste electrode: Part 2: Analytical performances

Authors :
Kauffmann, Jean-Michel
Digua, Khalid
Khodari, Mahmoud
Kauffmann, Jean-Michel
Digua, Khalid
Khodari, Mahmoud
Source :
Electroanalysis, 6 (5-6
Publication Year :
1994

Abstract

The hexadecylsulfonic acid (sodium salt) modified carbon paste electrode (HDSNa‐CPE) has been studied in batch and flowing systems, and its analytical performance has been established in comparison with a conventional carbon paste electrode (CPE). Amperometry, linear scan, and preconcentration voltammetry have been used for the investigation of several analytes of pharmacological interest. Because of the presence of surface functionalities, markedly different electrode responses have been observed at the HDSNa‐CPE depending on the nature (hydrophobicity and charge) of the investigated molecule. The HDSNa‐CPE showed, in linear scan voltammetry and for all the species investigated, higher responses compared to the CPE. The HDSNa‐CPE showed important current enhancements in voltammetric analysis of hydrophobic organic cations in acidic media and at low ionic strength. Copyright © 1994 VCH Publishers, Inc.<br />SCOPUS: ar.j<br />FLWNA<br />info:eu-repo/semantics/published

Details

Database :
OAIster
Journal :
Electroanalysis, 6 (5-6
Notes :
No full-text files, English
Publication Type :
Electronic Resource
Accession number :
edsoai.ocn764580024
Document Type :
Electronic Resource