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Study of sulfospinels

Authors :
Tressler, R. E
Stubican, V. S
Source :
NBS Solid State Chem..
Publication Year :
1972
Publisher :
United States: NASA Center for Aerospace Information (CASI), 1972.

Abstract

Several new compounds with the formula AB2S4 were synthesized. Pressure-induced polymorphism of the sulfospinels was investigated. Sulfospinels which produced new high-pressure phases were NiRh2S4, FeYb2S4, In2S3, CrIn2S4, NiIn2S4, CoIn2S4 and MnIn2S4. The only sulfospinels which transformed to the NiAs derivatives were those in which A and B atoms had unfilled d-orbitals. P-T phase relations were investigated for a series of sulfochromites. Thin films of several ACr2S4 sulfospinels were prepared by a flash evaporization technique on the (111) and (100) planes of NaCl and on the (100) plane of Mgo.

Subjects

Subjects :
Physics, Solid-State

Details

Language :
English
Database :
NASA Technical Reports
Journal :
NBS Solid State Chem.
Publication Type :
Report
Accession number :
edsnas.19720023083
Document Type :
Report