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Theoretical study of the bonding of the first- and second-row transition-metal positive ions to acetylene

Authors :
Sodupe, M
Bauschlicher, Charles W., Jr
Source :
Journal of Physical Chemistry. 95(22, 1)
Publication Year :
1991
Publisher :
United States: NASA Center for Aerospace Information (CASI), 1991.

Abstract

The bonding of transition-metal ions to acetylene is studied by using a theoretical treatment that includes electron correlation. The ions on the left side of the first and second transition rows insert into the pi bond to form a three-membered ring. On the right side of the row the bonding is electrostatic. The trends in bonding are discussed.

Subjects

Subjects :
Inorganic And Physical Chemistry

Details

Language :
English
ISSN :
00223654
Volume :
95
Issue :
22, 1
Database :
NASA Technical Reports
Journal :
Journal of Physical Chemistry
Publication Type :
Report
Accession number :
edsnas.19920051283
Document Type :
Report
Full Text :
https://doi.org/10.1021/j100175a042