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Ketene-forming eliminations from aryl phenylacetates promoted by R (sub)2 NH/R (sub)2 NH (sub)2 (super)+ in aqueous MeCN. Mechanistic borderline between E2 and E1cb
- Source :
- Journal of Organic Chemistry. July 26, 2002, Vol. 67 Issue 15, p5232, 7 p.
- Publication Year :
- 2002
-
Abstract
- Research has been conducted on the elimination reactions. Results indicate that these reactions proceed via the E2 mechanism and that this mechanism gradually changes from E2 to E1cb due to a systematic change of the reactant structure.
- Subjects :
- Chemistry, Organic -- Research
Acetates -- Physiological aspects
Solution (Chemistry) -- Physiological aspects
Nitrogen -- Physiological aspects
Hydrogen -- Physiological aspects
Carbon -- Physiological aspects
Methylation -- Physiological aspects
Elimination reactions -- Research
Biological sciences
Chemistry
Subjects
Details
- ISSN :
- 00223263
- Volume :
- 67
- Issue :
- 15
- Database :
- Gale General OneFile
- Journal :
- Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.92585636