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Ketene-forming eliminations from aryl phenylacetates promoted by R (sub)2 NH/R (sub)2 NH (sub)2 (super)+ in aqueous MeCN. Mechanistic borderline between E2 and E1cb

Authors :
Bong Rae Cho
Hyun Cheol Jeong
Yoon Je Seung
Sang Yong Pyun
Source :
Journal of Organic Chemistry. July 26, 2002, Vol. 67 Issue 15, p5232, 7 p.
Publication Year :
2002

Abstract

Research has been conducted on the elimination reactions. Results indicate that these reactions proceed via the E2 mechanism and that this mechanism gradually changes from E2 to E1cb due to a systematic change of the reactant structure.

Details

ISSN :
00223263
Volume :
67
Issue :
15
Database :
Gale General OneFile
Journal :
Journal of Organic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.92585636