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Preparation of Perfluorinated Imidoylamidoxime Polymers

Authors :
Rosser, R. W
Kratzer, R. H
Paciorek, K. J. L
Ito, T. I
Source :
NASA Tech Briefs. 6(1)
Publication Year :
1982
Publisher :
United States: NASA Center for Aerospace Information (CASI), 1982.

Abstract

Perfluorinated imidoylamidoxime polymers with excellent resistance to heat, chemicals and solvents are prepared by condensing a perfluorinated nitrile with a perfluorinated amidoxime in vacuum or inert atmosphere from 20 degrees to 70 degrees C. When both reactants are difunctional, oligomeric or polymeric products are obtained. After cyclization of imidoylamidoxime groups to 1,2,4-oxadiazole linkages, process yields highly resistant elastomers. Competing side reactions are inhibited by low processing temperature.

Subjects

Subjects :
Materials

Details

Language :
English
ISSN :
0145319X
Volume :
6
Issue :
1
Database :
NASA Technical Reports
Journal :
NASA Tech Briefs
Publication Type :
Report
Accession number :
edsnas.19810000036
Document Type :
Report