Monodeuterated methane in the outer solar system. I Spectroscopic analysis of the bands at 1.55 and 1.95 microns

The analysis of the near-infrared spectrum of monodeuterated methane (CH3D) near 6400/cm and 5100/cm is presented. Three new parallel bands which have locally perturbed upper states connecting with the ground state are identified, and approximate rotational constants are derived. The band centered near 6425/cm and the 9613 A band previously analyzed by Lutz, Danehy, and Ramsay (1978) are found to form an apparent vibrational progression with the nu2 fundamental at 2200/cm, and vibrational assignments of 3nu2 and 5nu2, respectively, are proposed. Detailed comparison of the rotational constants of the states involved is shown to support these assignments.