The optical and probe measurement of NO - A comparative study

Measurements were made of NO formation in both subsonic turbulent and nonturbulent media generated from gaseous and liquid fuels. Quartz and metallic, cooled and uncooled probes were employed, and optical measurements were made in the UV with narrow-line and continuum lamps. The extent of systematic error bias in these methods was studied over a wide range of conditions. High resolution measurements were made only on flat flames using a high pressure Xe lamp, while low resolution measurements were done with a hollow cathode lamp on flat flame, swirl burner and jet combustor exhausts. Optical data were reduced using a first principles spectral model and multiple zone treatment of the optical path. No major discrepancies related to processes occurring in probes were identified. Good agreement can be expected in measurements made in subsonic exhaust streams up to 2000 K.